Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
10th Edition
ISBN: 9781305957510
Author: ZUMDAHL, Steven S.; Zumdahl, Susan A.; DeCoste, Donald J.
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 12, Problem 81E
Assuming that the mechanism for the hydrogenation of C2H4 given in Section 11-7 is correct, would you predict that the product of the reaction of C2H4. with D2 would be CH2D—CH2D or CHD2—CH3? How could the reaction of C2H4 with D2 be used to confirm the mechanism for the hydrogenation of C2H4 given in Section 11-7?
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
In the Thermo Fisher application note about wine analysis (Lesson 3), the following
chromatogram was collected of nine components of wine. If peak 3 has a retention time of
3.15 minutes and a peak width of 0.070 minutes, and peak 4 has a retention time of 3.24
minutes and a peak width of 0.075 minutes, what is the resolution factor between the two
peaks? [Hint: it will help to review Lesson 2 for this question.]
MAU
300
200
T
34
5
100-
1 2
CO
6
7
8
9
0
2.4
2.6
2.8
3.0 3.2 3.4
3.6
3.8 4.0 4.2
4.4
4.6
4.8
5.0
5.2
Minutes
3.22
0.62
1.04
O 1.24
The diagram shows two
metals, A and B, which melt at
1000°C and 1400°C. State the
weight percentage of the
primary constituent (grains of
C) that would be obtained by
solidifying a 20% alloy of B.
1000°C
a+L
L+C
900°С
12
α
a+C
45
1200 C
L+y
140096
C+Y
a+ß
800°C
700°C
C+B
96
92
a+B
0
10
20
30
40
50
60
70 80 90 100
A
% peso B
B
8.
Choose the compound that will produce the spectrum below and assign the signals to the corresponding
protons.
2
4
3
ō (ppm)
OH
4
6 6
СОН
2
1
0
Chapter 12 Solutions
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
Ch. 12 - Define reaction rate. Distinguish between the...Ch. 12 - Distinguish between the differential rate law and...Ch. 12 - One experimental procedure that can be used to...Ch. 12 - The initial rate for a reaction is equal to the...Ch. 12 - Consider the zero-, first-, and second-order...Ch. 12 - Derive expressions for the half-life of zero-,...Ch. 12 - Prob. 7RQCh. 12 - What two requirements must be met to call a...Ch. 12 - Prob. 9RQCh. 12 - Give the Arrhenius equation. Take the natural log...
Ch. 12 - Why does a catalyst increase the rate of a...Ch. 12 - Define stability from both a kinetic and...Ch. 12 - Describe at least two experiments you could...Ch. 12 - Make a graph of [A] versus time for zero-, first-,...Ch. 12 - How does temperature affect k, the rate constant?...Ch. 12 - Consider the following statements: In general, the...Ch. 12 - For the reaction A+BC, explain at least two ways...Ch. 12 - A friend of yours states, A balanced equation...Ch. 12 - Provide a conceptual rationale for the differences...Ch. 12 - The rate constant (k) depends on which of the...Ch. 12 - Table 11-2 illustrates how the average rate of a...Ch. 12 - The rate law for a reaction can be determined only...Ch. 12 - The plot below shows the number of collisions with...Ch. 12 - For the reaction O2(g)+2NO(g)2NO2(g) the observed...Ch. 12 - Each of the statements given below is false....Ch. 12 - Define what is meant by unimolecular and...Ch. 12 - The type of rate law for a reaction, either the...Ch. 12 - The initial rate of a reaction doubles as the...Ch. 12 - Hydrogen reacts explosively with oxygen. However,...Ch. 12 - The central idea of the collision model is that...Ch. 12 - Consider the following energy plots for a chemical...Ch. 12 - Prob. 21QCh. 12 - Prob. 22QCh. 12 - The combustion of carbohydrates and the combustion...Ch. 12 - Would the slope of a ln(k) versus 1/T plot (with...Ch. 12 - Consider the reaction 4PH3(g)P4(g)+6H2(g) If, in a...Ch. 12 - In the Haber process for the production of...Ch. 12 - At 40C, H2O2 (aq) will decompose according to the...Ch. 12 - Consider the general reaction aA+bBcC and the...Ch. 12 - What are the units for each of the following if...Ch. 12 - The rate law for the reaction...Ch. 12 - The reaction 2NO(g)+Cl2(g)2NOCl(g) was studied at...Ch. 12 - The reaction 2I-(aq)+S2O82-(aq)I2(aq)+2SO42-(aq)...Ch. 12 - The decomposition of nitrosyl chloride was...Ch. 12 - The following data were obtained for the gas-phase...Ch. 12 - The reaction I(aq)+OCl(aq)IO(aq)+Cl(aq) was...Ch. 12 - The reaction 2NO(g)+O2(g)2NO2(g) was studied. and...Ch. 12 - The rote of the reaction between hemoglobin (Hb)...Ch. 12 - The following data were obtained for the reaction...Ch. 12 - The decomposition of hydrogen peroxide was...Ch. 12 - A certain reaction has the following general form:...Ch. 12 - The rate of the reaction NO2(g)+CO(g)NO(g)+CO2(g)...Ch. 12 - A certain reaction has the following general form:...Ch. 12 - The decomposition of ethanol (C2H5OH) on an...Ch. 12 - At 500 K in the presence of a copper surface,...Ch. 12 - The dimerization of butadiene 2C4H6(g)C8H12(g) was...Ch. 12 - The rate of the reaction O(g)+NO2(g)NO(g)+O2(g)...Ch. 12 - Experimental data for the reaction A2B+C have been...Ch. 12 - Prob. 48ECh. 12 - The reaction AB+C is known to be zero order in A...Ch. 12 - The decomposition of hydrogen iodide on finely...Ch. 12 - Prob. 51ECh. 12 - A first-order reaction is 75.0% complete in 320....Ch. 12 - The rate law for the decomposition of phosphine...Ch. 12 - DDT (molar mass = 354.49 g/mol) was a widely used...Ch. 12 - The rate law for the reaction...Ch. 12 - Prob. 57ECh. 12 - Theophylline is a pharmaceutical drug that is...Ch. 12 - You and a coworker have developed a molecule...Ch. 12 - Consider the hypothetical reaction A+B+2C2D+3E...Ch. 12 - Write the rate laws for the following elementary...Ch. 12 - A possible mechanism for the decomposition of...Ch. 12 - A proposed mechanism for a reaction is...Ch. 12 - The mechanism for the gas-phase reaction of...Ch. 12 - Is the mechanism NO+Cl2l1NOCl2NOCl2+NOl22NOCl...Ch. 12 - The reaction 2NO(g) + O2(g) 2NO2(g) exhibits the...Ch. 12 - For the following reaction profile, indicate a....Ch. 12 - Draw a rough sketch of the energy profile for each...Ch. 12 - The activation energy for the reaction...Ch. 12 - The activation energy for some reaction...Ch. 12 - The rate constant for the gas-phase decomposition...Ch. 12 - The reaction (CH3)3CBr+OH(CH3)3COH+Br in a certain...Ch. 12 - The activation energy for the decomposition of...Ch. 12 - A first-order reaction has rate constants of 4.6 ...Ch. 12 - A certain reaction has an activation energy of...Ch. 12 - Prob. 76ECh. 12 - Which of the following reactions would you expect...Ch. 12 - Prob. 78ECh. 12 - One mechanism for the destruction of ozone in the...Ch. 12 - One of the concerns about the use of Freons is...Ch. 12 - Assuming that the mechanism for the hydrogenation...Ch. 12 - The decomposition of NH3 to N2 and H2 was studied...Ch. 12 - The decomposition of many substances on the...Ch. 12 - Prob. 84ECh. 12 - A popular chemical demonstration is the magic...Ch. 12 - Prob. 86ECh. 12 - Consider the following representation of the...Ch. 12 - The reaction H2SeO3(aq) + 6I-(aq) + 4H+(aq) Se(s)...Ch. 12 - Consider two reaction vessels, one containing A...Ch. 12 - Sulfuryl chloride (SO2Cl2) decomposes to sulfur...Ch. 12 - For the reaction 2N2O5(g)4NO2(g)+O2(g) the...Ch. 12 - Experimental values for the temperature dependence...Ch. 12 - At 620. K butadiene dimerizes at a moderate rate....Ch. 12 - For a first order gas phase reaction A products,...Ch. 12 - Cobra venom helps the snake secure food by binding...Ch. 12 - Iodomethane (CH3I) is a commonly used reagent in...Ch. 12 - Experiments during a recent summer on a number of...Ch. 12 - The activation energy of a certain uncatalyzed...Ch. 12 - Consider the following initial rate data for the...Ch. 12 - Consider a hypothetical reaction between A and B:...Ch. 12 - Consider the reaction 3A+B+CD+E where the rate law...Ch. 12 - The thiosulfate ion (S2O32) is oxidized by iodine...Ch. 12 - The reaction A(aq)+B(aq)products(aq) was studied,...Ch. 12 - A certain substance, initially present at 0.0800...Ch. 12 - A reaction of the form aAProducts gives a plot of...Ch. 12 - A certain reaction has the form aAProducts At a...Ch. 12 - Which of the following statement(s) is( are) true?...Ch. 12 - Consider the hypothetical reaction A2(g) + B2(g) ...Ch. 12 - Experiments have shown that the average frequency...Ch. 12 - Consider a reaction of the type aA products, in...Ch. 12 - A study was made of the effect of the hydroxide...Ch. 12 - Two isomers (A and B) of a given compound dimerize...Ch. 12 - The reaction NO(g)+O3NO2(g)+O2(g) was studied by...Ch. 12 - Prob. 114CPCh. 12 - In the gas phase, the production of phosgene from...Ch. 12 - Most reactions occur by a series of steps. The...Ch. 12 - You are studying the kinetics of the reaction...Ch. 12 - The decomposition of NO2(g) occurs by the...Ch. 12 - The following data were collected in two studies...Ch. 12 - Consider the following hypothetical data collected...Ch. 12 - Consider the hypothetical reaction A+B+2C2D+3E In...Ch. 12 - Hydrogen peroxide and the iodide ion react in...Ch. 12 - Sulfuryl chloride undergoes first-order...Ch. 12 - Upon dissolving InCl(s) in HCl, In+(aq) undergoes...Ch. 12 - The decomposition of iodoethane in the gas phase...Ch. 12 - Consider the following reaction: CH3X+YCH3Y+X At...
Additional Science Textbook Solutions
Find more solutions based on key concepts
True or false? Some trails are considered vestigial because they existed long ago.
Biological Science (6th Edition)
2. Which of the following is the best example of the use of a referent? _
a. A red bicycle
b. Big as a dump tru...
Physical Science
Label each statement about the polynucleotide ATGGCG as true or false. The polynucleotide has six nucleotides. ...
General, Organic, and Biological Chemistry - 4th edition
Give the IUPAC name for each compound.
Organic Chemistry
Whether two metal foil leaves an electroscope get opposite charge when the electroscope is charged.
Physics of Everyday Phenomena
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 7. Assign all of the protons on the spectrum below. A B 2 C E 2 1 3 6 4 3 2 1 0arrow_forwarde. If (3R,4R)-3,4-dichloro-2,5-dimethylhexane and (3R,4S)-3,4-dichloro-2,5-dimethylhexane are in a solution at the same concentration, would this solution be expected to rotate plane polarized light (that is, be optically active)? Please provide your reasoning for your answer. [If you read this problem carefully, you will not need to draw out the structures to arrive at your answer...]arrow_forward1. How many neighbors does the proton that produces the multiplet below have? 2. 3. اللـ Draw a partial structure from the multiplet below. (The integration of the multiplet is 6) M Using the additivity constants found in appendix G of your lab manual, calculate the approximate chemical shifts of the protons indicated below. (Show your work!!!) B A Br SHarrow_forward
- 1) Suppose 0.1 kg ice at 0°C (273K) is in 0.5kg water at 20°C (293K). What is the change in entropy of the ice as it melts at 0°? To produce the original "water gas" mixture, carbon (in a combustible form known as coke) is reacted with steam: 131.4 kJ + H20(g) + C(s) → CO(g) + H2(g) From this information and the equations in the previous problem, calculate the enthalpy for the combustion or carbon to form carbon dioxide. kindly show me how to solve this long problem. Thanksarrow_forward4. An 'H-NMR of a compound is acquired. The integration for signal A is 5692 and the integration for signal B is 25614. What is the simplest whole number ratio of protons for signals A and B? (Show your work!!!) 5. Assign the carbons in the NMR below as either carbonyl, aromatic, or alkyl. 200 150 100 50 ō (ppm) 1arrow_forwardSpeaking of composite materials, indicate the correct option:(A). Composite materials can only be: metal-polymer or polymer-polymer.(B). Composite materials can be made up of particles, but not fibers or sheets.(C). When the reinforcing particles are uniformly distributed in a composite material, there may be a greater tendency for it to have isotropic properties.(D). None of the above is correct.arrow_forward
- If we are talking about viscoelastic modulus or viscoelastic relaxation modulus in polymers, indicate the correct option.(A). It reports the variation of elastic behavior as a function of time.(B). It is only useful for defining its glass transition temperature.(C). It only allows us to define the polymer degradation temperature.(D). Neither option is correct.arrow_forwardWhen natural light falls perpendicularly on a material A, it has a reflectivity of 0.813%. Indicate the value of the refractive index.arrow_forwardIn piezoelectricity and piezoelectric ceramics, one of the following options is false:(A). Piezoelectricity allows an electrical signal to be transformed into a mechanical one.(B). PbZrO3 is a well-known piezoelectric ceramic.(C). Piezoelectricity and ferroelectricity in general have no relationship.(D). One of the applications of piezoelectricity is sonar.arrow_forward
- (30 MARKS) Give the major product(s ) formed including relevant stereochemistry or the complete reaction conditions for the following reactions. More than one step may be required for each reaction arrow, in which case the steps must be numbered 1), 2) etc. (2 marks each box) h) i) h) OH i) HO H3PO4, heat 2 Brarrow_forwardNonearrow_forwardIndicate which option is false(A). Resistivity has a residual component and a thermal component.(B). In some materials resistivity increases with T and in others it decreases.(C). In insulating materials, resistivity is very low.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY