6th Edition

ISBN: 9781264840083

Author: SMITH

Publisher: MCG

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Textbook Question

Chapter 12, Problem 60P

Devise a synthesis of each compound from acetylene and any other required reagents.

a. Chapter 12, Problem 60P, 12.63 Devise a synthesis of each compound from acetylene and any other required reagents.
a. b. , example 1 b. c. d.

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Chapter 12, Problem 59P

Chapter 12, Problem 61P

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし

3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CN

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Chapter 12 Solutions

LL ORG CHEM

Ch. 12.1 - Prob. 1P Ch. 12.3 - Problem 12.2 What alkane is formed when each...Ch. 12.3 - Prob. 3P Ch. 12.3 - Prob. 4P Ch. 12.3 - Prob. 5P Ch. 12.3 - Prob. 6P Ch. 12.3 - Compound Molecular formula before...Ch. 12.4 - Problem 12.8 Draw the products formed when...Ch. 12.5 - Prob. 9P Ch. 12.5 - Prob. 10P

Ch. 12.5 - Problem 12.11 (a) Draw the structure of a compound...Ch. 12.5 - Prob. 12P Ch. 12.5 - Prob. 13P Ch. 12.6 - Problem 12.14 Draw the products of each...Ch. 12.8 - Prob. 15P Ch. 12.8 - Problem 12.16 Draw all stereoisomers formed when...Ch. 12.9 - Prob. 17P Ch. 12.9 - Problem 12.18 Draw the products formed when both...Ch. 12.10 - Problem 12.19 Draw the products formed when each...Ch. 12.10 - Prob. 20P Ch. 12.10 - Prob. 21P Ch. 12.11 - Problem 12.22 Draw the products formed when each...Ch. 12.11 - Prob. 23P Ch. 12.12 - Problem 12.24 Draw the organic products in each of...Ch. 12.13 - Prob. 25P Ch. 12 - 12.29 Draw the products formed when A is treated...Ch. 12 - Prob. 30P Ch. 12 - Prob. 31P Ch. 12 - Prob. 32P Ch. 12 - Prob. 33P Ch. 12 - Draw the organic products formed when cyclopentene...Ch. 12 - Draw the organic products formed when allylic...Ch. 12 - Prob. 39P Ch. 12 - Prob. 40P Ch. 12 - Prob. 41P Ch. 12 - What alkene is needed to synthesize each 1,2-diol...Ch. 12 - 12.48 Draw the products formed in each oxidative...Ch. 12 - What alkene or alkyne yields each set of products...Ch. 12 - Prob. 47P Ch. 12 - Prob. 48P Ch. 12 - Prob. 49P Ch. 12 - Prob. 50P Ch. 12 - 12.57 Draw the product of each asymmetric...Ch. 12 - 12.60 Identify A in the following reaction...Ch. 12 - Prob. 58P Ch. 12 - 12.62 It is sometimes necessary to isomerize a cis...Ch. 12 - 12.63 Devise a synthesis of each compound from...Ch. 12 - Prob. 61P

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