LL ORG CHEM
6th Edition
ISBN: 9781264840083
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 12, Problem 54P
Draw the product of each asymmetric
a. 
b. 
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A pdf file of your hand drawn, stepwise mechanisms for the reactions.
For each reaction in the assignment, you must write each mechanism
three times (there are 10 reactions, so 30 mechanisms). (A) do the work
on a tablet and save as a pdf., it is expected to write each mechanism
out and NOT copy and paste the mechanism after writing it just once.
Everything should be drawn out stepwise and every bond that is formed
and broken in the process of the reaction, and is expected to see all
relevant lone pair electrons and curved arrows.
Aldol:
NaOH
HO
H
Δ
NaOH
Δ
None
Draw structures corresponding to the following names and give IUPAC names for the
following compounds: (8 Point)
a)
b)
c)
CH3
CH2CH3
CH3CHCH2CH2CH
CH3
C=C
H3C
H
H2C=C=CHCH3
d)
CI
e) (3E,5Z)-2,6-Dimethyl-1,3,5,7-octatetraene
f) (Z)-4-bromo-3-methyl-3-penten-1-yne
g) cis-1-Bromo-2-ethylcyclopentane
h) (5R)-4,4,5-trichloro-3,3-dimethyldecane
Chapter 12 Solutions
LL ORG CHEM
Ch. 12.1 - Prob. 1PCh. 12.3 - Problem 12.2 What alkane is formed when each...Ch. 12.3 - Prob. 3PCh. 12.3 - Prob. 4PCh. 12.3 - Prob. 5PCh. 12.3 - Prob. 6PCh. 12.3 - Compound Molecular formula before...Ch. 12.4 - Problem 12.8 Draw the products formed when...Ch. 12.5 - Prob. 9PCh. 12.5 - Prob. 10P
Ch. 12.5 - Problem 12.11 (a) Draw the structure of a compound...Ch. 12.5 - Prob. 12PCh. 12.5 - Prob. 13PCh. 12.6 - Problem 12.14 Draw the products of each...Ch. 12.8 - Prob. 15PCh. 12.8 - Problem 12.16 Draw all stereoisomers formed when...Ch. 12.9 - Prob. 17PCh. 12.9 - Problem 12.18 Draw the products formed when both...Ch. 12.10 - Problem 12.19 Draw the products formed when each...Ch. 12.10 - Prob. 20PCh. 12.10 - Prob. 21PCh. 12.11 - Problem 12.22 Draw the products formed when each...Ch. 12.11 - Prob. 23PCh. 12.12 - Problem 12.24 Draw the organic products in each of...Ch. 12.13 - Prob. 25PCh. 12 - 12.29 Draw the products formed when A is treated...Ch. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Draw the organic products formed when cyclopentene...Ch. 12 - Draw the organic products formed when allylic...Ch. 12 - Prob. 39PCh. 12 - Prob. 40PCh. 12 - Prob. 41PCh. 12 - What alkene is needed to synthesize each 1,2-diol...Ch. 12 - 12.48 Draw the products formed in each oxidative...Ch. 12 - What alkene or alkyne yields each set of products...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Prob. 50PCh. 12 - 12.57 Draw the product of each asymmetric...Ch. 12 - 12.60 Identify A in the following reaction...Ch. 12 - Prob. 58PCh. 12 - 12.62 It is sometimes necessary to isomerize a cis...Ch. 12 - 12.63 Devise a synthesis of each compound from...Ch. 12 - Prob. 61P
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