The successive half-lives and the initial concentration of a reaction is given. By using these values, the concentration of A is to be calculated for each given time. Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. To determine : The concentration of A at 80 .0 min .

Question

Part 1. Aqueous 0.010M AgNO 3 is slowly added to a 50-ml solution containing both carbonate [co32-] = 0.105 M and sulfate [soy] = 0.164 M anions. Given the ksp of Ag2CO3 and Ag₂ soy below. Answer the ff: Ag₂ CO3 = 2 Ag+ caq) + co} (aq) ksp = 8.10 × 10-12 Ag₂SO4 = 2Ag+(aq) + soy² (aq) ksp = 1.20 × 10-5 a) which salt will precipitate first? (b) What % of the first anion precipitated will remain in the solution. by the time the second anion starts to precipitate? (c) What is the effect of low pH (more acidic) condition on the separate of the carbonate and sulfate anions via silver precipitation? What is the effect of high pH (more basic)? Provide appropriate explanation per answer

Answer 1

Question

Chapter 12, Problem 55E

(a)

Interpretation Introduction

Interpretation: The successive half-lives and the initial concentration of a reaction is given. By using these values, the concentration of A is to be calculated for each given time.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.

To determine: The concentration of A at 80.0 min .

(b)

Interpretation Introduction

Interpretation: The successive half-lives and the initial concentration of a reaction is given. By using these values, the concentration of A is to be calculated for each given time.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations.

To determine: The concentration of A at 30.0 min .

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