CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
8th Edition
ISBN: 2818440043505
Author: Bruice
Publisher: PEARSON
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Chapter 12, Problem 50P
Explain why the rate of bromination of methane decreases if HBr is added to the reaction mixture.
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Determine the entropy change for the reaction SO2(g) + O2(g)
following information:
Standard Entropy Values of Various Substance
Substance
SO2(g)
02(g)
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So (J/mol K)
248.2
205.0
256.8
→ SO3(g) given the
Indicate which one of the following reactions most certainly results in a negative AS sys.
O1402(g) + 3NH4NO3 (s) + C10 H22(1) → 3N2(g) + 17H2O(g) + 10CO2(g)
○
CO2(aq) = CO2(g)
○ H₂O(g) = H₂O(s)
CaCO3(g) = CaO(s) + CO2(g)
O CuSO4.5H2O(s) = CuSO4(s) + 5H2O(g)
Estimate the DH°rxn of the reaction below:
H
H-C-C=C-H
H
Н
A table of bond energy
Bond
H
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(kJ/mol)
C-H
413
C-O
360
C=O
743
C-C
348
|C = C
612
O-H
463
H-H
436
+
H-H
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H
H-C.
-
H
| | 1
HHH
Chapter 12 Solutions
CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
Ch. 12.2 - Prob. 1PCh. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3PCh. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6PCh. 12.5 - Prob. 8PCh. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12PCh. 12.7 - Prob. 13P
Ch. 12.7 - Prob. 14PCh. 12.8 - Prob. 15PCh. 12.8 - Draw the stereoisomers of the major...Ch. 12.9 - Prob. 18PCh. 12.9 - How many allylic substituted bromoalkenes are...Ch. 12.9 - a. How many stereoisomers are formed from the...Ch. 12.9 - Prob. 21PCh. 12.9 - Prob. 22PCh. 12.10 - Prob. 23PCh. 12.11 - How many atoms share the unpaired electrons in...Ch. 12.11 - Prob. 25PCh. 12 - Prob. 26PCh. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - a. What five-carbon alkene forms the same product...Ch. 12 - Prob. 39PCh. 12 - Starting with cyclohexane, how could the following...Ch. 12 - a. Propose a mechanism for the following reaction:...Ch. 12 - What stereoisomers are obtained from the following...Ch. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Draw the products of the following reactions,...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Explain why the rate of bromination of methane...Ch. 12 - Prob. 51PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
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