CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY
8th Edition
ISBN: 2818440043505
Author: Bruice
Publisher: PEARSON
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Chapter 12, Problem 3P

(a)

Interpretation Introduction

Interpretation:

The curved arrow pattern should be drawn for the given reaction showing the movement of electrons for bond making and bond breaking.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

(b)

Interpretation Introduction

Interpretation:

The curved arrow pattern should be drawn for the given reaction showing the movement of electrons for bond making and bond breaking.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

(c)

Interpretation Introduction

Interpretation:

The curved arrow pattern should be drawn for the given reaction showing the movement of electrons for bond making and bond breaking.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

(d)

Interpretation Introduction

Interpretation:

The curved arrow pattern should be drawn for the given reaction showing the movement of electrons for bond making and bond breaking.

Concept introduction:

Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.

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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. OH HO CI Br H CI CI Br CI CI Xf x f g Br D OH Br Br H₂N R. IN Ill I -N S OMe D II H CO₂H 1/111 DuckDuckG
These are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material! ? H H
Q5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship between each pair of the stereoisomers you have drawn.

Chapter 12 Solutions

CHEM 262 ORG CHEM EBOOK DIGITAL DELIVERY

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