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Concept explainers
(a)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using
(b)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
(c)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
(d)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Oxidation Reaction: The Dess-Martin Periodinane (DMP), a hyper valent iodine compound, offers selective and very mild oxidation of alcohols to
(e)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like
(f)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Alcohols treated with any metals or base which provides alkoxide.
(g)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Alcohols treated with any metals or base which provides alkoxide.
(h)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using
(i)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using
(j)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Alcohols treated with any metals or base which provides alkoxide.
(k)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Alcohols treated with any metals or base which provides alkoxide.
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Chapter 12 Solutions
ORGANIC CHEMISTRY: W/ACCESS
- Identify the missing organic reactants in the following reaction: X + Y H+ two steps Note: This chemical equation only focuses on the important organic molecules in the reaction. Additional inorganic or small-molecule reactants or products (like H2O) are not shown. In the drawing area below, draw the skeletal ("line") structures of the missing organic reactants X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. Х :arrow_forwardDraw the mechanism of friedel-crafts acylation using acetyl chloride of m-Xylenearrow_forwardI need help naming these in IUPACarrow_forward
- H R Part: 1/2 :CI: is a/an electrophile Part 2 of 2 Draw the skeletal structure of the product(s) for the Lewis acid-base reaction. Include lone pairs and formal charges (if applicable) on the structures. 4-7: H ö- H Skip Part Check X :C1: $ % L Fi Click and drag to start drawing a structure. MacBook Pro & ㅁ x G 0: P Add or increase positive formal cha Save For Later Submit ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centearrow_forwardDraw the friedel-crafts acylation mechanism of m-Xylenearrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- 1. Base on this experimental results, how do you know that the product which you are turning in is methyl 3-nitrobenzoate(meta substituted product ) rather than either of the other two products? 2. What observation suggests that at least a small amount of one or both of the other two isomers are in the mother liquor?arrow_forwardExplain Huckel's rule.arrow_forwardhere is my question can u help me please!arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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