ORGANIC CHEMISTRY: W/ACCESS
3rd Edition
ISBN: 9781119447719
Author: Klein
Publisher: WILEY
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Chapter 12, Problem 68IP
Interpretation Introduction
Interpretation:
The best reagents to perform this transformation has to be identified.
Concept introduction:
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides
Alcohols undergoing oxidation by using oxidizing agent like
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 12 Solutions
ORGANIC CHEMISTRY: W/ACCESS
Ch. 12.1 - Prob. 1LTSCh. 12.1 - PRACTICE the skill
Provide an IUPAC name for each...Ch. 12.1 - Safer alternatives to existing insecticides and...Ch. 12.1 - Prob. 3CCCh. 12.2 - Prob. 4CCCh. 12.2 - Prob. 2LTSCh. 12.2 - Prob. 5PTSCh. 12.2 - Flavonoids are a class of naturally occurring...Ch. 12.3 - Prob. 7CCCh. 12.3 - Prob. 8CC
Ch. 12.4 - Prob. 3LTSCh. 12.4 - Prob. 9PTSCh. 12.4 - Prob. 10ATSCh. 12.4 - Prob. 4LTSCh. 12.4 - Prob. 11PTSCh. 12.4 - Prob. 12ATSCh. 12.6 - Prob. 5LTSCh. 12.6 - Prob. 13PTSCh. 12.6 - Prob. 14PTSCh. 12.7 - Prob. 16CCCh. 12.9 - Prob. 6LTSCh. 12.9 - Prob. 17PTSCh. 12.9 - Prob. 18ATSCh. 12.9 - Prob. 19CCCh. 12.10 - Prob. 7LTSCh. 12.10 - PRACTICE the skill
Predict the major organic...Ch. 12.10 - Prob. 21ATSCh. 12.13 - Prob. 8LTSCh. 12.13 - Prob. 22PTSCh. 12.13 - Prob. 23ATSCh. 12.13 - Prob. 24CCCh. 12.13 - Prob. 9LTSCh. 12.13 - Prob. 25PTSCh. 12.13 - Prob. 26ATSCh. 12 - Prob. 27PPCh. 12 - Prob. 28PPCh. 12 - Prob. 29PPCh. 12 - Prob. 30PPCh. 12 - Prob. 31PPCh. 12 - Predict the major product of the reaction between...Ch. 12 - Prob. 33PPCh. 12 - Prob. 34PPCh. 12 - Using a Grignard reaction, show how you could...Ch. 12 - Each of the following alcohols can be prepared via...Ch. 12 - Prob. 37PPCh. 12 - Prob. 38PPCh. 12 - Prob. 39PPCh. 12 - Prob. 40PPCh. 12 - Prob. 41PPCh. 12 - Prob. 42PPCh. 12 - Prob. 43PPCh. 12 - Prob. 44PPCh. 12 - Prob. 45PPCh. 12 - Prob. 46PPCh. 12 - Prob. 47PPCh. 12 - Prob. 48PPCh. 12 - Prob. 49PPCh. 12 - Prob. 50PPCh. 12 - Prob. 51IPCh. 12 - Prob. 52IPCh. 12 - Prob. 53IPCh. 12 - Prob. 54IPCh. 12 - Prob. 55IPCh. 12 - Prob. 56IPCh. 12 - Prob. 57IPCh. 12 - Prob. 58IPCh. 12 - Prob. 59IPCh. 12 - Prob. 60IPCh. 12 - Prob. 61IPCh. 12 - Prob. 62IPCh. 12 - Prob. 63IPCh. 12 - Prob. 64IPCh. 12 - Prob. 65IPCh. 12 - The compound duryne was one of several...Ch. 12 - Estragole is an insect repellant that has been...Ch. 12 - Prob. 68IPCh. 12 - Prob. 70IPCh. 12 - Prob. 71IPCh. 12 - Prob. 72IPCh. 12 - Prob. 73IPCh. 12 - Prob. 74IPCh. 12 - Prob. 75CPCh. 12 - Prob. 76CPCh. 12 - Prob. 77CP
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- 2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); Reagents: H₂O (B); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI OH - α-α Br + enant Solvent Reagent(s) Solvent Reagent(s)arrow_forwardBased on concepts from Lecture 3-5, which of the following ionic compounds should be most soluble in water? Group of answer choices MgO BeO CaO BaOarrow_forwardFrom an energy standpoint, which two process - in the correct order - are involved in the dissolving of an ionic compound crystal? Group of answer choices Water coordination to the ions followed by sublimation into the gas phase Sublimation of the crystal into gas-phase ions followed by water coordination to the ions Ion dissociation from the crystal followed by water coordination to the ions Water coordination to the ions followed by ion dissociation from the crystalarrow_forward
- For which Group 2 metal (M), is this process the most exothermic? M2+(g) + O2−(g) + CO2(g) → MO(s) + CO2(g) Group of answer choices M = Sr M = Mg M = Ca M = Baarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); R₂BH (6); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI Solvent Reagent(s) Solvent Reagent(s) HO OHarrow_forwardFor which of the following ionic compounds would you expect the smallest difference between its theoretical and experimental lattice enthalpies? (You may assume these all have the same unit cell structure.) Electronegativities: Ca (1.0), Fe (1.8), Mg (1.2), O (3.5), S (2.5), Zn (1.6) Group of answer choices ZnO MgS CaO FeSarrow_forward
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