ORGANIC CHEMISTRY W/ALEKS
ORGANIC CHEMISTRY W/ALEKS
6th Edition
ISBN: 9781264905430
Author: SMITH
Publisher: MCG CUSTOM
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Chapter 12, Problem 31P
Interpretation Introduction

(a)

Interpretation: The organic product formed when the given alkene is treated with H2,Pd-C is to be drawn. The three dimensional structure of all the stereoisomers is to be indicated.

Concept introduction: The addition of H2 in presence of catalyst is known as catalytic hydrogenation reaction. This is a syn addition. Alkene is reduced to alkane. In this reaction weak pi bond of alkene and sigma bond between H2 is broken and two CH bonds are formed.

Interpretation Introduction

(b)

Interpretation: The organic product formed when the given alkene is treated with H2,Pd-C is to be drawn. The three dimensional structure of all the stereoisomers is to be indicated.

Concept introduction: The addition of H2 in presence of catalyst is known as catalytic hydrogenation reaction. This is a syn addition. Alkene is reduced to alkane. In this reaction weak pi bond of alkene and sigma bond between H2 is broken and two CH bonds are formed.

Interpretation Introduction

(c)

Interpretation: The organic product formed when the given alkene is treated with H2,Pd-C is to be drawn. And the three dimensional structure of all the stereoisomers is to be indicated.

Concept introduction: The addition of H2 in presence of catalyst is known as catalytic hydrogenation reaction. This is a syn addition. Alkene is reduced to alkane. In this reaction weak pi bond of alkene and sigma bond between H2 is broken and two CH bonds are formed.

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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.
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ORGANIC CHEMISTRY W/ALEKS

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