Oxidation products for each of the given reactions are to be determined. Concept introduction: Swern oxidation converts primary and secondary alcohols into aldehydes and ketones , respectively. The catalyst used is DMSO (dimethyl sulfoxide) and oxalyl chloride in triethylamine (organic base). When oxidation takes place, the hydrogen atom attached to the oxygen atom is removed to form aldehydes from alcohols or form carboxylic acids from aldehydes. Compounds with no hydrogen attached to oxygen cannot be oxidized using Swern oxidation. Examples of such compounds are tertiary alcohols and ethers.

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12, Problem 2PP

Interpretation Introduction

Interpretation:

Oxidation products for each of the given reactions are to be determined.

Concept introduction:

Swern oxidation converts primary and secondary alcohols into aldehydes and ketones, respectively. The catalyst used is DMSO (dimethyl sulfoxide) and oxalyl chloride in triethylamine (organic base).

When oxidation takes place, the hydrogen atom attached to the oxygen atom is removed to form aldehydes from alcohols or form carboxylic acids from aldehydes. Compounds with no hydrogen attached to oxygen cannot be oxidized using Swern oxidation. Examples of such compounds are tertiary alcohols and ethers.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12, Problem 2PP

Interpretation Introduction

Interpretation:

Oxidation products for each of the given reactions are to be determined.

Concept introduction:

Swern oxidation converts primary and secondary alcohols into aldehydes and ketones, respectively. The catalyst used is DMSO (dimethyl sulfoxide) and oxalyl chloride in triethylamine (organic base).

When oxidation takes place, the hydrogen atom attached to the oxygen atom is removed to form aldehydes from alcohols or form carboxylic acids from aldehydes. Compounds with no hydrogen attached to oxygen cannot be oxidized using Swern oxidation. Examples of such compounds are tertiary alcohols and ethers.

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Answer 3

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12, Problem 2PP

Interpretation Introduction

Interpretation:

Oxidation products for each of the given reactions are to be determined.

Concept introduction:

Swern oxidation converts primary and secondary alcohols into aldehydes and ketones, respectively. The catalyst used is DMSO (dimethyl sulfoxide) and oxalyl chloride in triethylamine (organic base).

When oxidation takes place, the hydrogen atom attached to the oxygen atom is removed to form aldehydes from alcohols or form carboxylic acids from aldehydes. Compounds with no hydrogen attached to oxygen cannot be oxidized using Swern oxidation. Examples of such compounds are tertiary alcohols and ethers.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12, Problem 2PP

Interpretation Introduction