Oxidation products for each of the given reactions are to be determined. Concept introduction: Swern oxidation converts primary and secondary alcohols into aldehydes and ketones , respectively. The catalyst used is DMSO (dimethyl sulfoxide) and oxalyl chloride in triethylamine (organic base). When oxidation takes place, the hydrogen atom attached to the oxygen atom is removed to form aldehydes from alcohols or form carboxylic acids from aldehydes. Compounds with no hydrogen attached to oxygen cannot be oxidized using Swern oxidation. Examples of such compounds are tertiary alcohols and ethers.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12, Problem 2PP

Interpretation Introduction

Interpretation:

Oxidation products for each of the given reactions are to be determined.

Concept introduction:

Swern oxidation converts primary and secondary alcohols into aldehydes and ketones, respectively. The catalyst used is DMSO (dimethyl sulfoxide) and oxalyl chloride in triethylamine (organic base).

When oxidation takes place, the hydrogen atom attached to the oxygen atom is removed to form aldehydes from alcohols or form carboxylic acids from aldehydes. Compounds with no hydrogen attached to oxygen cannot be oxidized using Swern oxidation. Examples of such compounds are tertiary alcohols and ethers.

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How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom molecule

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Answer 2

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12, Problem 2PP

Interpretation Introduction

Interpretation:

Oxidation products for each of the given reactions are to be determined.

Concept introduction:

Swern oxidation converts primary and secondary alcohols into aldehydes and ketones, respectively. The catalyst used is DMSO (dimethyl sulfoxide) and oxalyl chloride in triethylamine (organic base).

When oxidation takes place, the hydrogen atom attached to the oxygen atom is removed to form aldehydes from alcohols or form carboxylic acids from aldehydes. Compounds with no hydrogen attached to oxygen cannot be oxidized using Swern oxidation. Examples of such compounds are tertiary alcohols and ethers.

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Answer 3

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12, Problem 2PP

Interpretation Introduction

Interpretation:

Oxidation products for each of the given reactions are to be determined.

Concept introduction:

Swern oxidation converts primary and secondary alcohols into aldehydes and ketones, respectively. The catalyst used is DMSO (dimethyl sulfoxide) and oxalyl chloride in triethylamine (organic base).

When oxidation takes place, the hydrogen atom attached to the oxygen atom is removed to form aldehydes from alcohols or form carboxylic acids from aldehydes. Compounds with no hydrogen attached to oxygen cannot be oxidized using Swern oxidation. Examples of such compounds are tertiary alcohols and ethers.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 12, Problem 2PP

Interpretation Introduction