Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 12, Problem 27E
Interpretation Introduction
To determine:
The separation between layers of atoms in the crystal.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
An X-ray beam with l = 154 pm incident on the surface of a crystal produced a maximum reflection at an angle of u = 28.3°. Assuming n = 1, calculate the separation between layers of atoms in the crystal.
A crystal was analyzed with x-rays having 1.57 Å wavelength. A reflection was produced at θ = 21.9°. Assuming n = 1, what is the distance (in cm) between the layers of atoms in the crystal?
When an X-ray beam of l = 154 pm is incident on the surface of an iron crystal, it produces a maximum diffraction at an angle of u = 32.6°. Assuming n = 1, calculate the separation between layers of iron atoms in the crystal.
Chapter 12 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 12 - What is graphene? Why is graphene unique?Ch. 12 - Prob. 2ECh. 12 - What is a crystalline lattice? How is the lattice...Ch. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - What is the difference between hexagonal closest...Ch. 12 - What are the three basic types of solids and the...Ch. 12 - Prob. 8ECh. 12 - What kinds of forces hold each of the three basic...Ch. 12 - Prob. 10E
Ch. 12 - In an ionic compound, how are the relative sizes...Ch. 12 - Prob. 12ECh. 12 - Show how the fluorite structure accommodates a...Ch. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Describe the difference between vitreous silica...Ch. 12 - Prob. 21ECh. 12 - Prob. 22ECh. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - What is a polymer? What is the difference between...Ch. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - An X-ray beam of unknown wavelength is diffracted...Ch. 12 - Prob. 29ECh. 12 - Determine the coordination number for each...Ch. 12 - Calculate the packing efficiency of the...Ch. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Molybdenum crystallizes with the body-centred unit...Ch. 12 - Rhodium has a density of 12.41 g / cm3 and...Ch. 12 - Barium has a density of 3.59 g/cm3 and...Ch. 12 - Prob. 37ECh. 12 - Palladium crystallizes with a face-centered cubic...Ch. 12 - Prob. 39ECh. 12 - Identify each solid as molecular, ionic, or...Ch. 12 - Which solid has the highest melting point? Why?...Ch. 12 - Which solid has the highest melting point? Why?...Ch. 12 - Which solid in each pair has the higher melting...Ch. 12 - Which solid in each pair has the higher melting...Ch. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - The unit cells for cesium chloride and barium(ll)...Ch. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Consider the zinc blende structure in Figure 12.14...Ch. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - What are the name and formula of the compound...Ch. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - How many molecular orbitals are present in the...Ch. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Saran, the polymer used to make saran wrap, is an...Ch. 12 - One kind of polyester is a condensation copolymer...Ch. 12 - Nomex, a condensation copolymer used by...Ch. 12 - Prob. 73ECh. 12 - Polyacrylonitrile (PAN) is an addition polymer...Ch. 12 - Prob. 75ECh. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - Prob. 80ECh. 12 - Prob. 81ECh. 12 - The density of an unknown metal is 12.3 g/cm3 and...Ch. 12 - An unknown metal is found to have a density of...Ch. 12 - Prob. 84ECh. 12 - Prob. 85ECh. 12 - Prob. 86ECh. 12 - Prob. 87ECh. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Perovskite is a compound with a cubic unit cell...Ch. 12 - Prob. 93ECh. 12 - Despite Dalton's laws, it is now known that many...Ch. 12 - During the glass manufacturing process, the liquid...Ch. 12 - Why are X-rays used for crystallography? Why not...Ch. 12 - Compare the crystal structure of diamond (C) and...Ch. 12 - Prob. 98ECh. 12 - Prob. 99ECh. 12 - Have each group member select one of the cubic...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - Prob. 103ECh. 12 - Prob. 104ECh. 12 - Prob. 105ECh. 12 - Prob. 1SAQCh. 12 - A crystalline solid has a body-centered cubic...Ch. 12 - Prob. 3SAQCh. 12 - Prob. 4SAQCh. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Prob. 7SAQCh. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQCh. 12 - Prob. 11SAQCh. 12 - Prob. 12SAQCh. 12 - Prob. 13SAQCh. 12 - Prob. 14SAQCh. 12 - Prob. 15SAQ
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 8.98 If you know the density of material and the length of the edge of its cubic Iattice, how would you determine if it is face-centered cubic, body-centered cubic, or simple cubic Would you have to look up any information?arrow_forwardThe density of polonium metal is 9.2 g/cm3. If the extended lattice of polonium exhibits a simple cubic unit cell, estimate the atomic radius of polonium.arrow_forwardWhat is the spacing between crystal planes that diffract X-rays with a wavelength of 1.541 nm at an angle of 15.55 (first order reflection)?arrow_forward
- The density of tantalum at 20oC is 16.69 g/cm3 and its unit cell is cubic. Given that the first five observed Bragg diffraction angles are θ =19.31o, 27.88o, 34.95o, 41.41o and 47.69o, find the type of unit cell and its length. Take the wavelength of the x-ray radiation to be λ =154.433 pm.arrow_forwardWhen analyzed with X-ray diffraction, a crystal produces a reflection at θ = 25.0°. Calculate the distance between the layers of atoms in the crystal if n = 2. The wavelength of X rays is 3.34 Åarrow_forwardA first-order (n = 1) reflection from the plane of a cubic crystal was observed at a glancing angle of 11.2° when Cu Ka X-rays (λ = 154 pm) were used. What is the interatomic distance between the atoms in the unit cell in pm?arrow_forward
- Elemental silver reflects X-rays of wavelength 154.18 pm at angles of 19.076°, 22.171°, and 32.256°. However, there are no other reflections at angles of less than 33°. Assuming a cubic unit cell, determine its type and dimension. Calculate the mass density of silver. Hint: Calculate the expected reflections from different types of cubic unit cell and compare those with the data given.arrow_forwardThe surface energy of a single crystal depends on crystallographic orientation. Does this surface energy increase or decrease with an increase in planar density? Why?arrow_forwardIn the early days of X-ray crystallography there was an urgent need to know the wavelengths of X-rays. One technique was to measure the diffraction angle from a mechanically ruled grating. Another method was to estimate the separation of lattice planes from the measured density of a crystal. The mass density of NaCl is 2.17 g cm−3 and the (100) reflection using radiation of a certain wavelength occurred at 6.0°. Calculate the wavelength of the X-rays.arrow_forward
- Calculate the first-order (n=1) Bragg diffraction angle for 110.0 pm X-rays passing through a crystalline lattice having a spacing between adjacent molecular layers of 189.0 pm.arrow_forwardThe second-order Bragg diffraction of X-rays with l= 1.660 Å from a set of parallel planes in copper occurs at an angle 2Q = 54.70°. Calculate the distance between the scattering planes in the crystal.arrow_forwardplatinum crystallizes in a FCC lattice with all atoms at the lattice points It has a density 1338.905 lb/ft^3 and an atomic weight of 0.195108 kg/mol. From these data , calculate the length of a unit cell edge . Compare this with the value of 392.4 pm obtained from x - ray diffraction .arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningPrinciples of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co