Introduction to Chemistry
4th Edition
ISBN: 9781259288722
Author: BAUER
Publisher: MCG
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Chapter 12, Problem 19QP
Interpretation Introduction
Interpretation:
The energy diagram that shows the relative energies of the reactants, products, and the activated complex is to be drawn for the given reaction.
Concept Introduction:
Energy diagrams are diagrams, which show the potential energies of the reactants, transition state, and products as reaction proceeds with time.
For an exothermic reaction, the reactants are drawn above the products because their energy is greater. For an endothermic reaction, the reactants are drawn below the products.
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Consider this step in a radical reaction:
Y
What type of step is this? Check all that apply.
Draw the products of the step on the right-hand side of the drawing area
below. If more than one set of products is possible, draw any set.
Also, draw the mechanism arrows on the left-hand side of the drawing
area to show how this happens.
ionization
propagation
initialization
passivation
none of the above
22.16 The following groups are ortho-para directors.
(a)
-C=CH₂
H
(d)
-Br
(b)
-NH2
(c)
-OCHS
Draw a contributing structure for the resonance-stabilized cation formed during elec-
trophilic aromatic substitution that shows the role of each group in stabilizing the
intermediate by further delocalizing its positive charge.
22.17 Predict the major product or products from treatment of each compound with
Cl₁/FeCl₂-
OH
(b)
NO2
CHO
22.18 How do you account for the fact that phenyl acetate is less reactive toward electro-
philic aromatic substitution than anisole?
Phenyl acetate
Anisole
CH
(d)
Chapter 12 Solutions
Introduction to Chemistry
Ch. 12 - Prob. 1QCCh. 12 - Prob. 2QCCh. 12 - Prob. 3QCCh. 12 - Prob. 4QCCh. 12 - Prob. 5QCCh. 12 - Prob. 6QCCh. 12 - Prob. 1PPCh. 12 - Prob. 2PPCh. 12 - Prob. 3PPCh. 12 - Prob. 4PP
Ch. 12 - Prob. 5PPCh. 12 - Prob. 6PPCh. 12 - Prob. 7PPCh. 12 - Prob. 8PPCh. 12 - Prob. 9PPCh. 12 - Prob. 10PPCh. 12 - Consider the following equilibrium:...Ch. 12 - Prob. 12PPCh. 12 - Prob. 1QPCh. 12 - Match the key terms with the descriptions...Ch. 12 - Prob. 3QPCh. 12 - Prob. 4QPCh. 12 - Prob. 5QPCh. 12 - Prob. 6QPCh. 12 - Prob. 7QPCh. 12 - Prob. 8QPCh. 12 - Prob. 9QPCh. 12 - Prob. 10QPCh. 12 - Prob. 11QPCh. 12 - Prob. 12QPCh. 12 - Prob. 13QPCh. 12 - Prob. 14QPCh. 12 - Prob. 15QPCh. 12 - Prob. 16QPCh. 12 - Prob. 17QPCh. 12 - Prob. 18QPCh. 12 - Prob. 19QPCh. 12 - Prob. 20QPCh. 12 - Prob. 21QPCh. 12 - Prob. 22QPCh. 12 - Prob. 23QPCh. 12 - Prob. 24QPCh. 12 - Prob. 25QPCh. 12 - Prob. 26QPCh. 12 - Prob. 27QPCh. 12 - Prob. 28QPCh. 12 - Prob. 29QPCh. 12 - Prob. 30QPCh. 12 - Prob. 31QPCh. 12 - Prob. 32QPCh. 12 - Prob. 33QPCh. 12 - Prob. 34QPCh. 12 - Prob. 35QPCh. 12 - Prob. 36QPCh. 12 - Prob. 37QPCh. 12 - Prob. 38QPCh. 12 - Prob. 39QPCh. 12 - Prob. 40QPCh. 12 - Prob. 41QPCh. 12 - Prob. 42QPCh. 12 - Prob. 43QPCh. 12 - Prob. 44QPCh. 12 - Prob. 45QPCh. 12 - Prob. 46QPCh. 12 - Prob. 47QPCh. 12 - Prob. 48QPCh. 12 - Prob. 49QPCh. 12 - Prob. 50QPCh. 12 - Prob. 51QPCh. 12 - Prob. 52QPCh. 12 - Prob. 53QPCh. 12 - Prob. 54QPCh. 12 - Prob. 55QPCh. 12 - Prob. 56QPCh. 12 - Prob. 57QPCh. 12 - Prob. 58QPCh. 12 - Prob. 59QPCh. 12 - Prob. 60QPCh. 12 - Prob. 61QPCh. 12 - Prob. 62QPCh. 12 - Prob. 63QPCh. 12 - Prob. 64QPCh. 12 - Prob. 65QPCh. 12 - Prob. 66QPCh. 12 - Prob. 67QPCh. 12 - Prob. 68QPCh. 12 - Prob. 69QPCh. 12 - Prob. 70QPCh. 12 - Prob. 71QPCh. 12 - Prob. 72QPCh. 12 - Prob. 73QPCh. 12 - Prob. 74QPCh. 12 - Prob. 75QPCh. 12 - Prob. 76QPCh. 12 - Prob. 77QPCh. 12 - Prob. 78QPCh. 12 - Prob. 79QPCh. 12 - Prob. 80QPCh. 12 - Prob. 81QPCh. 12 - Prob. 82QPCh. 12 - Prob. 83QPCh. 12 - Prob. 84QPCh. 12 - Prob. 85QPCh. 12 - Prob. 86QPCh. 12 - Prob. 87QPCh. 12 - Prob. 88QPCh. 12 - Prob. 89QPCh. 12 - Prob. 90QPCh. 12 - Prob. 91QPCh. 12 - Prob. 92QPCh. 12 - Prob. 93QPCh. 12 - Prob. 94QPCh. 12 - Prob. 95QPCh. 12 - Prob. 96QPCh. 12 - Prob. 97QPCh. 12 - Prob. 98QPCh. 12 - Prob. 99QPCh. 12 - Prob. 100QPCh. 12 - Prob. 101QPCh. 12 - Prob. 102QPCh. 12 - Prob. 103QPCh. 12 - Prob. 104QPCh. 12 - Prob. 105QPCh. 12 - Prob. 106QPCh. 12 - Prob. 107QPCh. 12 - Prob. 108QPCh. 12 - Prob. 109QPCh. 12 - Prob. 110QPCh. 12 - Prob. 111QPCh. 12 - Prob. 112QPCh. 12 - Prob. 113QPCh. 12 - Prob. 114QPCh. 12 - Prob. 115QPCh. 12 - Prob. 116QPCh. 12 - Prob. 117QPCh. 12 - Prob. 118QPCh. 12 - Prob. 119QPCh. 12 - Prob. 120QPCh. 12 - Prob. 121QPCh. 12 - Prob. 122QPCh. 12 - Prob. 123QPCh. 12 - Prob. 124QPCh. 12 - Prob. 125QPCh. 12 - Prob. 126QPCh. 12 - Prob. 127QPCh. 12 - Prob. 128QPCh. 12 - Prob. 129QPCh. 12 - Prob. 130QPCh. 12 - Prob. 131QPCh. 12 - Prob. 132QPCh. 12 - Prob. 133QPCh. 12 - Prob. 134QPCh. 12 - Prob. 135QPCh. 12 - Prob. 136QPCh. 12 - Prob. 137QPCh. 12 - Prob. 138QPCh. 12 - Prob. 139QPCh. 12 - Prob. 140QPCh. 12 - Prob. 141QPCh. 12 - Prob. 142QPCh. 12 - Prob. 143QP
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