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(a)
Interpretation:
On increasing the concentration of the reactant, the average energy of collision increases or not is to be identified.
(b)
Interpretation:
On increasing the concentration of reactant, the collision frequency increases or not is to be identified.
(c)
Interpretation:
On increasing the concentration of reactant, the fraction of collisions with proper molecular orientation increases or not is to be identified.
Explanation:
With an increase in the concentration of reactant, the number of molecules colliding increases and the space between these molecules decreases. Hence, the possibility of molecules colliding increases, which leads to an increase in the collision frequency. However, there is no increase in the fraction of molecules with proper orientation because there is no increase in the kinetic energy or temperature.
(d)
Interpretation:
On increasing the concentration of reactant, the fraction of collision with sufficient energy increases or not is to be identified.
Explanation:
With an increase in the concentration of reactant, the number of molecules colliding increases and the space between these molecules decreases. Hence, the possibility of molecules colliding increases. As the collision increases, the energy of molecules increases and molecules start colliding with sufficient energy to overcome the activation energy.
(e)
Interpretation:
On increasing the concentration of reactant, the reaction rate increases or not is to be identified.
Explanation:
With an increase in the concentration of reactant, the number of molecules colliding increases and the space between these molecules decreases. Hence, the possibility of molecules colliding increases. As the collision increases, the energy of molecules increases and molecules start colliding with sufficient energy to overcome the activation energy and more reactants get converted into products. This leads to an increase in the
(d)
Interpretation:
On increasing the concentration of reactant, the fraction of collision with sufficient energy increases or not is to be identified.
(e)
Interpretation:
On increasing the concentration of reactant, the reaction rate increases or not is to be identified.
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Chapter 12 Solutions
Introduction to Chemistry
- Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. OH HO CI Br H CI CI Br CI CI Xf x f g Br D OH Br Br H₂N R. IN Ill I -N S OMe D II H CO₂H 1/111 DuckDuckGarrow_forwardThese are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material! ? H Harrow_forwardQ5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship between each pair of the stereoisomers you have drawn.arrow_forward
- Classify each pair of molecules according to whether or not they can participate in hydrogen bonding with one another. Participate in hydrogen bonding CH3COCH3 and CH3COCH2CH3 H2O and (CH3CH2)2CO CH3COCH3 and CH₂ CHO Answer Bank Do not participate in hydrogen bonding CH3CH2OH and HCHO CH3COCH2CH3 and CH3OHarrow_forwardNonearrow_forwardQ4: Comparing (3S,4S)-3,4-dimethylhexane and (3R,4S)-3,4-dimethylhexane, which one is optically active? Briefly explain.arrow_forward
- Nonearrow_forwardNonearrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 4A (g) + 2B (g) → 2C (g) + 7D (g) AHrxn =?kJ Substance AH in kJ/mol A (g) - 20.42 B (g) + 32.18 C (g) - 72.51 D (g) - 17.87arrow_forward
- Determine ASran for Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(aq) given the following information: Standard Entropy Values of Various Substance Substance So (J/mol • K) 60.9 Zn(s) HCl(aq) 56.5 130.58 H2(g) Zn2+(aq) -106.5 55.10 CI (aq)arrow_forward3) Catalytic hydrogenation of the compound below produced the expected product. However, a byproduct with molecular formula C10H12O is also formed in small quantities. What is the by product?arrow_forwardWhat is the ΔHorxn of the reaction? NaOH(aq) + HCl(aq) → H2O(l) + NaCl(aq) ΔHorxn 1= ________ kJ/molarrow_forward
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