BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
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Textbook Question
Chapter 12, Problem 14QP
Would each of these molecules be likely to form a liquid crystal? If not, why not?
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For a condensed binary system in equilibrium at constant pressure, indicate the maximum number of phases that can exist.
Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Consider the reaction of 2-methylpropane with a halogen. With which halogen will the product be almost exclusively 2-halo-2-methylpropane? 1. F2 2. Cl2 3. Br2 4. I2
Chapter 12 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 12.1 - Practice ProblemATTEMPT Saran Wrap, the original...Ch. 12.1 - Prob. 1PPBCh. 12.1 - Practice ProblemCONCEPTUALIZE Which diagram best...Ch. 12.1 - Prob. 1CPCh. 12.1 - Prob. 2CPCh. 12.2 - Prob. 1PPACh. 12.2 - Practice ProblemBUILD Kodel is a polymer used to...Ch. 12.2 - Prob. 1PPCCh. 12.3 - Prob. 1PPACh. 12.3 - Prob. 1PPB
Ch. 12.3 - Prob. 1PPCCh. 12.3 - Prob. 1CPCh. 12.3 - Prob. 2CPCh. 12.4 - Prob. 1PPACh. 12.4 - Prob. 1PPBCh. 12.4 - Prob. 1PPCCh. 12.5 - Prob. 1PPACh. 12.5 - Prob. 1PPBCh. 12.5 - Prob. 1PPCCh. 12.6 - Prob. 1CPCh. 12.6 - Prob. 2CPCh. 12 - 12.1 Bakelite, the first commercially produced...Ch. 12 - Prob. 2QPCh. 12 - Prob. 3QPCh. 12 - Prob. 4QPCh. 12 - Prob. 5QPCh. 12 - Prob. 6QPCh. 12 - Prob. 7QPCh. 12 - Prob. 8QPCh. 12 - Prob. 9QPCh. 12 - Prob. 10QPCh. 12 - Bakelite. described in Review Question 12.1, is...Ch. 12 - Is a normal liquid isotropic or anisotropic? How...Ch. 12 - Prob. 13QPCh. 12 - 12.14 Would each of these molecules be likely to...Ch. 12 - Prob. 15QPCh. 12 - 12.16 Would an ionic compound form a liquid...Ch. 12 - Prob. 17QPCh. 12 - Prob. 18QPCh. 12 - Prob. 19QPCh. 12 - 12.20 What are some advantages and disadvantages...Ch. 12 - Prob. 21QPCh. 12 - 12.22 How does an measure the peak and valley...Ch. 12 - Name four allotropic forms of carbon.Ch. 12 - Prob. 24QPCh. 12 - Prob. 25QPCh. 12 - Prob. 26QPCh. 12 - 12.27 What type of intermolecular forces holds the...Ch. 12 - Prob. 28QPCh. 12 - Prob. 29QPCh. 12 - Prob. 30QPCh. 12 - Prob. 31QPCh. 12 - Prob. 32QPCh. 12 - Prob. 33QPCh. 12 - Prob. 34QPCh. 12 - Prob. 35QPCh. 12 - Prob. 36QPCh. 12 - What types of bonding (covalent, ionic, network,...Ch. 12 - Draw representations of isotactic, syndiotactic....Ch. 12 - Prob. 39QPCh. 12 - Draw representations of block copolymers and graft...Ch. 12 - Prob. 41APCh. 12 - 12.42 Would the compound shown form a liquid...Ch. 12 - Prob. 43APCh. 12 - Prob. 44APCh. 12 - Fluoride ion is commonly used in drinking water...Ch. 12 - Prob. 1SEPPCh. 12 - Prob. 2SEPPCh. 12 - Prob. 3SEPPCh. 12 - Prob. 4SEPP
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- Part VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forwardPart VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward
- 3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward
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