BURDGE CHEMISTRY VALUE ED (LL)
4th Edition
ISBN: 9781259995958
Author: VALUE EDITION
Publisher: MCG CUSTOM
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 12.3, Problem 2CP
Interpretation Introduction
Interpretation:
The characteristics that make a molecule exhibit liquid crystal properties are to be selected.
Concept introduction:
The foremost requirement for a molecule to exhibit the properties of liquid crystals is its capability to align them in an ordered arrangement which, as a result, causes anisotropy.
The characteristics responsible for such an arrangement are structures with more length but less width, so that they can appear like rods.
Along with that rigidity, which can be due to pi bonds,
The rod-like shape and rigidity allow the molecules to align themselves in an ordered arrangement and hence result in anisotropy.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
In the phase diagram of steel (two components Fe and C), region A is the gamma austenite solid and region B contains the gamma solid and liquid. Indicate the degrees of freedom that the fields A and B have,
For a condensed binary system in equilibrium at constant pressure, indicate the maximum number of phases that can exist.
Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 12 Solutions
BURDGE CHEMISTRY VALUE ED (LL)
Ch. 12.1 - Practice ProblemATTEMPT Saran Wrap, the original...Ch. 12.1 - Prob. 1PPBCh. 12.1 - Practice ProblemCONCEPTUALIZE Which diagram best...Ch. 12.1 - Prob. 1CPCh. 12.1 - Prob. 2CPCh. 12.2 - Prob. 1PPACh. 12.2 - Practice ProblemBUILD Kodel is a polymer used to...Ch. 12.2 - Prob. 1PPCCh. 12.3 - Prob. 1PPACh. 12.3 - Prob. 1PPB
Ch. 12.3 - Prob. 1PPCCh. 12.3 - Prob. 1CPCh. 12.3 - Prob. 2CPCh. 12.4 - Prob. 1PPACh. 12.4 - Prob. 1PPBCh. 12.4 - Prob. 1PPCCh. 12.5 - Prob. 1PPACh. 12.5 - Prob. 1PPBCh. 12.5 - Prob. 1PPCCh. 12.6 - Prob. 1CPCh. 12.6 - Prob. 2CPCh. 12 - 12.1 Bakelite, the first commercially produced...Ch. 12 - Prob. 2QPCh. 12 - Prob. 3QPCh. 12 - Prob. 4QPCh. 12 - Prob. 5QPCh. 12 - Prob. 6QPCh. 12 - Prob. 7QPCh. 12 - Prob. 8QPCh. 12 - Prob. 9QPCh. 12 - Prob. 10QPCh. 12 - Bakelite. described in Review Question 12.1, is...Ch. 12 - Is a normal liquid isotropic or anisotropic? How...Ch. 12 - Prob. 13QPCh. 12 - 12.14 Would each of these molecules be likely to...Ch. 12 - Prob. 15QPCh. 12 - 12.16 Would an ionic compound form a liquid...Ch. 12 - Prob. 17QPCh. 12 - Prob. 18QPCh. 12 - Prob. 19QPCh. 12 - 12.20 What are some advantages and disadvantages...Ch. 12 - Prob. 21QPCh. 12 - 12.22 How does an measure the peak and valley...Ch. 12 - Name four allotropic forms of carbon.Ch. 12 - Prob. 24QPCh. 12 - Prob. 25QPCh. 12 - Prob. 26QPCh. 12 - 12.27 What type of intermolecular forces holds the...Ch. 12 - Prob. 28QPCh. 12 - Prob. 29QPCh. 12 - Prob. 30QPCh. 12 - Prob. 31QPCh. 12 - Prob. 32QPCh. 12 - Prob. 33QPCh. 12 - Prob. 34QPCh. 12 - Prob. 35QPCh. 12 - Prob. 36QPCh. 12 - What types of bonding (covalent, ionic, network,...Ch. 12 - Draw representations of isotactic, syndiotactic....Ch. 12 - Prob. 39QPCh. 12 - Draw representations of block copolymers and graft...Ch. 12 - Prob. 41APCh. 12 - 12.42 Would the compound shown form a liquid...Ch. 12 - Prob. 43APCh. 12 - Prob. 44APCh. 12 - Fluoride ion is commonly used in drinking water...Ch. 12 - Prob. 1SEPPCh. 12 - Prob. 2SEPPCh. 12 - Prob. 3SEPPCh. 12 - Prob. 4SEPP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
- 13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forwardPart III. Arrange the following carbons (in blue) in order of increasing chemical shift. HO B NH 2 A CIarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Living By Chemistry: First Edition TextbookChemistryISBN:9781559539418Author:Angelica StacyPublisher:MAC HIGHER
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Living By Chemistry: First Edition Textbook
Chemistry
ISBN:9781559539418
Author:Angelica Stacy
Publisher:MAC HIGHER
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning