The decomposition of NH 4 HS , NH 4 HS ( s ) ⇄ NH 3 ( g ) + H 2 S ( g ) is an endothermic process. Using Le principle, explain how increasing the temperature would affect the equilibrium. If more NH 4 HS is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional NH 3 is placed in the flask? What will happen to the pressure of NH 3 if some H 2 S is removed from the flask?
The decomposition of NH 4 HS , NH 4 HS ( s ) ⇄ NH 3 ( g ) + H 2 S ( g ) is an endothermic process. Using Le principle, explain how increasing the temperature would affect the equilibrium. If more NH 4 HS is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional NH 3 is placed in the flask? What will happen to the pressure of NH 3 if some H 2 S is removed from the flask?
Solution Summary: The author explains that an endothermic reaction is a reaction in which energy is consumed or added to the reaction. The effect of removal of H 2 S on the pressure of NH3 should be explained.
is an endothermic process. Using Le principle, explain how increasing the temperature would affect the equilibrium. If more
NH
4
HS
is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional
NH
3
is placed in the flask? What will happen to the pressure of
NH
3
if some
H
2
S
is removed from the flask?
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 12 Solutions
Bundle: Chemistry for Engineering Students, Loose-Leaf Version, 4th + OWLv2 with MindTap Reader with Student Solutions Manual, 1 term (6 months) Printed Access Card
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.