Study Guide And Selected Solutions Manual For Chemistry Format: Paperback
13th Edition
ISBN: 9780134553986
Author: Timberlake, Karen C
Publisher: Prentice Hall
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Chapter 12, Problem 12.60APP
Which of the following
a.
b.
c.
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Here are the energies (in kcal/mol) for staggered and eclipsed interactions
for CH, CC, and CBr bonds
eclipsed (0°) staggered (60°)
bonds
CH/CH
1.0
0.0
CH/CC
1.3
0.0
Br:
CC/CC
3.0
0.9
Br
CH/CBr
1.8
0.0
CC / CBr
3.3
1.0
CBr / CBr
3.7
1.2
a) I've drawn the Newman projection for one of the staggered conformations of the molecule
above, looking down the C2-C3 bond. Draw Newman projections for the other two staggered
and the three eclipsed conformations (in order).
CH₂
H3C.
H'
H
Br
b) Calculate the relative energies for each of the conformations and write them below each
conformation.
90. Draw the stereoisomers obtained from each of the following reactions:
a.
H₂
b.
H₂
C.
H₂
Pd/C
Pd/C
Pd/C
36. The emission spectrum below for a one-electron (hydrogen-like) species in the gas
phase shows all the lines, before they merge together, resulting from transitions to the
first excited state from higher energy states. Line A has a wavelength of 434 nm.
BA
Increasing wavelength, λ
(a) What are the upper and lower principal quantum numbers corresponding to the lines
labeled A and B? (b) Identify the one-electron species that exhibits the spectrum.
Chapter 12 Solutions
Study Guide And Selected Solutions Manual For Chemistry Format: Paperback
Ch. 12.1 - Give the IUPAC name for each of the following: a....Ch. 12.1 - Give the IUPAC name for each of the following: a....Ch. 12.1 - Prob. 12.3PPCh. 12.1 - Draw the condensed structural formula, or...Ch. 12.1 - Give the common name for each of the following: a....Ch. 12.1 - Prob. 12.6PPCh. 12.1 - Draw the condensed structural formula, or...Ch. 12.1 - Draw the condensed structural formula, or...Ch. 12.2 - Classify each of the following alcohols as primary...Ch. 12.2 - Classify each of the following alcohols as primary...
Ch. 12.2 - Prob. 12.11PPCh. 12.2 - Prob. 12.12PPCh. 12.2 - Give an explanation for each of the following...Ch. 12.2 - Give an explanation for each of the following...Ch. 12.3 - Identify each of the following compounds as an...Ch. 12.3 - Identify each of the following compounds as an...Ch. 12.3 - Give the common name for each of the following: a....Ch. 12.3 - Give the common name for each of the following: a....Ch. 12.3 - Give the IUPAC name for each of the following: a....Ch. 12.3 - Give the IUPAC name for each of the following: a....Ch. 12.3 - Draw the condensed structural formula for each of...Ch. 12.3 - Draw the condensed structural formula for each of...Ch. 12.3 - Which compound in each of the following pairs...Ch. 12.3 - Which compound in each of the following pairs...Ch. 12.4 - Write the balanced chemical equation for the...Ch. 12.4 - Write the balanced chemical equation for the...Ch. 12.4 - Prob. 12.27PPCh. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural or line-angle...Ch. 12.4 - Draw the condensed structural formulas for the...Ch. 12.4 - Draw the condensed structural formulas for the...Ch. 12.4 - Prob. 12.33PPCh. 12.4 - Prob. 12.34PPCh. 12.4 - Oxybenzone is an effective sunscreen whose...Ch. 12.4 - Avobenzone is a common ingredient in sunscreen....Ch. 12 - Prob. 12.37UTCCh. 12 - The compound frambinone has the taste of...Ch. 12 - A compound called resveratrol is an antioxidant,...Ch. 12 - A compound called cinnamaldehyde is found in...Ch. 12 - Prob. 12.41UTCCh. 12 - Prob. 12.42UTCCh. 12 - Prob. 12.43APPCh. 12 - Classify each of the following alcohols as primary...Ch. 12 - Give the IUPAC name for each of the following...Ch. 12 - Give the IUPAC name for each of the following...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Which compound in each pair would be more soluble...Ch. 12 - Which compound in each pair would be more soluble...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Give the IUPAC name for each of the following:...Ch. 12 - Give the IUPAC name for each of the following:...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Which of the following aldehydes or ketones are...Ch. 12 - Which of the following aldehydes or ketones are...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Draw the condensed structural or line-angle...Ch. 12 - Prob. 12.63CPCh. 12 - Draw the condensed structural formulas and give...Ch. 12 - A compound with the formula C4H8O is synthesized...Ch. 12 - A compound with the formula C5H10O oxidizes to...Ch. 12 - Compound A is a primary alcohol whose formula is...Ch. 12 - Compound X is a secondary alcohol whose formula is...Ch. 12 - Prob. 21CICh. 12 - Prob. 22CICh. 12 - Prob. 23CICh. 12 - Prob. 24CICh. 12 - Prob. 25CICh. 12 - lonone is a compound that gives violets their...
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- f) The unusual molecule [2.2.2] propellane is pictured. 1) Given the bond length and bond angles in the image, what hybridization scheme best describes the carbons marked by the askerisks? 2) What types of orbitals are used in the bond between the two carbons marked by the askerisks? 3) How does this bond compare to an ordinary carbon-carbon bond (which is usually 1.54 Å long)? H₂C H₂C CH2 1.60Å ハ C. * CH₂ H₂C * C H₂ 120°arrow_forwardQuestion Resonance Forms a) Draw all resonance forms of the molecules. Include curved arrow notation. Label major resonance contributor Resonance Forms a) Draw all resonance forms of the molecules. Include curved arrow notation. Label major resonance contributorarrow_forwardCan you show me or determine the longest carbon chain, which is octane? Potentially highlight it in different sections to show me, plz, or individually?arrow_forward
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- a. The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 " is best described as a hybrid of several contributing resonance forms, two of which are shown here. HO :0: HO + :Ö: Bicarbonate is crucial for the control of body pH (for example, blood pH 7.4). A more self-indulgent use is in baking soda, where it serves as a source of CO2 CO2 gas, which gives bread and pastry their fluffy constituency. (i) Draw at least one additional resonance form. = (ii) Using curved "electron-pushing" arrows, show how these Lewis structures may be interconverted by movement of electron pairs. (iii) Determine which form or forms will be the major contributor(s) to the real structure of bicarbonate, explaining your answer on the basis of the criteria in Section 1-5.arrow_forwardCalibri 11 + BIL NAME: Jaylena M A student is investigating the ctect of volume on pressure during a lab activity. The student uses the following volumes (mL). 12, 13, 14, 16, 17, 18, 19, 20, 21, 22, 23, 24, 26, 28, 30, 33, 34, 35, 38, 40, 42, 44. 46, and 50. As the volume changed they measured the following pressures (atm) 11.0, 10.5, 10.0, 9.2. 8.5, 78, 75, 7.0, 6.8, 6.5, 6.0, 5.9, 5.5, 5.0, 4.8, 4.5, 4.2, 3.9, 3.8, 3.5, 3.3, 3.2, 3.0, 2.9. What is the independent variable? Volume Imla What is the dependent variable? Pressure Jatm Use the data and make a PROPER data table. Volume 1mL) Pressure latm 110arrow_forwardDraw all resonance forms of the molecules. Include curved arrow notation. Label major resonance contributor.arrow_forward
- : Resonance Forms a) Draw all resonance forms of the molecules. Include curved arrow notation. Label major resonance contributor. SO₂ NO3arrow_forward1d. Use Le Chatelier's principle to describe the effect of the following changes on the position of the Haber-Bosch equilibrium: N2(g) + 3H2(g)= 2NH3(9) AH = -92kJ Choose one of the following answers: shift to reactant side, shift to product side or no change and draw the resulting graph. I. Increase the [N2(g)] Effect: H₂ N₂ NH3 II. Decrease the volume of the container. Effect: H₂ N₂2 NH3arrow_forwardf) The unusual molecule [2.2.2] propellane is pictured. 1) Given the bond length and bond angles in the image, what hybridization scheme best describes the carbons marked by the askerisks? 2) What types of orbitals are used in the bond between the two carbons marked by the askerisks? 3) How does this bond compare to an ordinary carbon-carbon bond (which is usually 1.54 Å long)? CH2 1.60Å H₂C * H₂C CH2 C H2C * C Of H₂ 120°arrow_forward
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