INTRO. TO CHEM LOOSELEAF W/ALEKS 18WKCR
INTRO. TO CHEM LOOSELEAF W/ALEKS 18WKCR
5th Edition
ISBN: 9781264125609
Author: BAUER
Publisher: MCG
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Chapter 12, Problem 125QP
Interpretation Introduction

Interpretation:

According to collision theory, the effect on reaction rate as the reaction reaches equilibrium, are to be explained.

Concept Introduction:

Collision theory is totally based on the fact that, for a reaction to occur the reactant species should collide together.

For the formation of a particular product, the reactants have to collide in a particular orientation or effective orientation and at the same time they have cross the energy barrier, and to cross they require sufficient energy known as activation energy.

Reactants that collide in the effective orientation form activated complex, an unstable high energy species are formed before the products, and get transformed into products with time.

The effective collision is affected by the following factors: temperature and concentration of reactants and surface area.

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Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400
• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak

Chapter 12 Solutions

INTRO. TO CHEM LOOSELEAF W/ALEKS 18WKCR

Ch. 12 - Prob. 5PPCh. 12 - Prob. 6PPCh. 12 - Prob. 7PPCh. 12 - Prob. 8PPCh. 12 - Prob. 9PPCh. 12 - Prob. 10PPCh. 12 - Consider the following equilibrium:...Ch. 12 - Prob. 12PPCh. 12 - Prob. 1QPCh. 12 - Match the key terms with the descriptions...Ch. 12 - Prob. 3QPCh. 12 - Prob. 4QPCh. 12 - Prob. 5QPCh. 12 - Prob. 6QPCh. 12 - Prob. 7QPCh. 12 - Prob. 8QPCh. 12 - Prob. 9QPCh. 12 - Prob. 10QPCh. 12 - Prob. 11QPCh. 12 - Prob. 12QPCh. 12 - Prob. 13QPCh. 12 - Prob. 14QPCh. 12 - Prob. 15QPCh. 12 - Prob. 16QPCh. 12 - Prob. 17QPCh. 12 - Prob. 18QPCh. 12 - Prob. 19QPCh. 12 - Prob. 20QPCh. 12 - Prob. 21QPCh. 12 - Prob. 22QPCh. 12 - Prob. 23QPCh. 12 - Prob. 24QPCh. 12 - Prob. 25QPCh. 12 - Prob. 26QPCh. 12 - Prob. 27QPCh. 12 - Prob. 28QPCh. 12 - Prob. 29QPCh. 12 - Prob. 30QPCh. 12 - Prob. 31QPCh. 12 - Prob. 32QPCh. 12 - Prob. 33QPCh. 12 - Prob. 34QPCh. 12 - Prob. 35QPCh. 12 - Prob. 36QPCh. 12 - Prob. 37QPCh. 12 - Prob. 38QPCh. 12 - Prob. 39QPCh. 12 - Prob. 40QPCh. 12 - Prob. 41QPCh. 12 - Prob. 42QPCh. 12 - Prob. 43QPCh. 12 - Prob. 44QPCh. 12 - Prob. 45QPCh. 12 - Prob. 46QPCh. 12 - Prob. 47QPCh. 12 - Prob. 48QPCh. 12 - Prob. 49QPCh. 12 - Prob. 50QPCh. 12 - Prob. 51QPCh. 12 - Prob. 52QPCh. 12 - Prob. 53QPCh. 12 - Prob. 54QPCh. 12 - Prob. 55QPCh. 12 - Prob. 56QPCh. 12 - Prob. 57QPCh. 12 - Prob. 58QPCh. 12 - Prob. 59QPCh. 12 - Prob. 60QPCh. 12 - Prob. 61QPCh. 12 - Prob. 62QPCh. 12 - Prob. 63QPCh. 12 - Prob. 64QPCh. 12 - Prob. 65QPCh. 12 - Prob. 66QPCh. 12 - Prob. 67QPCh. 12 - Prob. 68QPCh. 12 - Prob. 69QPCh. 12 - Prob. 70QPCh. 12 - Prob. 71QPCh. 12 - Prob. 72QPCh. 12 - Prob. 73QPCh. 12 - Prob. 74QPCh. 12 - Prob. 75QPCh. 12 - Prob. 76QPCh. 12 - Prob. 77QPCh. 12 - Prob. 78QPCh. 12 - Prob. 79QPCh. 12 - Prob. 80QPCh. 12 - Prob. 81QPCh. 12 - Prob. 82QPCh. 12 - Prob. 83QPCh. 12 - Prob. 84QPCh. 12 - Prob. 85QPCh. 12 - Prob. 86QPCh. 12 - Prob. 87QPCh. 12 - Prob. 88QPCh. 12 - Prob. 89QPCh. 12 - Prob. 90QPCh. 12 - Prob. 91QPCh. 12 - Prob. 92QPCh. 12 - Prob. 93QPCh. 12 - Prob. 94QPCh. 12 - Prob. 95QPCh. 12 - Prob. 96QPCh. 12 - Prob. 97QPCh. 12 - Prob. 98QPCh. 12 - Prob. 99QPCh. 12 - Prob. 100QPCh. 12 - Prob. 101QPCh. 12 - Prob. 102QPCh. 12 - Prob. 103QPCh. 12 - Prob. 104QPCh. 12 - Prob. 105QPCh. 12 - Prob. 106QPCh. 12 - Prob. 107QPCh. 12 - Prob. 108QPCh. 12 - Prob. 109QPCh. 12 - Prob. 110QPCh. 12 - Prob. 111QPCh. 12 - Prob. 112QPCh. 12 - Prob. 113QPCh. 12 - Prob. 114QPCh. 12 - Prob. 115QPCh. 12 - Prob. 116QPCh. 12 - Prob. 117QPCh. 12 - Prob. 118QPCh. 12 - Prob. 119QPCh. 12 - Prob. 120QPCh. 12 - Prob. 121QPCh. 12 - Prob. 122QPCh. 12 - Prob. 123QPCh. 12 - Prob. 124QPCh. 12 - Prob. 125QPCh. 12 - Prob. 126QPCh. 12 - Prob. 127QPCh. 12 - Prob. 128QPCh. 12 - Prob. 129QPCh. 12 - Prob. 130QPCh. 12 - Prob. 131QPCh. 12 - Prob. 132QPCh. 12 - Prob. 133QPCh. 12 - Prob. 134QPCh. 12 - Prob. 135QPCh. 12 - Prob. 136QPCh. 12 - Prob. 137QPCh. 12 - Prob. 138QPCh. 12 - Prob. 139QPCh. 12 - Prob. 140QPCh. 12 - Prob. 141QPCh. 12 - Prob. 142QPCh. 12 - Prob. 143QP
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