The wide range of solubility of ionic compounds in water has to be explained. Concept Introduction: Solubility of an ionic compound is primarily influenced by – lattice energy, hydration energy and ion-dipole interaction. The energy released when gaseous state ions of unlike charges that are infinitely farther apart combine to form a stable ionic solid is called Lattice energy . Conversely, the energy required to break the electrostatic force of attraction between the ions of unlike charges in the ionic solid and revert them to gaseous state is also termed as Lattice energy of an ionic solid. Hydration energy refers to the quantity of energy released when one mole of ion gets hydrated at constant pressure. Hydration energy of an ion depends upon its ionic size. Ion-dipole attraction is the attractive force between ion (from the solute) and a dipole (from polar solvent).

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

Answer 1

Question

Chapter 12, Problem 12.4QP

Interpretation Introduction

Interpretation:

The wide range of solubility of ionic compounds in water has to be explained.

Concept Introduction:

Solubility of an ionic compound is primarily influenced by – lattice energy, hydration energy and ion-dipole interaction.

The energy released when gaseous state ions of unlike charges that are infinitely farther apart combine to form a stable ionic solid is called Lattice energy. Conversely, the energy required to break the electrostatic force of attraction between the ions of unlike charges in the ionic solid and revert them to gaseous state is also termed as Lattice energy of an ionic solid.

Hydration energy refers to the quantity of energy released when one mole of ion gets hydrated at constant pressure. Hydration energy of an ion depends upon its ionic size.

Ion-dipole attraction is the attractive force between ion (from the solute) and a dipole (from polar solvent).

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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3

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