(a) Interpretation: Whether the peak at m / z = 83 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated. Concept introduction: In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

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Answer 1

Question

Chapter 12, Problem 12.19P

Interpretation Introduction

(a)

Interpretation:

Whether the peak at m/z=83 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(b)

Interpretation:

Whether the peak at m/z=56 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(c)

Interpretation:

Whether the peak at m/z=41 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

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Answer 2

Question

Chapter 12, Problem 12.19P

Interpretation Introduction

(a)

Interpretation:

Whether the peak at m/z=83 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(b)

Interpretation:

Whether the peak at m/z=56 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(c)

Interpretation:

Whether the peak at m/z=41 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

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Answer 3

Question

Chapter 12, Problem 12.19P

Interpretation Introduction

(a)

Interpretation:

Whether the peak at m/z=83 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(b)

Interpretation:

Whether the peak at m/z=56 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(c)

Interpretation:

Whether the peak at m/z=41 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Expert Solution & Answer

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Answer 4

Question

Chapter 12, Problem 12.19P

Interpretation Introduction

(a)

Interpretation:

Whether the peak at m/z=83 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(b)

Interpretation:

Whether the peak at m/z=56 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(c)

Interpretation:

Whether the peak at m/z=41 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Expert Solution & Answer

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Answer 5

Chapter 12, Problem 12.19P

Interpretation Introduction

(a)

Interpretation:

Whether the peak at m/z=83 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(b)

Interpretation:

Whether the peak at m/z=56 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Interpretation Introduction

(c)

Interpretation:

Whether the peak at m/z=41 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Answer 6

Chapter 12, Problem 12.19P

Interpretation Introduction

(a)

Interpretation:

Whether the peak at m/z=83 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Answer 7

Chapter 12, Problem 12.19P

Interpretation Introduction

(a)

Interpretation:

Whether the peak at m/z=83 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the peak at m/z=56 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the peak at m/z=56 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the peak at m/z=41 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the peak at m/z=41 in mass spectrum of 1-heptanol is odd-electron or even-electron fragment is to be stated.

Concept introduction:

In mass spectrometry, an electron is lost to form a molecular ion. Two types of fragmentation occur. A stable molecular ion decomposes slowly and a peak with large relative abundance is detected in the mass spectrometer. If the molecular ion is unstable, it decomposes into several ions.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 12 - Prob. 12.1P Ch. 12 - Prob. 12.2P Ch. 12 - Prob. 12.3P Ch. 12 - Prob. 12.4P Ch. 12 - Prob. 12.5P Ch. 12 - Prob. 12.6P Ch. 12 - Prob. 12.7P Ch. 12 - Prob. 12.8P Ch. 12 - Prob. 12.9P Ch. 12 - Prob. 12.10P

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Chapter 12 Solutions