(a) Interpretation: The structure of the fragment in the EI mass spectrum of 3 -amino- 3 -methylhexane at m / z = 72 is to be drawn and a mechanism of its formation is to be stated. Concept introduction: In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

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Answer 1

Question

Chapter 12, Problem 12.35AP

Interpretation Introduction

(a)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-amino-3-methylhexane at m/z=72 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(b)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-methyl-3-hexanol at m/z=73 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment in the EI mass spectrum of pentanol at m/z=70 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(d)

Interpretation:

The structure of the fragment in the EI mass spectrum of neopentane at m/z=57 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

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1 (c) 2-Methyl-3-pentanol reacts with PCC to form compound F. (i) Draw the structure of F. (ii) In the mass spectrum, identify the m/z value of the molecular ion peak for compound F. (ii) Fragmentation of radical cation F exhibits two fragment ion peaks at m/z 57 and m/z 71. Propose the structures of these two fragments. (iv) Draw the resonance structure for each of the cation in (iii).

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Answer 2

Question

Chapter 12, Problem 12.35AP

Interpretation Introduction

(a)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-amino-3-methylhexane at m/z=72 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(b)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-methyl-3-hexanol at m/z=73 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment in the EI mass spectrum of pentanol at m/z=70 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(d)

Interpretation:

The structure of the fragment in the EI mass spectrum of neopentane at m/z=57 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

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Answer 3

Question

Chapter 12, Problem 12.35AP

Interpretation Introduction

(a)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-amino-3-methylhexane at m/z=72 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(b)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-methyl-3-hexanol at m/z=73 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment in the EI mass spectrum of pentanol at m/z=70 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(d)

Interpretation:

The structure of the fragment in the EI mass spectrum of neopentane at m/z=57 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

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Answer 4

Question

Chapter 12, Problem 12.35AP

Interpretation Introduction

(a)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-amino-3-methylhexane at m/z=72 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(b)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-methyl-3-hexanol at m/z=73 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment in the EI mass spectrum of pentanol at m/z=70 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(d)

Interpretation:

The structure of the fragment in the EI mass spectrum of neopentane at m/z=57 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

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Answer 5

Chapter 12, Problem 12.35AP

Interpretation Introduction

(a)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-amino-3-methylhexane at m/z=72 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(b)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-methyl-3-hexanol at m/z=73 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment in the EI mass spectrum of pentanol at m/z=70 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Interpretation Introduction

(d)

Interpretation:

The structure of the fragment in the EI mass spectrum of neopentane at m/z=57 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 6

Chapter 12, Problem 12.35AP

Interpretation Introduction

(a)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-amino-3-methylhexane at m/z=72 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 7

Chapter 12, Problem 12.35AP

Interpretation Introduction

(a)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-amino-3-methylhexane at m/z=72 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-methyl-3-hexanol at m/z=73 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of the fragment in the EI mass spectrum of 3-methyl-3-hexanol at m/z=73 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment in the EI mass spectrum of pentanol at m/z=70 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment in the EI mass spectrum of pentanol at m/z=70 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure of the fragment in the EI mass spectrum of neopentane at m/z=57 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure of the fragment in the EI mass spectrum of neopentane at m/z=57 is to be drawn and a mechanism of its formation is to be stated.

Concept introduction:

In mass spectroscopy, compounds are identified on the basis of mass of compound. When the compound breaks into fragments then they can be distinguished from the other compounds. This technique is also used to differentiate the isotopes of compounds. This technique does not involve electromagnetic radiations. Two peaks are used to identify the compound, the molecular ion which is the mass of the compound and base peak is the peak of most abundant element.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12 - Prob. 12.1P Ch. 12 - Prob. 12.2P Ch. 12 - Prob. 12.3P Ch. 12 - Prob. 12.4P Ch. 12 - Prob. 12.5P Ch. 12 - Prob. 12.6P Ch. 12 - Prob. 12.7P Ch. 12 - Prob. 12.8P Ch. 12 - Prob. 12.9P Ch. 12 - Prob. 12.10P

Solution Summary: The author explains how the structure of the fragment in the EI mass spectrum of 3 -amino- methylhexane at m/z=72 is to be drawn and a mechanism

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