EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 8220101443908
Author: Harris
Publisher: MAC HIGHER
Question
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Chapter 12, Problem 12.10P

(a)

Interpretation Introduction

Interpretation:

Activity coefficient of SO42  ion that has ionic strength of 0.01 M has to be calculated.

Concept Introduction:

Extended Debye Huckel law quantifies activity coefficient in terms of ionic strength and hydrated size as follows:

  logγ=0.51z2μ1+(αμ/305)

Here

z denotes charge.

μ denotes ionic strength.

γ denotes activity coefficient.

α denotes ionic size.

(b)

Interpretation Introduction

Interpretation:

Activity coefficient of Sc3+  ion that has ionic strength of 0.005 M has to be calculated.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Activity coefficient of Eu3+  ion that has ionic strength of 0.1 M has to be calculated.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

Activity coefficient of (CH3CH2)3NH+ ion that has ionic strength of 0.05 M has to be calculated.

Concept Introduction:

Refer to part (a).

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