a) Interpretation: The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided. Concept introduction: The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. To identify: The products formed in the reaction given and to provide the mechanism of the reaction.

Question

For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PH

Answer 1

Question

Chapter 11.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. ? Will the first MgBr product that forms in this reaction create a new CC bond? olo ? OH جمله O Yes Ⓒ No MgCl ? Will the first product that forms in this reaction create a new CC bond? Click and drag to start drawing a structure. Yes No X ☐ : ☐ टे PH

Assign all the protons

PROPOSE REACTION MECHANISM FOR ACID-CATALYZED REACTION OF 3-PENTANONE WITH DIMETHYLAMINE

Answer 2

Question

Chapter 11.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Expert Solution & Answer

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Answer 3

Question

Chapter 11.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Expert Solution & Answer

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Answer 4

Question

Chapter 11.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Expert Solution & Answer

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Answer 5

Chapter 11.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 6

Chapter 11.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 7

Chapter 11.SE, Problem 30MP

Interpretation Introduction

a)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 8

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 9

Interpretation Introduction

b)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to be provided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product. The methoxyl group is an ortho and para orienting group.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 10

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 11

Interpretation Introduction

c)

Interpretation:

The products formed in the reaction given are to be identified. The mechanism of the reaction also is to berovided.

Concept introduction:

The mechanism of the electrophilic substitution reaction is to be given. In the first step the electrophile is produced. In the second step the electrons of the aromatic ring attacks the elctrophile to give a resonance stabilized intermediate. In the last step the intermediate deprotonates to yield the product.

To identify:

The products formed in the reaction given and to provide the mechanism of the reaction.

Answer 12

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Answer 13

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Answer 23

Ch. 11.1 - Prob. 1P Ch. 11.2 - Prob. 2P Ch. 11.2 - Prob. 3P Ch. 11.3 - Prob. 4P Ch. 11.3 - Prob. 5P Ch. 11.3 - Rank the following compounds in order of their...Ch. 11.3 - Organic solvents like benzene, ether, and...Ch. 11.4 - Prob. 8P Ch. 11.4 - Prob. 9P Ch. 11.4 - Prob. 10P

Chapter 11 Solutions