General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
5th Edition
ISBN: 9780321967466
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 11.9, Problem 11.76QAP
Why would the pH of your blood plasma decrease if you hold your breath?
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 11 Solutions
General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
Ch. 11.1 - Indicate whether each of the following statements...Ch. 11.1 - Prob. 11.2QAPCh. 11.1 - Prob. 11.3QAPCh. 11.1 - Name each of the following acids or bases: a....Ch. 11.1 - Write formulas for each of the following acids and...Ch. 11.1 - Write formulas for each of the following acids and...Ch. 11.2 - Identify the reactant that is a Bronsted-Lowry...Ch. 11.2 - Prob. 11.8QAPCh. 11.2 - Prob. 11.9QAPCh. 11.2 - Prob. 11.10QAP
Ch. 11.2 - Prob. 11.11QAPCh. 11.2 - Prob. 11.12QAPCh. 11.2 - Identify the Bronsted-Lowry acid-base pairs in...Ch. 11.2 - Prob. 11.14QAPCh. 11.2 - Prob. 11.15QAPCh. 11.2 - Prob. 11.16QAPCh. 11.3 - What is meant by the phrase ”A strong acid as a...Ch. 11.3 - Prob. 11.18QAPCh. 11.3 - Prob. 11.19QAPCh. 11.3 - Prob. 11.20QAPCh. 11.3 - Prob. 11.21QAPCh. 11.3 - Prob. 11.22QAPCh. 11.3 - Prob. 11.23QAPCh. 11.3 - Prob. 11.24QAPCh. 11.3 - Prob. 11.25QAPCh. 11.3 - Prob. 11.26QAPCh. 11.4 - Answer true or false for each of the following: A...Ch. 11.4 - Prob. 11.28QAPCh. 11.4 - Prob. 11.29QAPCh. 11.4 - Consider the following acids and their...Ch. 11.4 - Prob. 11.31QAPCh. 11.4 - Prob. 11.32QAPCh. 11.5 - Why are the concentrations of H3O+ and OH- equal...Ch. 11.5 - Prob. 11.34QAPCh. 11.5 - Prob. 11.35QAPCh. 11.5 - Prob. 11.36QAPCh. 11.5 - Prob. 11.37QAPCh. 11.5 - Prob. 11.38QAPCh. 11.5 - Prob. 11.39QAPCh. 11.5 - Prob. 11.40QAPCh. 11.5 - 11.41 Calculate the of each aqueous solution with...Ch. 11.5 - Prob. 11.42QAPCh. 11.6 - Prob. 11.43QAPCh. 11.6 - Prob. 11.44QAPCh. 11.6 - Prob. 11.45QAPCh. 11.6 - Prob. 11.46QAPCh. 11.6 - Prob. 11.47QAPCh. 11.6 - Prob. 11.48QAPCh. 11.6 - Prob. 11.49QAPCh. 11.6 - Prob. 11.50QAPCh. 11.6 - Prob. 11.51QAPCh. 11.6 - Prob. 11.52QAPCh. 11.6 - Prob. 11.53QAPCh. 11.6 - Prob. 11.54QAPCh. 11.7 - Prob. 11.55QAPCh. 11.7 - Complete and balance the equation for each of the...Ch. 11.7 - Prob. 11.57QAPCh. 11.7 - Prob. 11.58QAPCh. 11.7 - Prob. 11.59QAPCh. 11.7 - Prob. 11.60QAPCh. 11.8 - Prob. 11.61QAPCh. 11.8 - Prob. 11.62QAPCh. 11.8 - Prob. 11.63QAPCh. 11.8 - Prob. 11.64QAPCh. 11.8 - A solution of 0.204 M NaOH is used to titrate 50.0...Ch. 11.8 - Prob. 11.66QAPCh. 11.9 - Which of the following represents a buffer system?...Ch. 11.9 - Prob. 11.68QAPCh. 11.9 - Prob. 11.69QAPCh. 11.9 - Prob. 11.70QAPCh. 11.9 - Prob. 11.71QAPCh. 11.9 - Prob. 11.72QAPCh. 11.9 - Prob. 11.73QAPCh. 11.9 - Prob. 11.74QAPCh. 11.9 - Why would the pH of your blood plasma increase if...Ch. 11.9 - Why would the pH of your blood plasma decrease if...Ch. 11.9 - Prob. 11.77QAPCh. 11.9 - Someone with severe diabetes obtains energy by the...Ch. 11.9 - Prob. 11.79QAPCh. 11.9 - When food enters the stomach, HCI is released and...Ch. 11.9 - Prob. 11.81QAPCh. 11.9 - Prob. 11.82QAPCh. 11.9 - Prob. 11.83QAPCh. 11.9 - Prob. 11.84QAPCh. 11.9 - Prob. 11.85QAPCh. 11.9 - Prob. 11.86QAPCh. 11 - Prob. 11.87UTCCh. 11 - Prob. 11.88UTCCh. 11 - Prob. 11.89UTCCh. 11 - Prob. 11.90UTCCh. 11 - Prob. 11.91UTCCh. 11 - Prob. 11.92UTCCh. 11 - Prob. 11.93UTCCh. 11 - Prob. 11.94UTCCh. 11 - Prob. 11.95UTCCh. 11 - Prob. 11.96UTCCh. 11 - Identify each of the following as an acid, base,...Ch. 11 - Idenúfy each of the following as an acid, base, or...Ch. 11 - Complete the following table: (11.2) Acid...Ch. 11 - Complete the following table: (11.2) Base...Ch. 11 - Using Table 11.3, identify the stronger acid in...Ch. 11 - Prob. 11.102AQAPCh. 11 - Determine the pH for each of the following...Ch. 11 - Determine the pH for each of the following...Ch. 11 - Prob. 11.105AQAPCh. 11 - Prob. 11.106AQAPCh. 11 - Calculate the [H3O+] and [OH] for a solution with...Ch. 11 - Calculate the [H3O+]and [OH]for a solution with...Ch. 11 - Solution A has a pH of 4.5, and solution B has a...Ch. 11 - Solution X has a pH of 9.5, and solution Y has a...Ch. 11 - Prob. 11.111AQAPCh. 11 - Prob. 11.112AQAPCh. 11 - What is the pH of a solution prepared by...Ch. 11 - Prob. 11.114AQAPCh. 11 - For each of the following: (11.2, 11.3) 1. H2S a....Ch. 11 - Prob. 11.116CQCh. 11 - Prob. 11.117CQCh. 11 - Prob. 11.118CQCh. 11 - Prob. 11.119CQCh. 11 - Prob. 11.120CQCh. 11 - Prob. 11.121CQCh. 11 - Prob. 11.122CQCh. 11 - Prob. 11.123CQCh. 11 - Prob. 11.124CQCh. 11 - Prob. 11.125CQCh. 11 - Prob. 11.126CQCh. 11 - Prob. 11.127CQCh. 11 - Prob. 11.128CQCh. 11 - Prob. 11.129CQCh. 11 - Prob. 11.130CQCh. 11 - Prob. 19CICh. 11 - Prob. 20CICh. 11 - Prob. 21CICh. 11 - Prob. 22CICh. 11 - Prob. 23CICh. 11 - Prob. 24CICh. 11 - A volume of 200.0 mL of a carbonic acid buffer for...Ch. 11 - Prob. 26CI
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- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forward
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