Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 11.4, Problem 40PP
Explain each of the following observations:
a. Boiling water at sea level is hotter than boiling water in the mountains.
b. Water used to sterilize surgical equipment is heated to
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
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11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
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Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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4 Bromo
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b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
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Chapter 11 Solutions
Basic Chemistry
Ch. 11.1 - Prob. 1PPCh. 11.1 - Prob. 2PPCh. 11.1 - Prob. 3PPCh. 11.1 - Prob. 4PPCh. 11.1 - Prob. 5PPCh. 11.1 - Prob. 6PPCh. 11.1 - Prob. 7PPCh. 11.1 - Prob. 8PPCh. 11.2 - Prob. 9PPCh. 11.2 - Prob. 10PP
Ch. 11.2 - Prob. 11PPCh. 11.2 - Prob. 12PPCh. 11.2 - Prob. 13PPCh. 11.2 - Prob. 14PPCh. 11.2 - Prob. 15PPCh. 11.2 - Prob. 16PPCh. 11.2 - Prob. 17PPCh. 11.2 - Prob. 18PPCh. 11.2 - Prob. 19PPCh. 11.2 - Prob. 20PPCh. 11.2 - Prob. 21PPCh. 11.2 - Prob. 22PPCh. 11.2 - Prob. 23PPCh. 11.2 - Prob. 24PPCh. 11.3 - Prob. 25PPCh. 11.3 - Prob. 26PPCh. 11.3 - Prob. 27PPCh. 11.3 - Prob. 28PPCh. 11.3 - Prob. 29PPCh. 11.3 - Prob. 30PPCh. 11.3 - Prob. 31PPCh. 11.3 - Prob. 32PPCh. 11.4 - Prob. 33PPCh. 11.4 - Prob. 34PPCh. 11.4 - Prob. 35PPCh. 11.4 - Prob. 36PPCh. 11.4 - Prob. 37PPCh. 11.4 - Prob. 38PPCh. 11.4 - Prob. 39PPCh. 11.4 - Explain each of the following observations: a....Ch. 11.4 - A tank contains isoflurane, an inhaled anesthetic,...Ch. 11.4 - Prob. 42PPCh. 11.5 - Prob. 43PPCh. 11.5 - Prob. 44PPCh. 11.5 - Prob. 45PPCh. 11.5 - Prob. 46PPCh. 11.5 - Prob. 47PPCh. 11.5 - Prob. 48PPCh. 11.6 - Prob. 49PPCh. 11.6 - Prob. 50PPCh. 11.6 - Prob. 51PPCh. 11.6 - Prob. 52PPCh. 11.6 - Prob. 53PPCh. 11.6 - Prob. 54PPCh. 11.7 - Prob. 55PPCh. 11.7 - What is the volume, in liters, of 4.00 mol of...Ch. 11.7 - An oxygen gas container has a volume of 20.0 L....Ch. 11.7 - Prob. 58PPCh. 11.7 - A 25.0-g sample of nitrogen, N2 , has a volume of...Ch. 11.7 - A 0.226-g sample of carbon dioxide, CO2 , has a...Ch. 11.7 - Prob. 61PPCh. 11.7 - Prob. 62PPCh. 11.7 - Prob. 63PPCh. 11.7 - Prob. 64PPCh. 11.8 - HCl reacts with magnesium metal to produce...Ch. 11.8 - When heated to 350Cat0.950atm , ammonium nitrate...Ch. 11.8 - Butane undergoes combustion when it reacts with...Ch. 11.8 - Potassium nitrate decomposes to potassium nitrite...Ch. 11.8 - Prob. 69PPCh. 11.8 - Nitrogen dioxide reacts with water to produce...Ch. 11.9 - Prob. 71PPCh. 11.9 - Prob. 72PPCh. 11.9 - Prob. 73PPCh. 11.9 - Prob. 74PPCh. 11.9 - Prob. 75PPCh. 11.9 - Prob. 76PPCh. 11.9 - An air sample in the lungs contains oxygen at 93...Ch. 11.9 - Prob. 78PPCh. 11.9 - Prob. 79PPCh. 11.9 - Prob. 80PPCh. 11.9 - Prob. 81PPCh. 11.9 - Prob. 82PPCh. 11 - Prob. 83UTCCh. 11 - Prob. 84UTCCh. 11 - Prob. 85UTCCh. 11 - Indicate which diagram (1, 2, or 3) represents the...Ch. 11 - A balloon is filled with helium gas with a partial...Ch. 11 - Prob. 88UTCCh. 11 - Prob. 89APPCh. 11 - In the fermentation of glucose (wine making), 780...Ch. 11 - Prob. 91APPCh. 11 - Prob. 92APPCh. 11 - In 1783, Jacques Charles launched his first...Ch. 11 - Prob. 94APPCh. 11 - Prob. 95APPCh. 11 - Prob. 96APPCh. 11 - Prob. 97APPCh. 11 - A steel cylinder with a volume of 15.0 L is filled...Ch. 11 - A sample of gas with a mass of 1.62 g occupies a...Ch. 11 - Prob. 100APPCh. 11 - How many grams of...Ch. 11 - A container is filled with...Ch. 11 - How many liters of H2 gas can be produced at...Ch. 11 - Prob. 104APPCh. 11 - Prob. 105APPCh. 11 - Hydrogen gas can be produced in the laboratory...Ch. 11 - Prob. 107APPCh. 11 - Prob. 108APPCh. 11 - A gas mixture contains oxygen and argon at partial...Ch. 11 - Prob. 110APPCh. 11 - Prob. 111CPCh. 11 - When heated, KClO3 forms KCl and O2 . When a...Ch. 11 - A sample of gas with a mass of 1.020 g occupies a...Ch. 11 - A sample of an unknown gas with a mass of 3.24 g...Ch. 11 - Prob. 115CPCh. 11 - When sensors in a car detect a collision, they...Ch. 11 - Prob. 117CPCh. 11 - Prob. 118CPCh. 11 - Prob. 119CPCh. 11 - A hyperbaric chamber has a volume of 1510 L. How...Ch. 11 - Laparoscopic surgery involves inflating the...Ch. 11 - Prob. 122CPCh. 11 - Prob. 123CPCh. 11 - Prob. 124CP
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