The S N 2 reaction between [R]-2-bromobutane and hydroxide ion is to be determined. The stereo chemistry of both the reactant and the product has to be stated. Concept introduction: In S N 2 reaction when a nucleophile OH - ion approaches the Carbon atom the halide group on the opposite side of the carbon atom leaves immediately by altering the stereochemistry. To determine: The S N 2 reaction between [R]-2-bromobutane and hydroxide ion.

Question

Consider the following Figure 2 and two atoms that are initially an infinite distance apart, x =00, at which point the potential energy of the system is U = 0. If they are brought together to x = x, the potential energy is related to the total force P by dU dx = P Given this, qualitatively sketch the variation of U with x. What happens at x=x? What is the significance of x = x, in terms of the potential energy? 0 P, Force 19 Attraction Total Repulsion x, Distance Figure 2. Variation with distance of the attractive, repulsive, and total forces between atoms. The slope dP/dx at the equilibrium spacing xe is proportional to the elastic modulus E; the stress σb, corresponding to the peak in total force, is the theoretical cohesive strength.

Answer 1

Question

Chapter 11.2, Problem 2P

Interpretation Introduction

Interpretation:

The S_N2 reaction between [R]-2-bromobutane and hydroxide ion is to be determined. The stereo chemistry of both the reactant and the product has to be stated.

Concept introduction:

In S_N2 reaction when a nucleophile OH^- ion approaches the Carbon atom the halide group on the opposite side of the carbon atom leaves immediately by altering the stereochemistry.

To determine:

The S_N2 reaction between [R]-2-bromobutane and hydroxide ion.

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Consider the following Figure 2 and two atoms that are initially an infinite distance apart, x =00, at which point the potential energy of the system is U = 0. If they are brought together to x = x, the potential energy is related to the total force P by dU dx = P Given this, qualitatively sketch the variation of U with x. What happens at x=x? What is the significance of x = x, in terms of the potential energy? 0 P, Force 19 Attraction Total Repulsion x, Distance Figure 2. Variation with distance of the attractive, repulsive, and total forces between atoms. The slope dP/dx at the equilibrium spacing xe is proportional to the elastic modulus E; the stress σb, corresponding to the peak in total force, is the theoretical cohesive strength.

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