What products would you expect from the reaction of 1-bromopropane with each of the following? (a) NaNH 2 (b) KOC(CH 3 ) 3 (c) NaI (d) NaCN (e) NaC≡CH (f) Mg, then H 2 O

Question

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Answer 1

Textbook Question

Chapter 11.SE, Problem 50AP

What products would you expect from the reaction of 1-bromopropane with each of the following?

(a) NaNH₂

(b) KOC(CH₃)₃

(c) NaI

(d) NaCN

(e) NaC≡CH

(f) Mg, then H₂O

Expert Solution

Interpretation Introduction

a)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 1

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 2

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 3

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

b)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 4

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 5

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 6

The potassium tertiary butoxide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

c)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 7

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 8

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 9

The sodium iodide is acts as nucleophile, 1-bromo propane undergoes nucleophilic substitution reaction with sodium iodide gives 1-iodo propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

d)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 10

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 11

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 12

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

e)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 13

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 14

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 15

1-bromo propane undergoes nucleophilic substitution reaction with given alkyne compound gives the corresponding alkyne product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

f)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 16

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 17

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 18

1-bromo propane reaction with magnesium gives Grignard reagent and it undergoes hydrolysis gives propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

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Answer 2

Textbook Question

Chapter 11.SE, Problem 50AP

What products would you expect from the reaction of 1-bromopropane with each of the following?

(a) NaNH₂

(b) KOC(CH₃)₃

(c) NaI

(d) NaCN

(e) NaC≡CH

(f) Mg, then H₂O

Expert Solution

Interpretation Introduction

a)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 1

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 2

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 3

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

b)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 4

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 5

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 6

The potassium tertiary butoxide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

c)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 7

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 8

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 9

The sodium iodide is acts as nucleophile, 1-bromo propane undergoes nucleophilic substitution reaction with sodium iodide gives 1-iodo propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

d)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 10

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 11

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 12

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

e)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 13

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 14

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 15

1-bromo propane undergoes nucleophilic substitution reaction with given alkyne compound gives the corresponding alkyne product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

f)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 16

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 17

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 18

1-bromo propane reaction with magnesium gives Grignard reagent and it undergoes hydrolysis gives propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Textbook Question

Chapter 11.SE, Problem 50AP

What products would you expect from the reaction of 1-bromopropane with each of the following?

(a) NaNH₂

(b) KOC(CH₃)₃

(c) NaI

(d) NaCN

(e) NaC≡CH

(f) Mg, then H₂O

Expert Solution

Interpretation Introduction

a)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 1

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 2

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 3

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

b)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 4

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 5

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 6

The potassium tertiary butoxide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

c)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 7

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 8

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 9

The sodium iodide is acts as nucleophile, 1-bromo propane undergoes nucleophilic substitution reaction with sodium iodide gives 1-iodo propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

d)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 10

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 11

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 12

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

e)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 13

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 14

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 15

1-bromo propane undergoes nucleophilic substitution reaction with given alkyne compound gives the corresponding alkyne product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

f)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 16

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 17

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 18

1-bromo propane reaction with magnesium gives Grignard reagent and it undergoes hydrolysis gives propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

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Answer 4

Textbook Question

Chapter 11.SE, Problem 50AP

What products would you expect from the reaction of 1-bromopropane with each of the following?

(a) NaNH₂

(b) KOC(CH₃)₃

(c) NaI

(d) NaCN

(e) NaC≡CH

(f) Mg, then H₂O

Expert Solution

Interpretation Introduction

a)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 1

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 2

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 3

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

b)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 4

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 5

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 6

The potassium tertiary butoxide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

c)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 7

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 8

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 9

The sodium iodide is acts as nucleophile, 1-bromo propane undergoes nucleophilic substitution reaction with sodium iodide gives 1-iodo propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

d)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 10

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 11

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 12

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

e)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 13

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 14

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 15

1-bromo propane undergoes nucleophilic substitution reaction with given alkyne compound gives the corresponding alkyne product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

f)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 16

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 17

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 18

1-bromo propane reaction with magnesium gives Grignard reagent and it undergoes hydrolysis gives propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

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Answer 5

Textbook Question

Answer 6

Textbook Question

Answer 7

Expert Solution

Interpretation Introduction

a)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 1

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 2

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 3

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

b)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 4

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 5

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 6

The potassium tertiary butoxide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

c)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 7

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 8

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 9

The sodium iodide is acts as nucleophile, 1-bromo propane undergoes nucleophilic substitution reaction with sodium iodide gives 1-iodo propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

d)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 10

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 11

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 12

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

e)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 13

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 14

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 15

1-bromo propane undergoes nucleophilic substitution reaction with given alkyne compound gives the corresponding alkyne product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Expert Solution

Interpretation Introduction

f)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 16

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 17

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 18

1-bromo propane reaction with magnesium gives Grignard reagent and it undergoes hydrolysis gives propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 8

Expert Solution

Interpretation Introduction

a)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 1

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 2

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 3

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Interpretation Introduction

a)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer 13

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 1

Answer 14

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 2

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 3

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Answer 15

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 16

Expert Solution

Interpretation Introduction

b)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 4

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 5

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 6

The potassium tertiary butoxide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Interpretation Introduction

b)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer 21

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 4

Answer 22

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 5

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 6

The potassium tertiary butoxide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

Answer 23

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 24

Expert Solution

Interpretation Introduction

c)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 7

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 8

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 9

The sodium iodide is acts as nucleophile, 1-bromo propane undergoes nucleophilic substitution reaction with sodium iodide gives 1-iodo propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Interpretation Introduction

c)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer 29

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 7

Answer 30

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 8

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 9

The sodium iodide is acts as nucleophile, 1-bromo propane undergoes nucleophilic substitution reaction with sodium iodide gives 1-iodo propane.

Answer 31

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 32

Expert Solution

Interpretation Introduction

d)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 10

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 11

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 12

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Interpretation Introduction

d)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer 37

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 10

Answer 38

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 11

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 12

The sodium amide is acts as a base and it abstract the acidic proton from 1-bromo propane gives carbanion, this carbanion under goes elimination reaction gives propene as a major product.

1-bromo propane undergoes nucleophilic substitution reaction gives propyl amine as a minor product.

Answer 39

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 40

Expert Solution

Interpretation Introduction

e)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 13

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 14

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 15

1-bromo propane undergoes nucleophilic substitution reaction with given alkyne compound gives the corresponding alkyne product.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Interpretation Introduction

e)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer 45

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 13

Answer 46

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 14

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 15

1-bromo propane undergoes nucleophilic substitution reaction with given alkyne compound gives the corresponding alkyne product.

Answer 47

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 48

Expert Solution

Interpretation Introduction

f)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.

Answer to Problem 50AP

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 16

Explanation of Solution

Given information:

The reactant of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 17

The product of the reaction is given below,

EP ORGANIC CHEMISTRY,24 MONTH-OWLV2, Chapter 11.SE, Problem 50AP , additional homework tip 18

1-bromo propane reaction with magnesium gives Grignard reagent and it undergoes hydrolysis gives propane.

Conclusion

The product of the reaction is given when 1-bromopropane reacts with the given reagents.

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Interpretation Introduction

f)

Interpretation:

The product has to be identified when 1-bromopropane reacts with the given reagents.

Concept introduction:

S_N1 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid which yield the corresponding carbocation intermediate, this carbocation intermediate undergoes substitution reaction which yields the corresponding substitution product.

Tertiary alcohols undergo substitution very fast than the secondary alcohols because tertiary carbocation is more stable than the secondary carbocation than the primary carbocation.

Primary alcohol is less stable therefore it wonâ€™t undergo S_N1 substitution reaction.

S_N2 reaction:

The alcohol is reaction with acids like hydrochloric acid or hydrobromic acid, the bromine atom attacks back side of the carbon atoms in simultaneous manner and which is bearing alcohol group which yield the corresponding product.

Elimination reaction: An elimination reaction is removal of two substituents in a molecule and forms alkene. An elimination reaction is one or two-step process which based on the mechanism when two substituents removed from the molecule in single step is called E2 reaction. When two substituents are removed from the molecule in two steps is called E1 reaction.

The Grignard reaction:

Alkyl, vinyl, or aryl-magnesium halides (RMgX) is called as Grignard reagent.