Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Textbook Question
Chapter 1.12, Problem 1.24P
Chloroform, once used as an anesthetic agent, has a density of 1.474 g/mL. What volume would you use if you needed 12.37 g?
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6. Which one is the major organic product
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CO₂Me
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2. H₂O
CH₂OH
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A
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1. (10 points) Pulverized coal pellets, which may be
°
approximated as carbon spheres of radius r = 1 mm, are
burned in a pure oxygen atmosphere at 1450 K and 1 atm.
Oxygen is transferred to the particle surface by diffusion, where
it is consumed in the reaction C + O₂ →> CO₂. The reaction rate
is first order and of the form No2 = k₁C₁₂(r), where k₁ = 0.1 m/s.
Neglecting changes in r, determine the steady-state O₂ molar
consumption rate in kmol/s. At 1450 K, the binary diffusion
coefficient for O2 and CO2 is 1.71 x 10ª m²/s.
2. (20 points) Consider combustion of hydrogen gas in a mixture
of hydrogen and oxygen adjacent to the metal wall of a
combustion chamber. Combustion occurs at constant
temperature and pressure according to the chemical reaction
2H₂+ O₂→ 2H₂O. Measurements under steady-state conditions
at 10 mm from the wall indicate that the molar concentrations
of hydrogen, oxygen, and water vapor are 0.10, 0.10, and 0.20
kmol/m³, respectively. The generation rate of water vapor is
0.96x102 kmol/m³s throughout the region of interest. The binary
diffusion coefficient for each of the species (H, O̟, and H₂O) in
the remaining species is 0.6 X 10-5 m²/s.
(a) Determine an expression for and make a qualitative plot
of C as a function of distance from the wall.
H2
(b) Determine the value of C2 at the wall.
H2
(c) On the same coordinates used in part (a), sketch curves
for the concentrations of oxygen and water vapor. This will
require you to calculate Co, and C.
02
H20
(d) What is the molar flux of water…
Chapter 1 Solutions
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Ch. 1.2 - Pure acetic acid, which gives the sour taste to...Ch. 1.3 - Classify each of the following as a mixture or a...Ch. 1.3 - Classify each of the following as a physical...Ch. 1.3 - In the next image, red spheres represent element A...Ch. 1.3 - The active ingredient in aspirin, ASA, melts at...Ch. 1.3 - Prob. 1.2CIAPCh. 1.4 - Match the names of the elements described below...Ch. 1.4 - Identify the elements represented in each of the...Ch. 1.6 - Calomel (Hg2Cl2) is not toxic but methyl mercury...Ch. 1.6 - Give the full name of the following units and...
Ch. 1.8 - Prob. 1.8PCh. 1.8 - How would you record the temperature reading on...Ch. 1.8 - Prob. 1.10PCh. 1.8 - Convert the following values from scientific...Ch. 1.8 - Prob. 1.12PCh. 1.9 - Round off the following quantities to the...Ch. 1.9 - Carry out the following calculations, rounding...Ch. 1.10 - Prob. 1.15PCh. 1.10 - Convert 0.840 qt to milliliters in a single...Ch. 1.10 - A patient is to receive 20 mg of methimazole, a...Ch. 1.10 - Calculate the dosage in milligrams per kilogram...Ch. 1.11 - A thermochromic plastic chip included in a...Ch. 1.11 - A temperature-sensitive bath toy undergoes several...Ch. 1.11 - The highest land temperature ever recorded was 136...Ch. 1.11 - Prob. 1.20PCh. 1.11 - Prob. 1.21PCh. 1.11 - What is the specific heat of aluminum if it takes...Ch. 1.12 - A sample of pumice, a porous volcanic rock, weighs...Ch. 1.12 - Chloroform, once used as an anesthetic agent, has...Ch. 1.12 - The sulfuric acid solution in an automobile...Ch. 1.12 - Prob. 1.6CIAPCh. 1.12 - Prob. 1.7CIAPCh. 1 - The six elements in blue at the far right of the...Ch. 1 - Identify the three elements indicated on the...Ch. 1 - The radioactive element indicated on the following...Ch. 1 - (a)What is the specific gravity of the following...Ch. 1 - Assume that you have two graduated cylinders, one...Ch. 1 - State the length of the pencil depicted in the...Ch. 1 - Assume that you are delivering a solution sample...Ch. 1 - Assume that identical hydrometers are placed in...Ch. 1 - What is the difference between a physical change...Ch. 1 - Which of the following is a physical change and...Ch. 1 - Which of the following is a physical change and...Ch. 1 - Name and describe the three states of matter.Ch. 1 - Prob. 1.38ASPCh. 1 - Sulfur dioxide is a compound produced when sulfur...Ch. 1 - Butane (C4H8) is an easily compressible gas used...Ch. 1 - Classify each of the following as a mixture or a...Ch. 1 - Which of these terms, (i) mixture, (ii) solid,...Ch. 1 - Hydrogen peroxide, often used in solutions to...Ch. 1 - Prob. 1.44ASPCh. 1 - What is the most abundant element in the earths...Ch. 1 - Prob. 1.46ASPCh. 1 - Supply the missing names or symbols for the...Ch. 1 - Prob. 1.48ASPCh. 1 - Prob. 1.49ASPCh. 1 - Prob. 1.50ASPCh. 1 - Glucose, a form of sugar, has the formula C6H12O6....Ch. 1 - Prob. 1.52ASPCh. 1 - Prob. 1.53ASPCh. 1 - Prob. 1.54ASPCh. 1 - Prob. 1.55ASPCh. 1 - Prob. 1.56ASPCh. 1 - Prob. 1.57ASPCh. 1 - How many pictograms are in 1 mg? In 35 ng?Ch. 1 - How many microliters are in 1 L? In 20 mL?Ch. 1 - Prob. 1.60ASPCh. 1 - Prob. 1.61ASPCh. 1 - Prob. 1.62ASPCh. 1 - Prob. 1.63ASPCh. 1 - Prob. 1.64ASPCh. 1 - Round off each of the numbers in Problem 1.63 to...Ch. 1 - Carry out the following calculations, express each...Ch. 1 - Prob. 1.67ASPCh. 1 - Carry out the following conversions: (a) 3.614 mg...Ch. 1 - Carry out the following conversions. Consult...Ch. 1 - Express the following quantities in more...Ch. 1 - Fill in the blanks to complete the equivalencies...Ch. 1 - Prob. 1.72ASPCh. 1 - The muzzle velocity of a projectile fired from a 9...Ch. 1 - Prob. 1.74ASPCh. 1 - The Willis Tower in Chicago has an approximate...Ch. 1 - Prob. 1.76ASPCh. 1 - Prob. 1.77ASPCh. 1 - The white blood cell concentration in normal blood...Ch. 1 - Prob. 1.79ASPCh. 1 - Diethyl ether, a substance once used as a general...Ch. 1 - Prob. 1.81ASPCh. 1 - Calculate the specific heat of copper if it takes...Ch. 1 - Prob. 1.83ASPCh. 1 - A 150 g sample of mercury and a 150 g sample of...Ch. 1 - When 100 cal (418 J) of heat is applied to a 125 g...Ch. 1 - Prob. 1.86ASPCh. 1 - Prob. 1.87ASPCh. 1 - Prob. 1.88ASPCh. 1 - Prob. 1.89ASPCh. 1 - Prob. 1.90ASPCh. 1 - Ethylene glycol, commonly used as automobile...Ch. 1 - Prob. 1.92ASPCh. 1 - Prob. 1.93ASPCh. 1 - Prob. 1.94ASPCh. 1 - Prob. 1.95ASPCh. 1 - Prob. 1.96ASPCh. 1 - Prob. 1.97ASPCh. 1 - Prob. 1.98ASPCh. 1 - Prob. 1.99ASPCh. 1 - Approximately 75 mL of blood is pumped by a normal...Ch. 1 - Prob. 1.101CPCh. 1 - Prob. 1.102CPCh. 1 - Prob. 1.103CPCh. 1 - Prob. 1.104CPCh. 1 - Prob. 1.105CPCh. 1 - Prob. 1.106CPCh. 1 - Prob. 1.107CPCh. 1 - When 1.0 tablespoon of butter is burned or used by...Ch. 1 - Prob. 1.109CPCh. 1 - Prob. 1.110CPCh. 1 - Prob. 1.111CPCh. 1 - At a certain point, the Celsius and Fahrenheit...Ch. 1 - Prob. 1.113GPCh. 1 - Prob. 1.114GPCh. 1 - Sulfuric acid (H2SO4, density 1.83 g/mL) is...
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