(a)
Interpretation:
Condensed formula and line formula for 1-bromo-3-hexyne has to be drawn.
Concept Introduction:
Organic compounds can be drawn from its IUPAC name. Initially, the parent chain is identified from the IUPAC name. After that the carbon chain is drawn with carbon atoms alone. Next step is to add the substituents in the respective positions as indicated in the IUPAC name. Remaining valency of carbon atom is satisfied by adding correct number of hydrogen atoms.
Condensed structural formula is a simplified form of representation of a molecule. This gives the information about all the atoms present in molecule and the atoms are placed in sequential order which gives information about which atom is bonded to other atom.
Line formula is the simplest representation of molecule. Carbon atoms are not explicitly shown in line formula. Intersection of lines and the end point of line are considered as carbon atoms. At the end-point it is understood as methyl group. Heteroatoms and hydrogen bonded to the heteroatoms are shown explicitly.
(b)
Interpretation:
Condensed formula and line formula for dichloroethyne has to be drawn.
Concept Introduction:
Refer part (a).
(c)
Interpretation:
Condensed formula and line formula for 2-butyne has to be drawn.
Concept Introduction:
Refer part (a).
(d)
Interpretation:
Condensed formula and line formula for 9-iodo-1-nonyne has to be drawn.
Concept Introduction:
Refer part (a).
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Chapter 11 Solutions
GENERAL,ORGANIC+BIOCHEM (LOOSELEAF)
- Calculate the reaction rate for selenious acid, H2SeO3, if 0.1150 M I-1 decreases to 0.0770 M in 12.0 minutes. H2SeO3(aq) + 6I-1(aq) + 4H+1(aq) ⟶ Se(s) + 2I3-1(aq) + 3H2O(l)arrow_forwardProblem 5-31 Which of the following objects are chiral? (a) A basketball (d) A golf club (b) A fork (c) A wine glass (e) A spiral staircase (f) A snowflake Problem 5-32 Which of the following compounds are chiral? Draw them, and label the chirality centers. (a) 2,4-Dimethylheptane (b) 5-Ethyl-3,3-dimethylheptane (c) cis-1,4-Dichlorocyclohexane Problem 5-33 Draw chiral molecules that meet the following descriptions: (a) A chloroalkane, C5H11Cl (c) An alkene, C6H12 (b) An alcohol, C6H140 (d) An alkane, C8H18 Problem 5-36 Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. How H3C CH3 many chirality centers does erythronolide B have? OH Identify them. H3C -CH3 OH Erythronolide B H3C. H3C. OH OH CH3arrow_forwardPLEASE HELP! URGENT! PLEASE RESPOND!arrow_forward
- 2. Propose a mechanism for this reaction. ہلی سے ملی N H (excess)arrow_forwardSteps and explanationn please.arrow_forwardProblem 5-48 Assign R or S configurations to the chirality centers in ascorbic acid (vitamin C). OH H OH HO CH2OH Ascorbic acid O H Problem 5-49 Assign R or S stereochemistry to the chirality centers in the following Newman projections: H Cl H CH3 H3C. OH H3C (a) H H H3C (b) CH3 H Problem 5-52 Draw the meso form of each of the following molecules, and indicate the plane of symmetry in each: OH OH (a) CH3CHCH2CH2CHCH3 CH3 H3C. -OH (c) H3C CH3 (b) Problem 5-66 Assign R or S configurations to the chiral centers in cephalexin, trade-named Keflex, the most widely prescribed antibiotic in the United States. H2N H IHH S Cephalexin N. CH3 CO₂Harrow_forward
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