Study Guide for Chemistry: The Central Science
13th Edition
ISBN: 9780321949288
Author: Theodore E. Brown, James C. Hill
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 11, Problem 77AE
In dichloromethane, CH2Cl2 (μ= 1.60D)), the dispersion force contribution to the intermolecular attractive forces is about five times larger than the dipole—dipole contribution. Compared to CH2Cl2, would you expect the relative importance of the dipole—dipole contribution to increase or decrease (a) in dibromomethane (μ = 1.43 D)?, (b) in difluoromethane (μ = 1.93 D)? (c) Explain.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Liquid cyclohexanone (C6H100) has a normal boiling point of 155 °C and liquid cyclopentanone (CÁH§O) has a
normal boiling point of 131 °C.
(a) In which of the two are the intermolecular forces the weakest?
(b) Which of the two would you expect to have the lowest surface tension at 25 °C?
Which of the following liquids has higher surface tension: ethanol (C2H5OH) or dimethyl ether (CH3OCH3) and why?
Consider what happens when liquid CH 3 OH dissolves in CHCl 3 . (a) What type of attractive forces must be overcome in the liquid CHCl 3 ? (b) What type of forces must be overcome in the liquid CH 3 OH? (c) What type of attractive forces are important when CH 3 OH dissolves in liquid CHCl 3 ?
Chapter 11 Solutions
Study Guide for Chemistry: The Central Science
Ch. 11.2 - Only two isotopes of copper occur naturally:63Cu...Ch. 11.2 - 2.36 Rubidium has two naturally occurring...Ch. 11.3 - a. Thomson’s cathode-ray tube (Figure 2.49) and...Ch. 11.3 -
2.38 Consider the mass spectrometer shown in...Ch. 11.4 - Naturally occurring magnesium has the following...Ch. 11.4 - Mass spectrometry is more often applied to...Ch. 11.5 - 2-41 For each of the following elements, write its...Ch. 11.5 - Locate each of the following elements in the...Ch. 11.6 - 2-43 For each of the following elements, write its...Ch. 11.6 - 2.44 The elements of group 4A show an interesting...
Ch. 11.7 - 2.45 The structural formulas of the compounds...Ch. 11.7 - 2.46 Ball-and-stick representations of benzene, a...Ch. 11 - Prob. 1DECh. 11 - 2.59 Using the periodic table to guide you,...Ch. 11 -
2.71 Name the following ionic compounds:
a....Ch. 11 -
2.83
What is a functional group?
What functional...Ch. 11 - The element lead (Pb) consists of four naturally...Ch. 11 - Prob. 5ECh. 11 - The molecules have the same molecular formula...Ch. 11 - A sample of an ionic compound containing iron and...Ch. 11 -
The compound dioxane, which is used as a solvent...Ch. 11 - If 3.00 g of titanium metal is reacted with 6.00 g...Ch. 11 -
2.48 Two substances have the same molecular and...Ch. 11 - 2.49 Write the empirical formula corresponding to...Ch. 11 - Determine the molecular and empirical formulas of...Ch. 11 - 251 How many hydrogen atoms are un each of the...Ch. 11 - Prob. 14ECh. 11 - 253 Write the molecular and structural formulas...Ch. 11 - 2-54 Write the molecular and structural formulas...Ch. 11 - Fill in the gaps in the following table’Ch. 11 - 2.56 Fill in the gaps in the following...Ch. 11 - Prob. 19ECh. 11 - Prob. 20ECh. 11 - Predict the chemical formulas of the compounds...Ch. 11 - Prob. 22ECh. 11 - Prob. 23ECh. 11 - Predict whether each of the following compounds is...Ch. 11 - 2.66 Which of the following are ionic, and which...Ch. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 -
2.69 Give the names and charges of the cation and...Ch. 11 - Give the names and charges of the cation and anion...Ch. 11 - Prob. 30ECh. 11 -
Give the chemical formula for each of the...Ch. 11 -
2.75 Give the name or chemical formula, as...Ch. 11 - Prob. 33ECh. 11 -
2.T Give the name or Chemical formula, as...Ch. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 - Assume that you encounter the following sentences...Ch. 11 - a. What is a hydrocarbon? b. Pentane is the alkane...Ch. 11 - Prob. 39ECh. 11 -
2.85 Chloropropane is derived from propane by...Ch. 11 - Prob. 41ECh. 11 - Suppose a scientist repeats the Millikan oil-drop...Ch. 11 -
2.88 The natural abundance of 3He is...Ch. 11 - A cube of gold that is 1.00 cm on a side has a...Ch. 11 -
2.90 The diameter of a rubidium atom is 4.95 A....Ch. 11 -
2.91
Assuming the dimensions of the nucleus and...Ch. 11 - (a) What is the significance of the critical...Ch. 11 -
2.93 The nucleus of 6Li is a powerful absorber of...Ch. 11 - The element oxygen has three naturally occurring...Ch. 11 - Using a suitable reference such as the CRC...Ch. 11 - There are two different isotopes of bromine atoms....Ch. 11 -
2.99 It is common in mass spectrometry to assume...Ch. 11 - From the following list of elements—Ar, H, Ga, Al,...Ch. 11 - Prob. 54ECh. 11 -
2.102 The explosion of an atomic bomb releases...Ch. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 -
2.105 From the molecular structures shown here,...Ch. 11 -
2.106 Name each of the following oxides. Assuming...Ch. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Give the chemical names of each of the following...Ch. 11 -
2.112 Many familiar substances have common,...Ch. 11 -
2.113 Because many ions and compounds have very...Ch. 11 -
2.114 In what part of the atom does the strong...Ch. 11 - In the following diagram, the white spheres...Ch. 11 - In the following digram, the white spheres...Ch. 11 - Prob. 68ECh. 11 - Balance these equations by providing the missing...Ch. 11 - Write the balanced equation for the reaction that...Ch. 11 - Prob. 71ECh. 11 - Which of the following is the correct formula...Ch. 11 - Prob. 73AECh. 11 - Prob. 74AECh. 11 - Calculate the percentage of potassium by mass in...Ch. 11 - Which of the following samples contains the fewest...Ch. 11 - In dichloromethane, CH2Cl2 (= 1.60D)), the...Ch. 11 - Prob. 78AECh. 11 -
How many oxygen atoms are in (a) 0.25 mol...Ch. 11 - Prob. 80AECh. 11 - Prob. 81AECh. 11 - What is the mass, in grams, of 6.33 mol of NaHC03...Ch. 11 - What is the mass, in grams, of (a) 0.50 mol of...Ch. 11 - How many chlorine atoms are in 12.2 g of CCL4? a....Ch. 11 -
a. How many nitric acid molecules are in 4.20 g...Ch. 11 - A 2.144-g sample of phosgene, a compound used as a...Ch. 11 - A 5.325-g sample of methyl benzoate, a compound...Ch. 11 -
Cyclohexane a commonly used organic solvent, is...Ch. 11 - Prob. 89AECh. 11 - Prob. 90IECh. 11 - Decomposition of KCIO3 is sometimes used to...Ch. 11 - Propane, C3 H8 (Figure 3.8), is a common fuel used...Ch. 11 -
Methanol, CH3OH, reacts with oxygen from air in a...Ch. 11 - When 24 mol of methanol and 15 mol of oxygen...Ch. 11 - a. When 1.50 mol of Al and 3.00 mol of Cl2 combine...Ch. 11 - Molten gallium reacts with arsenic to form the...Ch. 11 -
When a 2.00-g strip of zinc metal is placed in...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What are intermolecular forces? How do they differ from intramolecular forces? What are dipole-dipole forces? How do typical dipole-dipole forces differ from hydrogen bonding interactions? In what ways are they similar? What are London dispersion forces? How do typical London dispersion forces differ from dipole-dipole forces? In what ways are they similar? Describe the relationship between molecular size and strength of London dispersion forces. Place the major types of intermolecular forces in order of increasing strength. Is there some overlap? That is, can the strongest London dispersion forces be greater than some dipole-dipole forces? Give an example of such an instance.arrow_forwardIntermolecular forces: What type of forces must be overcome between I2 molecules when solid I2 dissolves in methanol, CH3OH? What type of forces must be disrupted between CH3OH molecules when I2 dissolves? What type of forces exist between I2 and CH3OH molecules in solution?arrow_forwardDefine the following terms and describe how each depends on the strength of the intermolecular forces. a. surface tension b. viscosity c. melting point d. boiling point e. vapor pressurearrow_forward
- On the basis of intermolecular attractions, explain the differences in the boiling points of n butane (1 C) and chloroethane (12 C), which have similar molar masses.arrow_forwardp-Dichlorobenzene, C6H4Cl2, can be one of the ingredients in mothballs. Its vapor pressure at 20C is 0.40 mm Hg. (a) How many milligrams of C6H4Cl2 will sublime into an evacuated 750-mL flask at 20C? (b) If 5.0 mg of p-dichlorobenzene were put into an evacuated 750-mL flask, how many milligrams would remain in the solid phase? (c) What is the final pressure in an evacuated 500-mL flask at 20C that contains 2.00 mg of p-dichlorobenzene? Will there be any solid in the flask?arrow_forward(a) Which is generally stronger, intermolecular interactionsor intramolecular interactions? (b) Which of thesekinds of interactions are broken when a liquid is convertedto a gas?arrow_forward
- 5. The boiling points of the halogens increase in the order F,< Cl,< Br,< l2 due to interactions. the resulting increasing (a) (d) (c) ion-ion ion-dipole dispersion forces (b) hydrogen-bonding (e) permanent dipole-dipole 6. For which of the following would permanent dipole-dipole interactions play an important role in determining physical properties in the liquid state? (a) BF3 (b) CIF (с) ВеCl (d) F2 (e) CCI4 7. For which of the following would dispersion forces be the most important factor in determining physical properties in the liquid state? (a) H20 (b) NaCI (c) F2 (d) HF (e) NH,CIarrow_forwardPredict the intermolecular forces of attraction expected to act on each of the following substances in the physical state given; (a) NaCl(s) (b) He(g) (c) H2O(l) (d) NaCl(aq) (e) MgSO 4 (s) (f) C7 H16 (l) (heptane) (g) NH 3 (aq) (h) air (g)arrow_forward4. A. Use the list of intermolecular and interparticle forces listed below to account for the following phenomena. Justify your answer in each case. London Dispersion Forces lonic Bonding Dipole-Dipole Interactions Metallic Bonding Hydrogen Bonding Covalent Bonding (i) Nacl has a very high heat of vaporization. (ii) The high volatility of helium (boiling point is - 267 °C, lowest of any element). (iii) What are the strongest attractive forces that must be overcome to boil carbon tetrachloride, (CCl,)? B. Read the following statement: NaF has a higher melting point than F2 because it has a greater molar mass. Do you agree with the statement? Explain why you believe the statement is true or falsrarrow_forward
- The boiling points, surface tensions, and viscosities ofwater and several alcohols are as shown below: (a) From ethanol to propanol to n-butanol the boilingpoints, surface tensions, and viscosities all increase. Whatis the reason for this increase? (b) How do you explainthe fact that propanol and ethylene glycol have similarmolecular weights (60 versus 62 amu), yet the viscosity ofethylene glycol is more than 10 times larger than propanol?(c) How do you explain the fact that water has thehighest surface tension but the lowest viscosity?arrow_forwardThe boiling points, surface tensions, and viscosities ofwater and several alcohols are as shown below:(a) From ethanol to propanol to n-butanol the boilingpoints, surface tensions, and viscosities all increase. Whatis the reason for this increase? (b) How do you explainthe fact that propanol and ethylene glycol have similarmolecular weights (60 versus 62 amu), yet the viscosity ofethylene glycol is more than 10 times larger than propanol?(c) How do you explain the fact that water has thehighest surface tension but the lowest viscosity?arrow_forwardThe boiling points, surface tensions, and viscosities ofwater and several alcohols are as shown below:(a) From ethanol to propanol to n-butanol the boilingpoints, surface tensions, and viscosities all increase. Whatis the reason for this increase? (b) How do you explainthe fact that propanol and ethylene glycol have similarmolecular weights (60 versus 62 amu), yet the viscosity ofethylene glycol is more than 10 times larger than propanol?(c) How do you explain the fact that water has thehighest surface tension but the lowest viscosity?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Types of Matter: Elements, Compounds and Mixtures; Author: Professor Dave Explains;https://www.youtube.com/watch?v=dggHWvFJ8Xs;License: Standard YouTube License, CC-BY