The product of the reaction shown is to be determined. Concept introduction: 1,3-dipoles are represented by a Lewis structure such that four electrons are delocalized over three atoms. One of them is positively charged while the other is negatively charged. This dipole acts as a 4π electron component and can add to a 2π electron component via the [4+2]-cycloaddition . The 2π electron component can also be an alkyne which changes to an alkene upon addition. The resultant structure contains a new five membered ring consisting of the 1,3-dipole attached to the two atoms of the alkyne. The triple bond between the carbon atoms of the alkyne changes to a double bond.

Question

Want to see the full answer?

Answer 1

Question

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Please help me figure out these calculation and what should be plotted. These are notes for my chemistry class.

None

Answer 2

Question

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Answer 6

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Answer 7

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 11.1 - Prob. 1P Ch. 11.1 - Prob. 2P Ch. 11.2 - The two compounds shown differ by a factor of 60...Ch. 11.2 - Prob. 4P Ch. 11.2 - Prob. 5P Ch. 11.2 - Prob. 6P Ch. 11.3 - Prob. 7P Ch. 11.3 - Prob. 8P Ch. 11.3 - Evaluate 2,3,3-trimethyl-1-butene as a candidate...Ch. 11.4 - After heating a solution of allyl tert-butyl...

Solution Summary: The author explains that the product of the reaction shown is to be determined. The resultant structure has a double bond only between the carbon and nitrogen atoms of nitrile oxide.

Want to see the full answer?

Chapter 11 Solutions