The product of the reaction shown is to be determined. Concept introduction: 1,3-dipoles are represented by a Lewis structure such that four electrons are delocalized over three atoms. One of them is positively charged while the other is negatively charged. This dipole acts as a 4π electron component and can add to a 2π electron component via the [4+2]-cycloaddition . The 2π electron component can also be an alkyne which changes to an alkene upon addition. The resultant structure contains a new five membered ring consisting of the 1,3-dipole attached to the two atoms of the alkyne. The triple bond between the carbon atoms of the alkyne changes to a double bond.

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Answer 1

Question

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

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Answer 2

Question

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Expert Solution & Answer

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Answer 3

Question

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

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Answer 4

Question

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Expert Solution & Answer

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Answer 5

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Answer 6

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Answer 7

Chapter 11, Problem 57DSP

Interpretation Introduction

Interpretation:

The product of the reaction shown is to be determined.

Concept introduction:

1,3-dipoles

are represented by a Lewis structure such that four electrons are delocalized over three atoms.

One of them is positively charged while the other is negatively charged.

This dipole acts as a 4π electron component and can add to a 2π

electron component via the [4+2]-cycloaddition.

The 2π

electron component can also be an alkyne which changes to an alkene upon addition.

The resultant structure contains a new five membered ring consisting of the 1,3-dipole

attached to the two atoms of the alkyne.

The triple bond between the carbon atoms of the alkyne changes to a double bond.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11.1 - Prob. 1P Ch. 11.1 - Prob. 2P Ch. 11.2 - The two compounds shown differ by a factor of 60...Ch. 11.2 - Prob. 4P Ch. 11.2 - Prob. 5P Ch. 11.2 - Prob. 6P Ch. 11.3 - Prob. 7P Ch. 11.3 - Prob. 8P Ch. 11.3 - Evaluate 2,3,3-trimethyl-1-butene as a candidate...Ch. 11.4 - After heating a solution of allyl tert-butyl...

Solution Summary: The author explains that the product of the reaction shown is to be determined. The resultant structure has a double bond only between the carbon and nitrogen atoms of nitrile oxide.

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Chapter 11 Solutions