
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
expand_more
expand_more
format_list_bulleted
Question
Chapter 11, Problem 45P
Interpretation Introduction
Interpretation:
The product for each of the given compounds undergoing intramolecular Diels -Alder reaction is to be given.
Concept Introduction:
The Diels-Alder reaction is the conjugate addition of an
The two double bonded carbon atoms in the dienophile constitute two possible sites of reaction.
The reaction occurs in one step without forming an intermediate.
The product of a Diels-Alder reaction always contains one more ring than the reactants.
In intramolecular Diels-Alder reaction, a molecule has three double bonds and two of them are conjugated.
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Steps and explanation please
Steps and explanation please
can you please draw out and list step-by-step the synthetic strategy for this rxn? thank you sm in advance
Chapter 11 Solutions
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
Ch. 11.1 - Prob. 1PCh. 11.1 - Prob. 2PCh. 11.2 - The two compounds shown differ by a factor of 60...Ch. 11.2 - Prob. 4PCh. 11.2 - Prob. 5PCh. 11.2 - Prob. 6PCh. 11.3 - Prob. 7PCh. 11.3 - Prob. 8PCh. 11.3 - Evaluate 2,3,3-trimethyl-1-butene as a candidate...Ch. 11.4 - After heating a solution of allyl tert-butyl...
Ch. 11.5 - Prob. 11PCh. 11.6 - Prob. 12PCh. 11.8 - Prob. 13PCh. 11.9 - What dienes containing isolated double bonds are...Ch. 11.10 - Prob. 15PCh. 11.10 - Prob. 16PCh. 11.11 - Prob. 17PCh. 11.12 - Dicarbonyl compounds such as quinones are reactive...Ch. 11.12 - 2,3-Di-tert-butyl-1,3-butadiene is extremely...Ch. 11.12 - Methyl acrylate (H2C=CHCO2CH3) reacts with...Ch. 11.13 - Prob. 21PCh. 11.14 - What diene and dienophile could you use to prepare...Ch. 11.14 - Write equations in the synthetic direction for the...Ch. 11.16 - Prob. 24PCh. 11.16 - Prob. 25PCh. 11 - Write structural formulas for each of the...Ch. 11 - Give an acceptable IUPAC name for each of the...Ch. 11 - A certain species of grasshopper secretes an...Ch. 11 - Which of the following are chiral?...Ch. 11 - Describe the molecular geometry expected for...Ch. 11 - Prob. 31PCh. 11 - What compound of molecular formula C6H10 gives...Ch. 11 - Prob. 33PCh. 11 - Prob. 34PCh. 11 - Prob. 35PCh. 11 - Prob. 36PCh. 11 - Identify the more reactive dienophile in each of...Ch. 11 - Prob. 38PCh. 11 - Prob. 39PCh. 11 - Prob. 40PCh. 11 - Prob. 41PCh. 11 - Prob. 42PCh. 11 - Prob. 43PCh. 11 - Prob. 44PCh. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - Show how to prepare each of the following...Ch. 11 - Prob. 48PCh. 11 - Prob. 49PCh. 11 - Prob. 50PCh. 11 - Compound A was converted to compound B by the...Ch. 11 - Suggest reasonable explanations for each of the...Ch. 11 - Prob. 53PCh. 11 - Prob. 54PCh. 11 - Prob. 55DSPCh. 11 - Prob. 56DSPCh. 11 - Prob. 57DSPCh. 11 - Prob. 58DSPCh. 11 - Prob. 59DSP
Knowledge Booster
Similar questions
- Steps and explanations pleasearrow_forwardUse diagram to answer the following: 1.Is the overall rxn endo- or exothermic. Explain briefly your answer____________________2. How many steps in this mechanism?_____________3. Which is the rate determining step? Explain briefly your answer____________________4. Identify (circle and label) the reactants,the products and intermediate (Is a Cation, Anion, or a Radical?) Please explain and provide full understanding.arrow_forwardDraw the entire mechanism and add Curved Arrows to show clearly how electrons areredistributed in the process. Please explain and provide steps clearly.arrow_forward
- Match the denticity to the ligand. Water monodentate ✓ C₂O2 bidentate H₂NCH₂NHCH2NH2 bidentate x EDTA hexadentate Question 12 Partially correct Mark 2 out of 2 Flag question Provide the required information for the coordination compound shown below: Na NC-Ag-CN] Number of ligands: 20 Coordination number: 2✔ Geometry: linear Oxidation state of transition metal ion: +3 x in 12 correct out of 2 question Provide the required information for the coordination compound shown below. Na NC-Ag-CN] Number of ligands: 20 Coordination number: 2 Geometry: linear 0 Oxidation state of transition metal ion: +3Xarrow_forwardCan you explain step by step behind what the synthetic strategy would be?arrow_forwardPlease explain step by step in detail the reasoning behind this problem/approach/and answer. thank you!arrow_forward
- 2. Predict the product(s) that forms and explain why it forms. Assume that any necessary catalytic acid is present. .OH HO H₂N OHarrow_forwardconsider the rate of the reaction below to be r. Whats the rate after each reaction? Br + NaCN CN + NaBr a. Double the concentration of alkyl bromide b. Halve the concentration of the electrophile & triple concentration of cyanide c. Halve the concentration of alkyl chloridearrow_forwardPredict the organic reactant that is involved in the reaction below, and draw the skeletal ("line") structures of the missing organic reactant. Please include all steps & drawings & explanations.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning


Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning