The IUPAC name for the given cycloalkane needs to be determined. Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

Question

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Answer 1

Question

Chapter 11, Problem 55P

(a)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(a)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 1

The above structure contains a cycloalkane ring with 5 carbon atoms thus, it is cyclopentane.

Here, numbering will be done according to the number of substituents present of cyclopentane ring. There are 2 substituent at one position and 1 substituent at other.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 2

From the above structure, there are 2 propyl groups at 1^s^t position and 1 butyl group at 2ⁿ^d position of cyclopentane ring.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 3

(b)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(b)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 4

The numbering will be done according to the longest carbon chain in the molecule.

The numbering is done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 5

From the above structure, there is 1 ethyl group at 3^r^d position and 1 methyl group at 5^t^h position of the main chain containing 7 carbon atoms.

Therefore, the IUPAC name of the structure will be:

Thus,

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 6

(c)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(c)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 7

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 8

Thus, there are 5 carbon atoms in the parent chain. Also, there are 2 methyl groups at 2ⁿ^d position, 1 methyl group at 3^r^d position and 1 methyl group at 4^t^h position. There are total 4 methyl substituents.

Therefore, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 9

(d)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(d)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 10

It contains a cycloalkane with 8 carbon atoms. Two substituents are same thus, numbering will start from any one of the substituent side.

The numbering can be represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 11

From the above structure, there is 1 methyl and 1 propyl group at 1^s^t and 6^t^h position.

Thus, IUPAC name will be as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 12

Stereochemistry can also be determined by giving priority to the groups attached.

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 13

The 1-2 movement is clockwise but the lowest priority group is in front of the curved arrow so assignment will be reversed. Here, clockwise is S and anti or counterclockwise is R. Since, in the above structure the movement is clockwise so the configuration will be S for both sides. The IUPAC name with configuration will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 14

(e)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(e)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 15

It contains a cycloalkane ring with 6 carbon atoms.

The numbering is represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 16

From the above structure, there is 1 methyl group at 1^s^t position, 1 methyl group at 2ⁿ^d position and 1 ethyl group at 4^t^h position.

Thus, IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 17

(f)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(f)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 18

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 19

From the above structure, there is 1 ethyl group at 4^t^h position and 1 methyl group each at 3^r^d, 6^t^h and 8^t^h carbon atom in the chain.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 20

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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the four structures. Compound C Possible conformations (circle one): Дет

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Answer 2

Question

Chapter 11, Problem 55P

(a)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(a)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 1

The above structure contains a cycloalkane ring with 5 carbon atoms thus, it is cyclopentane.

Here, numbering will be done according to the number of substituents present of cyclopentane ring. There are 2 substituent at one position and 1 substituent at other.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 2

From the above structure, there are 2 propyl groups at 1^s^t position and 1 butyl group at 2ⁿ^d position of cyclopentane ring.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 3

(b)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(b)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 4

The numbering will be done according to the longest carbon chain in the molecule.

The numbering is done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 5

From the above structure, there is 1 ethyl group at 3^r^d position and 1 methyl group at 5^t^h position of the main chain containing 7 carbon atoms.

Therefore, the IUPAC name of the structure will be:

Thus,

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 6

(c)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(c)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 7

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 8

Thus, there are 5 carbon atoms in the parent chain. Also, there are 2 methyl groups at 2ⁿ^d position, 1 methyl group at 3^r^d position and 1 methyl group at 4^t^h position. There are total 4 methyl substituents.

Therefore, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 9

(d)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(d)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 10

It contains a cycloalkane with 8 carbon atoms. Two substituents are same thus, numbering will start from any one of the substituent side.

The numbering can be represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 11

From the above structure, there is 1 methyl and 1 propyl group at 1^s^t and 6^t^h position.

Thus, IUPAC name will be as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 12

Stereochemistry can also be determined by giving priority to the groups attached.

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 13

The 1-2 movement is clockwise but the lowest priority group is in front of the curved arrow so assignment will be reversed. Here, clockwise is S and anti or counterclockwise is R. Since, in the above structure the movement is clockwise so the configuration will be S for both sides. The IUPAC name with configuration will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 14

(e)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(e)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 15

It contains a cycloalkane ring with 6 carbon atoms.

The numbering is represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 16

From the above structure, there is 1 methyl group at 1^s^t position, 1 methyl group at 2ⁿ^d position and 1 ethyl group at 4^t^h position.

Thus, IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 17

(f)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(f)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 18

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 19

From the above structure, there is 1 ethyl group at 4^t^h position and 1 methyl group each at 3^r^d, 6^t^h and 8^t^h carbon atom in the chain.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 20

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Answer 3

Question

Chapter 11, Problem 55P

(a)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(a)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 1

The above structure contains a cycloalkane ring with 5 carbon atoms thus, it is cyclopentane.

Here, numbering will be done according to the number of substituents present of cyclopentane ring. There are 2 substituent at one position and 1 substituent at other.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 2

From the above structure, there are 2 propyl groups at 1^s^t position and 1 butyl group at 2ⁿ^d position of cyclopentane ring.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 3

(b)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(b)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 4

The numbering will be done according to the longest carbon chain in the molecule.

The numbering is done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 5

From the above structure, there is 1 ethyl group at 3^r^d position and 1 methyl group at 5^t^h position of the main chain containing 7 carbon atoms.

Therefore, the IUPAC name of the structure will be:

Thus,

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 6

(c)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(c)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 7

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 8

Thus, there are 5 carbon atoms in the parent chain. Also, there are 2 methyl groups at 2ⁿ^d position, 1 methyl group at 3^r^d position and 1 methyl group at 4^t^h position. There are total 4 methyl substituents.

Therefore, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 9

(d)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(d)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 10

It contains a cycloalkane with 8 carbon atoms. Two substituents are same thus, numbering will start from any one of the substituent side.

The numbering can be represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 11

From the above structure, there is 1 methyl and 1 propyl group at 1^s^t and 6^t^h position.

Thus, IUPAC name will be as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 12

Stereochemistry can also be determined by giving priority to the groups attached.

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 13

The 1-2 movement is clockwise but the lowest priority group is in front of the curved arrow so assignment will be reversed. Here, clockwise is S and anti or counterclockwise is R. Since, in the above structure the movement is clockwise so the configuration will be S for both sides. The IUPAC name with configuration will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 14

(e)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(e)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 15

It contains a cycloalkane ring with 6 carbon atoms.

The numbering is represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 16

From the above structure, there is 1 methyl group at 1^s^t position, 1 methyl group at 2ⁿ^d position and 1 ethyl group at 4^t^h position.

Thus, IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 17

(f)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(f)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 18

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 19

From the above structure, there is 1 ethyl group at 4^t^h position and 1 methyl group each at 3^r^d, 6^t^h and 8^t^h carbon atom in the chain.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 20

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Answer 4

Question

Chapter 11, Problem 55P

(a)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(a)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 1

The above structure contains a cycloalkane ring with 5 carbon atoms thus, it is cyclopentane.

Here, numbering will be done according to the number of substituents present of cyclopentane ring. There are 2 substituent at one position and 1 substituent at other.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 2

From the above structure, there are 2 propyl groups at 1^s^t position and 1 butyl group at 2ⁿ^d position of cyclopentane ring.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 3

(b)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(b)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 4

The numbering will be done according to the longest carbon chain in the molecule.

The numbering is done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 5

From the above structure, there is 1 ethyl group at 3^r^d position and 1 methyl group at 5^t^h position of the main chain containing 7 carbon atoms.

Therefore, the IUPAC name of the structure will be:

Thus,

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 6

(c)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(c)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 7

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 8

Thus, there are 5 carbon atoms in the parent chain. Also, there are 2 methyl groups at 2ⁿ^d position, 1 methyl group at 3^r^d position and 1 methyl group at 4^t^h position. There are total 4 methyl substituents.

Therefore, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 9

(d)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(d)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 10

It contains a cycloalkane with 8 carbon atoms. Two substituents are same thus, numbering will start from any one of the substituent side.

The numbering can be represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 11

From the above structure, there is 1 methyl and 1 propyl group at 1^s^t and 6^t^h position.

Thus, IUPAC name will be as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 12

Stereochemistry can also be determined by giving priority to the groups attached.

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 13

The 1-2 movement is clockwise but the lowest priority group is in front of the curved arrow so assignment will be reversed. Here, clockwise is S and anti or counterclockwise is R. Since, in the above structure the movement is clockwise so the configuration will be S for both sides. The IUPAC name with configuration will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 14

(e)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(e)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 15

It contains a cycloalkane ring with 6 carbon atoms.

The numbering is represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 16

From the above structure, there is 1 methyl group at 1^s^t position, 1 methyl group at 2ⁿ^d position and 1 ethyl group at 4^t^h position.

Thus, IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 17

(f)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(f)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 18

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 19

From the above structure, there is 1 ethyl group at 4^t^h position and 1 methyl group each at 3^r^d, 6^t^h and 8^t^h carbon atom in the chain.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 20

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Answer 5

Chapter 11, Problem 55P

(a)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(a)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 1

The above structure contains a cycloalkane ring with 5 carbon atoms thus, it is cyclopentane.

Here, numbering will be done according to the number of substituents present of cyclopentane ring. There are 2 substituent at one position and 1 substituent at other.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 2

From the above structure, there are 2 propyl groups at 1^s^t position and 1 butyl group at 2ⁿ^d position of cyclopentane ring.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 3

(b)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(b)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 4

The numbering will be done according to the longest carbon chain in the molecule.

The numbering is done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 5

From the above structure, there is 1 ethyl group at 3^r^d position and 1 methyl group at 5^t^h position of the main chain containing 7 carbon atoms.

Therefore, the IUPAC name of the structure will be:

Thus,

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 6

(c)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(c)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 7

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 8

Thus, there are 5 carbon atoms in the parent chain. Also, there are 2 methyl groups at 2ⁿ^d position, 1 methyl group at 3^r^d position and 1 methyl group at 4^t^h position. There are total 4 methyl substituents.

Therefore, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 9

(d)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(d)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 10

It contains a cycloalkane with 8 carbon atoms. Two substituents are same thus, numbering will start from any one of the substituent side.

The numbering can be represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 11

From the above structure, there is 1 methyl and 1 propyl group at 1^s^t and 6^t^h position.

Thus, IUPAC name will be as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 12

Stereochemistry can also be determined by giving priority to the groups attached.

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 13

The 1-2 movement is clockwise but the lowest priority group is in front of the curved arrow so assignment will be reversed. Here, clockwise is S and anti or counterclockwise is R. Since, in the above structure the movement is clockwise so the configuration will be S for both sides. The IUPAC name with configuration will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 14

(e)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(e)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 15

It contains a cycloalkane ring with 6 carbon atoms.

The numbering is represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 16

From the above structure, there is 1 methyl group at 1^s^t position, 1 methyl group at 2ⁿ^d position and 1 ethyl group at 4^t^h position.

Thus, IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 17

(f)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(f)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 18

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 19

From the above structure, there is 1 ethyl group at 4^t^h position and 1 methyl group each at 3^r^d, 6^t^h and 8^t^h carbon atom in the chain.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 20

Answer 6

Chapter 11, Problem 55P

(a)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(a)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 1

The above structure contains a cycloalkane ring with 5 carbon atoms thus, it is cyclopentane.

Here, numbering will be done according to the number of substituents present of cyclopentane ring. There are 2 substituent at one position and 1 substituent at other.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 2

From the above structure, there are 2 propyl groups at 1^s^t position and 1 butyl group at 2ⁿ^d position of cyclopentane ring.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 3

Answer 7

Chapter 11, Problem 55P

(a)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

Answer 8

(a)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 1

The above structure contains a cycloalkane ring with 5 carbon atoms thus, it is cyclopentane.

Here, numbering will be done according to the number of substituents present of cyclopentane ring. There are 2 substituent at one position and 1 substituent at other.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 2

From the above structure, there are 2 propyl groups at 1^s^t position and 1 butyl group at 2ⁿ^d position of cyclopentane ring.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 3

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

(b)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(b)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 4

The numbering will be done according to the longest carbon chain in the molecule.

The numbering is done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 5

From the above structure, there is 1 ethyl group at 3^r^d position and 1 methyl group at 5^t^h position of the main chain containing 7 carbon atoms.

Therefore, the IUPAC name of the structure will be:

Thus,

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 6

Answer 13

(b)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

Answer 14

(b)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 4

The numbering will be done according to the longest carbon chain in the molecule.

The numbering is done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 5

From the above structure, there is 1 ethyl group at 3^r^d position and 1 methyl group at 5^t^h position of the main chain containing 7 carbon atoms.

Therefore, the IUPAC name of the structure will be:

Thus,

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 6

Answer 15

(b)

Expert Solution

Answer 16

(b)

Expert Solution

Answer 17

Expert Solution

Answer 18

(c)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(c)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 7

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 8

Thus, there are 5 carbon atoms in the parent chain. Also, there are 2 methyl groups at 2ⁿ^d position, 1 methyl group at 3^r^d position and 1 methyl group at 4^t^h position. There are total 4 methyl substituents.

Therefore, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 9

Answer 19

(c)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

Answer 20

(c)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 7

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 8

Thus, there are 5 carbon atoms in the parent chain. Also, there are 2 methyl groups at 2ⁿ^d position, 1 methyl group at 3^r^d position and 1 methyl group at 4^t^h position. There are total 4 methyl substituents.

Therefore, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 9

Answer 21

(c)

Expert Solution

Answer 22

(c)

Expert Solution

Answer 23

Expert Solution

Answer 24

(d)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(d)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 10

It contains a cycloalkane with 8 carbon atoms. Two substituents are same thus, numbering will start from any one of the substituent side.

The numbering can be represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 11

From the above structure, there is 1 methyl and 1 propyl group at 1^s^t and 6^t^h position.

Thus, IUPAC name will be as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 12

Stereochemistry can also be determined by giving priority to the groups attached.

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 13

The 1-2 movement is clockwise but the lowest priority group is in front of the curved arrow so assignment will be reversed. Here, clockwise is S and anti or counterclockwise is R. Since, in the above structure the movement is clockwise so the configuration will be S for both sides. The IUPAC name with configuration will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 14

Answer 25

(d)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

Answer 26

(d)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 10

It contains a cycloalkane with 8 carbon atoms. Two substituents are same thus, numbering will start from any one of the substituent side.

The numbering can be represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 11

From the above structure, there is 1 methyl and 1 propyl group at 1^s^t and 6^t^h position.

Thus, IUPAC name will be as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 12

Stereochemistry can also be determined by giving priority to the groups attached.

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 13

The 1-2 movement is clockwise but the lowest priority group is in front of the curved arrow so assignment will be reversed. Here, clockwise is S and anti or counterclockwise is R. Since, in the above structure the movement is clockwise so the configuration will be S for both sides. The IUPAC name with configuration will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 14

Answer 27

(d)

Expert Solution

Answer 28

(d)

Expert Solution

Answer 29

Expert Solution

Answer 30

(e)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(e)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 15

It contains a cycloalkane ring with 6 carbon atoms.

The numbering is represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 16

From the above structure, there is 1 methyl group at 1^s^t position, 1 methyl group at 2ⁿ^d position and 1 ethyl group at 4^t^h position.

Thus, IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 17

Answer 31

(e)

Interpretation Introduction

Interpretation: The IUPAC name for the given cycloalkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

Answer 32

(e)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 15

It contains a cycloalkane ring with 6 carbon atoms.

The numbering is represented as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 16

From the above structure, there is 1 methyl group at 1^s^t position, 1 methyl group at 2ⁿ^d position and 1 ethyl group at 4^t^h position.

Thus, IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 17

Answer 33

(e)

Expert Solution

Answer 34

(e)

Expert Solution

Answer 35

Expert Solution

Answer 36

(f)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

(f)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 18

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 19

From the above structure, there is 1 ethyl group at 4^t^h position and 1 methyl group each at 3^r^d, 6^t^h and 8^t^h carbon atom in the chain.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 20

Answer 37

(f)

Interpretation Introduction

Interpretation: The IUPAC name for the given alkane needs to be determined.

Concept Introduction: According to the IUPAC rule, numbering of atom is done to find the longest continuous carbon chain in the molecule. After that name of groups attached to the chain are identified. The location of substituent groups is designated by numbers and name. The last step is to assemble the name by listing the groups in alphabetical order. Prefixes such as di, tri, tetra etc. are used to represent groups of same kind.

Answer 38

(f)

Expert Solution

Explanation of Solution

The given structure is as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 18

The numbering will be done according to the longest carbon chain in the molecule.

The numbering can be done as follows:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 19

From the above structure, there is 1 ethyl group at 4^t^h position and 1 methyl group each at 3^r^d, 6^t^h and 8^t^h carbon atom in the chain.

Thus, the IUPAC name of the molecule will be:

Introduction To General, Organic, And Biochemistry, Chapter 11, Problem 55P , additional homework tip 20

Answer 39

(f)

Expert Solution

Answer 40

(f)

Expert Solution

Answer 41

Expert Solution

Answer 42

Ch. 11.2 - Prob. 11.1QC Ch. 11.3 - Prob. 11.2QC Ch. 11.3 - Prob. 11.3QC Ch. 11.4 - Problem 11-4 Write the molecular formula and IUPAC...Ch. 11.6 - Problem 11-5 Write the molecular formula and IUPAC...Ch. 11.7 - Prob. 11.6QC Ch. 11.8 - Prob. 11.7QC Ch. 11.9 - Prob. 11.8QC Ch. 11.10 - Prob. 11.9QC Ch. 11 - 11-11 Define: Hydrocarbon Alkane Saturated...

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