Think of the reaction shown here as involving the transfer of a fluoride ion from ClF 2 to AsF 5 , to form the ions ClF 2 + and AsF 6 − . As a result, the hybridization scheme of each central atom must change. For each reactant molecule and product ion, indicate (a) its geometric structure and (b) the hybridization scheme for its central atom. ClF 3 +AsF 3 → ( ClF 2 + ) ( AsF 6 − )
Think of the reaction shown here as involving the transfer of a fluoride ion from ClF 2 to AsF 5 , to form the ions ClF 2 + and AsF 6 − . As a result, the hybridization scheme of each central atom must change. For each reactant molecule and product ion, indicate (a) its geometric structure and (b) the hybridization scheme for its central atom. ClF 3 +AsF 3 → ( ClF 2 + ) ( AsF 6 − )
Solution Summary: The author explains the Lewis structure and VSEPR theory used to determine the geometry and shape of the molecule.
Think of the reaction shown here as involving the transfer of a fluoride ion from
ClF
2
to
AsF
5
, to form the ions
ClF
2
+
and
AsF
6
−
. As a result, the hybridization scheme of each central atom must change. For each reactant molecule and product ion, indicate (a) its geometric structure and (b) the hybridization scheme for its central atom.
3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
198.0
200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 11 Solutions
General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
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Quantum Molecular Orbital Theory (PChem Lecture: LCAO and gerade ungerade orbitals); Author: Prof Melko;https://www.youtube.com/watch?v=l59CGEstSGU;License: Standard YouTube License, CC-BY