(a) Interpretation: The hybrid orbital sp 2 is to be defined. Concept introduction: The hybridization is a process in which mixing of two or more atomic orbitals occurs, thuis resulting in the new hybrid orbit. These atomic orbitals which are going to mix have slightly different energies as compared to each other.
(a) Interpretation: The hybrid orbital sp 2 is to be defined. Concept introduction: The hybridization is a process in which mixing of two or more atomic orbitals occurs, thuis resulting in the new hybrid orbit. These atomic orbitals which are going to mix have slightly different energies as compared to each other.
Solution Summary: The author explains that the hybrid orbital sp 2 is a combination of one‘s’ and two ‘p’ orbitals. An antibonding molecular orbit is represented by the sign of asterisk.
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Chapter 11, Problem 77SAE
Interpretation Introduction
(a)
Interpretation:
The hybrid orbital sp2 is to be defined.
Concept introduction:
The hybridization is a process in which mixing of two or more atomic orbitals occurs, thuis resulting in the new hybrid orbit. These atomic orbitals which are going to mix have slightly different energies as compared to each other.
Interpretation Introduction
(b)
Interpretation:
The symbol σ2p* is to be defined.
Concept introduction:
There are two types of molecular orbital which are bonding molecular orbit and the antibonding molecular orbital. An antibonding molecular orbital is represented by the sign of asterisk. This antibonding molecular orbital weakens the bonding between any two atoms.
Interpretation Introduction
(c)
Interpretation:
The term bond order is to be defined.
Concept introduction:
Bond order can be defined as the number of chemical bonds which are present between two atoms. These chemical bonds are formed by the bonding electrons or by antibonding electrons. Stability of any molecule is determined by the value of the bond order.
Interpretation Introduction
(d)
Interpretation:
The term p bond is to be defined.
Concept introduction:
The covalent bonds which are formed by the overlap of atomic orbitals are called pi bonds. In this bond, formations overlap of p-orbitals of two atoms occurs which are placed parallel to each other.
6. Draw the molecular orbital diagram shown to determine which of the following is paramagnetic.
B22+
B22+, B2, C22, B22 and N22+
Molecular Orbital Diagram
B2
C22-
B22-
N22+
Which molecule is paramagnetic?
3. Put the following species in order of increasing bond length by using molecular orbital diagrams and
calculating their bond orders: F2, F2, F2+
Molecular Orbital Diagram
F2
F2
F2+
Bond Order
Shortest bond:
Longest bond
3. Put the following species in order of increasing bond length by using molecular orbital diagrams and
calculating their bond orders: F2, F2, F2+
Molecular Orbital Diagram
F2
F2
F2+
Bond Order
Chapter 11 Solutions
General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
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