EBK CHEMISTRY
1st Edition
ISBN: 9780133888584
Author: Tro
Publisher: VST
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Chapter 11, Problem 31E
Interpretation Introduction
To determine: Final pressure of a gas when its volume is increased to 9.4 L.
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Understanding how substituents activate
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
HN
NH2
Check
X
(Choose one)
(Choose one)
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects on benzene
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Inductive Effects
Resonance Effects
Overall Electron-Density
Molecule
CF3
O donating
O donating
O withdrawing
O withdrawing
O no inductive effects
O no resonance effects
electron-rich
electron-deficient
O similar to benzene
CH3
O donating
O withdrawing
O no inductive effects
O donating
O withdrawing
Ono resonance effects
O electron-rich
O electron-deficient
O similar to benzene
Explanation
Check
Х
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* Hint: Think back to Chem 1 solubility rules.
Follow Up Questions for Part B
12. What impact do the following disturbances to a system at equilibrium have on k, the rate constant
for the forward reaction? Explain. (4 pts)
a) Changing the concentration of a reactant or product. (2 pts)
b) Changing the temperature of an exothermic reaction. (2 pts)
of
Chapter 11 Solutions
EBK CHEMISTRY
Ch. 11 - Prob. 1SAQCh. 11 - Prob. 2SAQCh. 11 - Prob. 3SAQCh. 11 - Prob. 4SAQCh. 11 - Prob. 5SAQCh. 11 - Prob. 6SAQCh. 11 - Prob. 7SAQCh. 11 - A gas mixture is a 1.55-L container at 298 K...Ch. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQ
Ch. 11 - Prob. 11SAQCh. 11 - Prob. 12SAQCh. 11 - Prob. 13SAQCh. 11 - Prob. 14SAQCh. 11 - Prob. 15SAQCh. 11 - Prob. 1ECh. 11 - Prob. 2ECh. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - Prob. 19ECh. 11 - Prob. 20ECh. 11 - Prob. 21ECh. 11 - Prob. 22ECh. 11 - If a reaction occurs in the gas phase at STP, the...Ch. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Prob. 32ECh. 11 - A 48.3-mL sample of gas in a cylinder is warmed...Ch. 11 - A syringe containing 1.55 mL of oxygen gas is...Ch. 11 - A balloon contains 0.158 mol of gas and has a...Ch. 11 - Prob. 36ECh. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - Prob. 39ECh. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - A wine-dispensing system uses argon canisters to...Ch. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Prob. 50ECh. 11 - Aerosol cans carry clear warnings against...Ch. 11 - Prob. 52ECh. 11 - Prob. 53ECh. 11 - Use the molar volume of a gas at STP to calculate...Ch. 11 - What is the density (in g/L) of hydrogen gas at...Ch. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 - A 113-mL gas sample has a mass of 0.171 g at a...Ch. 11 - A sample of gas has a mass of 38.8 mg. Its volume...Ch. 11 - Prob. 60ECh. 11 - A gas mixture contains each of these gases at the...Ch. 11 - A gas mixture with a total pressure of 745 mmHg...Ch. 11 - We add a 1.20-g sample of dry ice to a 755-mL...Ch. 11 - A 275-mL flask contains pure helium at a pressure...Ch. 11 - A gas mixture contains 1.25 g N2 and 0.85 g O2 in...Ch. 11 - Prob. 66ECh. 11 - The hydrogen gas formed in a chemical reaction is...Ch. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - Prob. 72ECh. 11 - Prob. 73ECh. 11 - Prob. 74ECh. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - CH3OH can be synthesized by the reaction:...Ch. 11 - Oxygen gas reacts with powered aluminum according...Ch. 11 - Automobile airbags inflate following serious...Ch. 11 - Lithium reacts with nitrogen gas according to the...Ch. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - Carbon monoxide gas reacts with hydrogen gas to...Ch. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - Use the vander Waals equation and the ideal gas...Ch. 11 - Pennies that are currently being minted are...Ch. 11 - A 2.85 g sample of an unknown chlorofluorocarbon...Ch. 11 - Prob. 97ECh. 11 - A 118 mL flask is evacuated and found to have a...Ch. 11 - Prob. 99ECh. 11 - A gaseous hydrogen- and carbon-containing compound...Ch. 11 - Prob. 101ECh. 11 - Consider the reaction: 2Ag2O(s)4Ag(s)+O2(g) If...Ch. 11 - When hydrochloric acid is poured over potassium...Ch. 11 - Consider the reaction: 2SO2(g)+O2(g)2SO(g)3 If...Ch. 11 - Ammonium carbonate decomposes upon heating...Ch. 11 - Ammonium nitrate decomposes explosively upon...Ch. 11 - Prob. 107ECh. 11 - Prob. 108ECh. 11 - Gaseous ammonia is injected into the exhaust...Ch. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 112ECh. 11 - Prob. 113ECh. 11 - Prob. 114ECh. 11 - Prob. 115ECh. 11 - Prob. 116ECh. 11 - Prob. 117ECh. 11 - Prob. 118ECh. 11 - Prob. 119ECh. 11 - Prob. 120ECh. 11 - Prob. 121ECh. 11 - Prob. 122ECh. 11 - Prob. 123ECh. 11 - Prob. 124ECh. 11 - Prob. 125ECh. 11 - Prob. 126ECh. 11 - When 0.583 g of neon is added to an 800-cm3bulb...Ch. 11 - A gas mixture composed of helium and argon has a...Ch. 11 - Prob. 129ECh. 11 - Prob. 130ECh. 11 - Prob. 131ECh. 11 - Prob. 132ECh. 11 - Prob. 133ECh. 11 - Prob. 134ECh. 11 - The atmosphere slowly oxidizes hydrocarbons in a...Ch. 11 - Prob. 136ECh. 11 - Prob. 137ECh. 11 - Prob. 138ECh. 11 - Prob. 139ECh. 11 - Prob. 140ECh. 11 - Prob. 141ECh. 11 - Prob. 142ECh. 11 - Prob. 143ECh. 11 - Which gas would you expect to deviate most from...Ch. 11 - Prob. 145ECh. 11 - Prob. 146ECh. 11 - Prob. 147E
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