EBK CHEMISTRY
1st Edition
ISBN: 9780133888584
Author: Tro
Publisher: VST
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Chapter 11, Problem 24E
Interpretation Introduction
To determine: Deviation from
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Given a 1,3-dicarbonyl compound, state the (condensed) formula of the compound obtaineda) if I add hydroxylamine (NH2OH) to give an isooxazole.b) if I add thiosemicarbazide (NH2-CO-NH-NH2) to give an isothiazole.
Complete the following acid-base reactions and predict the direction of equilibrium
for each. Justify your prediction by citing pK values for the acid and conjugate acid in
each equilibrium.
(a)
(b) NHs
(c)
O₂N
NH
NH
OH
H₁PO₁
23.34 Show how to convert each starting material into isobutylamine in good yield.
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(b)
Br
OEt
(c)
(d)
(e)
(f)
H
Chapter 11 Solutions
EBK CHEMISTRY
Ch. 11 - Prob. 1SAQCh. 11 - Prob. 2SAQCh. 11 - Prob. 3SAQCh. 11 - Prob. 4SAQCh. 11 - Prob. 5SAQCh. 11 - Prob. 6SAQCh. 11 - Prob. 7SAQCh. 11 - A gas mixture is a 1.55-L container at 298 K...Ch. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQ
Ch. 11 - Prob. 11SAQCh. 11 - Prob. 12SAQCh. 11 - Prob. 13SAQCh. 11 - Prob. 14SAQCh. 11 - Prob. 15SAQCh. 11 - Prob. 1ECh. 11 - Prob. 2ECh. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - Prob. 19ECh. 11 - Prob. 20ECh. 11 - Prob. 21ECh. 11 - Prob. 22ECh. 11 - If a reaction occurs in the gas phase at STP, the...Ch. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Prob. 32ECh. 11 - A 48.3-mL sample of gas in a cylinder is warmed...Ch. 11 - A syringe containing 1.55 mL of oxygen gas is...Ch. 11 - A balloon contains 0.158 mol of gas and has a...Ch. 11 - Prob. 36ECh. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - Prob. 39ECh. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - A wine-dispensing system uses argon canisters to...Ch. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Prob. 50ECh. 11 - Aerosol cans carry clear warnings against...Ch. 11 - Prob. 52ECh. 11 - Prob. 53ECh. 11 - Use the molar volume of a gas at STP to calculate...Ch. 11 - What is the density (in g/L) of hydrogen gas at...Ch. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 - A 113-mL gas sample has a mass of 0.171 g at a...Ch. 11 - A sample of gas has a mass of 38.8 mg. Its volume...Ch. 11 - Prob. 60ECh. 11 - A gas mixture contains each of these gases at the...Ch. 11 - A gas mixture with a total pressure of 745 mmHg...Ch. 11 - We add a 1.20-g sample of dry ice to a 755-mL...Ch. 11 - A 275-mL flask contains pure helium at a pressure...Ch. 11 - A gas mixture contains 1.25 g N2 and 0.85 g O2 in...Ch. 11 - Prob. 66ECh. 11 - The hydrogen gas formed in a chemical reaction is...Ch. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - Prob. 72ECh. 11 - Prob. 73ECh. 11 - Prob. 74ECh. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - CH3OH can be synthesized by the reaction:...Ch. 11 - Oxygen gas reacts with powered aluminum according...Ch. 11 - Automobile airbags inflate following serious...Ch. 11 - Lithium reacts with nitrogen gas according to the...Ch. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - Carbon monoxide gas reacts with hydrogen gas to...Ch. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - Use the vander Waals equation and the ideal gas...Ch. 11 - Pennies that are currently being minted are...Ch. 11 - A 2.85 g sample of an unknown chlorofluorocarbon...Ch. 11 - Prob. 97ECh. 11 - A 118 mL flask is evacuated and found to have a...Ch. 11 - Prob. 99ECh. 11 - A gaseous hydrogen- and carbon-containing compound...Ch. 11 - Prob. 101ECh. 11 - Consider the reaction: 2Ag2O(s)4Ag(s)+O2(g) If...Ch. 11 - When hydrochloric acid is poured over potassium...Ch. 11 - Consider the reaction: 2SO2(g)+O2(g)2SO(g)3 If...Ch. 11 - Ammonium carbonate decomposes upon heating...Ch. 11 - Ammonium nitrate decomposes explosively upon...Ch. 11 - Prob. 107ECh. 11 - Prob. 108ECh. 11 - Gaseous ammonia is injected into the exhaust...Ch. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 112ECh. 11 - Prob. 113ECh. 11 - Prob. 114ECh. 11 - Prob. 115ECh. 11 - Prob. 116ECh. 11 - Prob. 117ECh. 11 - Prob. 118ECh. 11 - Prob. 119ECh. 11 - Prob. 120ECh. 11 - Prob. 121ECh. 11 - Prob. 122ECh. 11 - Prob. 123ECh. 11 - Prob. 124ECh. 11 - Prob. 125ECh. 11 - Prob. 126ECh. 11 - When 0.583 g of neon is added to an 800-cm3bulb...Ch. 11 - A gas mixture composed of helium and argon has a...Ch. 11 - Prob. 129ECh. 11 - Prob. 130ECh. 11 - Prob. 131ECh. 11 - Prob. 132ECh. 11 - Prob. 133ECh. 11 - Prob. 134ECh. 11 - The atmosphere slowly oxidizes hydrocarbons in a...Ch. 11 - Prob. 136ECh. 11 - Prob. 137ECh. 11 - Prob. 138ECh. 11 - Prob. 139ECh. 11 - Prob. 140ECh. 11 - Prob. 141ECh. 11 - Prob. 142ECh. 11 - Prob. 143ECh. 11 - Which gas would you expect to deviate most from...Ch. 11 - Prob. 145ECh. 11 - Prob. 146ECh. 11 - Prob. 147E
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- Please help me Please use https://app.molview.com/ to draw this. I tried, but I couldn't figure out how to do it.arrow_forwardPropose a synthesis of 1-butanamine from the following: (a) a chloroalkane of three carbons (b) a chloroalkane of four carbonsarrow_forwardSelect the stronger base from each pair of compounds. (a) H₂CNH₂ or EtzN (b) CI or NH2 NH2 (c) .Q or EtzN (d) or (e) N or (f) H or Harrow_forward
- 4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HOarrow_forwardb. H3C CH3 H3O+ ✓ H OHarrow_forward2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. CH3arrow_forward
- Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.arrow_forwardIdentify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.arrow_forwardInstructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.arrow_forward
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