Introduction To Chemistry
5th Edition
ISBN: 9781259911149
Author: BAUER, Richard C., Birk, James P., Marks, Pamela
Publisher: Mcgraw-hill Education,
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Chapter 11, Problem 30QP
Interpretation Introduction
Interpretation:
The insolubility of nonpolar solutes in a polar solvent in terms of intermolecular force is to be explained.
Concept Introduction:
Solubility is the property of a substance in which its solid or liquid or gaseous state is dissolved in a liquid (dissolved in solid or gas also).
The solubility of any substance is dependent on the intermolecular force of attraction between solute and solvent.
The more the intermolecular force of attraction between solute and solvent, the more the solubility of the solute.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 11 Solutions
Introduction To Chemistry
Ch. 11 - Prob. 1QCCh. 11 - Prob. 2QCCh. 11 - Prob. 3QCCh. 11 - Prob. 4QCCh. 11 - Prob. 5QCCh. 11 - Prob. 6QCCh. 11 - Prob. 1PPCh. 11 - Prob. 2PPCh. 11 - Prob. 3PPCh. 11 - Prob. 4PP
Ch. 11 - Prob. 5PPCh. 11 - Prob. 6PPCh. 11 - Prob. 7PPCh. 11 - Prob. 8PPCh. 11 - Prob. 9PPCh. 11 - Prob. 10PPCh. 11 - Prob. 11PPCh. 11 - Prob. 1QPCh. 11 - Prob. 2QPCh. 11 - Prob. 3QPCh. 11 - Prob. 4QPCh. 11 - Prob. 5QPCh. 11 - Prob. 6QPCh. 11 - Prob. 7QPCh. 11 - Prob. 8QPCh. 11 - Prob. 9QPCh. 11 - Prob. 10QPCh. 11 - Prob. 11QPCh. 11 - Prob. 12QPCh. 11 - Prob. 13QPCh. 11 - Prob. 14QPCh. 11 - Prob. 15QPCh. 11 - Prob. 16QPCh. 11 - Prob. 17QPCh. 11 - Prob. 18QPCh. 11 - Prob. 19QPCh. 11 - When NaOH dissolves in water, the solution feels...Ch. 11 - Prob. 21QPCh. 11 - Prob. 22QPCh. 11 - Prob. 23QPCh. 11 - Prob. 24QPCh. 11 - Prob. 25QPCh. 11 - Prob. 26QPCh. 11 - Use the rue “like dissolves like� to predict...Ch. 11 - Prob. 28QPCh. 11 - Prob. 29QPCh. 11 - Prob. 30QPCh. 11 - Use intermolecular forces to explain why NaCl is...Ch. 11 - Prob. 32QPCh. 11 - Prob. 33QPCh. 11 - Prob. 34QPCh. 11 - Prob. 35QPCh. 11 - Prob. 36QPCh. 11 - Prob. 37QPCh. 11 - Prob. 38QPCh. 11 - Prob. 39QPCh. 11 - Prob. 40QPCh. 11 - Prob. 41QPCh. 11 - Prob. 42QPCh. 11 - Prob. 43QPCh. 11 - Prob. 44QPCh. 11 - How might you prepare a saturated solution of a...Ch. 11 - Prob. 46QPCh. 11 - Prob. 47QPCh. 11 - Prob. 48QPCh. 11 - Prob. 49QPCh. 11 - Prob. 50QPCh. 11 - Prob. 51QPCh. 11 - Prob. 52QPCh. 11 - Prob. 53QPCh. 11 - Prob. 54QPCh. 11 - Prob. 55QPCh. 11 - Prob. 56QPCh. 11 - Prob. 57QPCh. 11 - Prob. 58QPCh. 11 - The chemical trichloroethylene (TCE) is a...Ch. 11 - Prob. 60QPCh. 11 - Prob. 61QPCh. 11 - Prob. 62QPCh. 11 - Prob. 63QPCh. 11 - Prob. 64QPCh. 11 - Prob. 65QPCh. 11 - Prob. 66QPCh. 11 - Prob. 67QPCh. 11 - Prob. 68QPCh. 11 - Drinking water may contain a low concentration of...Ch. 11 - Prob. 70QPCh. 11 - Prob. 71QPCh. 11 - Prob. 72QPCh. 11 - Prob. 73QPCh. 11 - Prob. 74QPCh. 11 - Prob. 75QPCh. 11 - Prob. 76QPCh. 11 - Prob. 77QPCh. 11 - Prob. 78QPCh. 11 - Prob. 79QPCh. 11 - Prob. 80QPCh. 11 - Prob. 81QPCh. 11 - Prob. 82QPCh. 11 - Prob. 83QPCh. 11 - Prob. 84QPCh. 11 - Prob. 85QPCh. 11 - Prob. 86QPCh. 11 - Prob. 87QPCh. 11 - Prob. 88QPCh. 11 - Prob. 89QPCh. 11 - Prob. 90QPCh. 11 - Prob. 91QPCh. 11 - Prob. 92QPCh. 11 - Prob. 93QPCh. 11 - Prob. 94QPCh. 11 - Prob. 95QPCh. 11 - Prob. 96QPCh. 11 - Prob. 97QPCh. 11 - Prob. 98QPCh. 11 - Prob. 99QPCh. 11 - Prob. 100QPCh. 11 - Prob. 101QPCh. 11 - Prob. 102QPCh. 11 - Prob. 103QPCh. 11 - Prob. 104QPCh. 11 - Prob. 105QPCh. 11 - Prob. 106QPCh. 11 - Prob. 107QPCh. 11 - The solubility of KNO3 increases as the...Ch. 11 - Prob. 109QPCh. 11 - Prob. 110QPCh. 11 - Prob. 111QPCh. 11 - Prob. 112QPCh. 11 - Prob. 113QPCh. 11 - Prob. 114QPCh. 11 - Prob. 115QPCh. 11 - Prob. 116QPCh. 11 - Prob. 117QPCh. 11 - Prob. 118QPCh. 11 - Prob. 119QPCh. 11 - Prob. 120QPCh. 11 - A salad dressing can be made by shaking together...Ch. 11 - Prob. 122QPCh. 11 - Prob. 123QPCh. 11 - Prob. 124QPCh. 11 - Prob. 125QPCh. 11 - Prob. 126QPCh. 11 - Prob. 127QPCh. 11 - Prob. 128QPCh. 11 - Prob. 129QPCh. 11 - Prob. 130QPCh. 11 - Prob. 131QPCh. 11 - Prob. 132QPCh. 11 - Prob. 133QPCh. 11 - Lead(II) iodide, PbI2, is a yellow solid with a...Ch. 11 - Prob. 135QPCh. 11 - Prob. 136QPCh. 11 - Prob. 137QPCh. 11 - Prob. 138QPCh. 11 - Prob. 139QP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY