FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
15th Edition
ISBN: 9781119797807
Author: Hein
Publisher: WILEY
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Chapter 11, Problem 2PE
Interpretation Introduction
Interpretation:
From the given picture, Chlorine atom and Chloride ion has to be identified and explained.
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4. C6H100
5
I peak
3
2
PPM
Integration values: 1.79ppm (2), 4.43ppm (1.33)
Ipeak
None
3. Consider the compounds below and determine if they are aromatic, antiaromatic, or
non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I
electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly
drawn and you should be able to tell that the bonding electrons and lone pair electrons
should reside in which hybridized atomic orbital 2. You should consider ring strain-
flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti-
aromaticity)
H H
N
N:
NH2
N
Aromaticity
(Circle)
Aromatic Aromatic Aromatic Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic TT
electrons
Me
H
Me
Aromaticity
(Circle)
Aromatic Aromatic Aromatic
Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic πT
electrons
H
HH…
Chapter 11 Solutions
FOUNDATIONS OF COLLEGE CHEM +KNEWTONALTA
Ch. 11.1 - Prob. 11.1PCh. 11.2 - Prob. 11.2PCh. 11.3 - Prob. 11.3PCh. 11.4 - Prob. 11.4PCh. 11.4 - Prob. 11.5PCh. 11.5 - Prob. 11.6PCh. 11.6 - Prob. 11.7PCh. 11.6 - Prob. 11.8PCh. 11.7 - Prob. 11.9PCh. 11.8 - Prob. 11.10P
Ch. 11.9 - Prob. 11.11PCh. 11.10 - Prob. 11.12PCh. 11 - Prob. 1RQCh. 11 - Prob. 2RQCh. 11 - Prob. 3RQCh. 11 - Prob. 4RQCh. 11 - Prob. 5RQCh. 11 - Prob. 6RQCh. 11 - Prob. 7RQCh. 11 - Prob. 8RQCh. 11 - Prob. 9RQCh. 11 - Prob. 10RQCh. 11 - Prob. 11RQCh. 11 - Prob. 12RQCh. 11 - Prob. 13RQCh. 11 - Prob. 14RQCh. 11 - Prob. 15RQCh. 11 - Prob. 16RQCh. 11 - Prob. 17RQCh. 11 - Prob. 18RQCh. 11 - Prob. 19RQCh. 11 - Prob. 20RQCh. 11 - Prob. 21RQCh. 11 - Prob. 22RQCh. 11 - Prob. 23RQCh. 11 - Prob. 24RQCh. 11 - Prob. 25RQCh. 11 - Prob. 26RQCh. 11 - Prob. 28RQCh. 11 - Prob. 30RQCh. 11 - Prob. 31RQCh. 11 - Prob. 33RQCh. 11 - Prob. 36RQCh. 11 - Prob. 1PECh. 11 - Prob. 2PECh. 11 - Prob. 3PECh. 11 - Prob. 4PECh. 11 - Prob. 5PECh. 11 - Prob. 6PECh. 11 - Prob. 7PECh. 11 - Prob. 8PECh. 11 - Prob. 9PECh. 11 - Prob. 10PECh. 11 - Prob. 11PECh. 11 - Prob. 12PECh. 11 - Prob. 13PECh. 11 - Prob. 14PECh. 11 - Prob. 15PECh. 11 - Prob. 16PECh. 11 - Prob. 17PECh. 11 - Prob. 18PECh. 11 - Prob. 19PECh. 11 - Prob. 20PECh. 11 - Prob. 21PECh. 11 - Prob. 22PECh. 11 - Prob. 23PECh. 11 - Prob. 24PECh. 11 - Prob. 25PECh. 11 - Prob. 26PECh. 11 - Prob. 27PECh. 11 - Prob. 28PECh. 11 - Prob. 29PECh. 11 - Prob. 30PECh. 11 - Prob. 31PECh. 11 - Prob. 32PECh. 11 - Prob. 33PECh. 11 - Prob. 34PECh. 11 - Prob. 35PECh. 11 - Prob. 36PECh. 11 - Prob. 37PECh. 11 - Prob. 38PECh. 11 - Prob. 39PECh. 11 - Prob. 40PECh. 11 - Prob. 47PECh. 11 - Prob. 48PECh. 11 - Prob. 49PECh. 11 - Prob. 50PECh. 11 - Prob. 51PECh. 11 - Prob. 52PECh. 11 - Prob. 55AECh. 11 - Prob. 56AECh. 11 - Prob. 57AECh. 11 - Prob. 58AECh. 11 - Prob. 59AECh. 11 - Prob. 63AECh. 11 - Prob. 64AECh. 11 - Prob. 65AECh. 11 - Prob. 66AECh. 11 - Prob. 67AECh. 11 - Prob. 68AECh. 11 - Prob. 76AECh. 11 - Prob. 77AECh. 11 - Prob. 78AECh. 11 - Prob. 81AECh. 11 - Prob. 82AECh. 11 - Prob. 83AECh. 11 - Prob. 84AECh. 11 - Prob. 85AECh. 11 - Prob. 86AECh. 11 - Prob. 87AECh. 11 - Prob. 88CECh. 11 - Prob. 89CECh. 11 - Prob. 90CECh. 11 - Prob. 92CECh. 11 - Prob. 93CECh. 11 - Prob. 94CECh. 11 - Prob. 95CE
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- A chemistry graduate student is studying the rate of this reaction: 2 HI (g) →H2(g) +12(g) She fills a reaction vessel with HI and measures its concentration as the reaction proceeds: time (minutes) [IH] 0 0.800M 1.0 0.301 M 2.0 0.185 M 3.0 0.134M 4.0 0.105 M Use this data to answer the following questions. Write the rate law for this reaction. rate = 0 Calculate the value of the rate constant k. k = Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol.arrow_forwardNonearrow_forwardNonearrow_forward
- Q2: Label the following molecules as chiral or achiral, and label each stereocenter as R or S. CI CH3 CH3 NH2 C CH3 CH3 Br CH3 X &p Bra 'CH 3 "CH3 X Br CH3 Me - N OMe O DuckDuckarrow_forward1. For the four structures provided, Please answer the following questions in the table below. a. Please draw π molecular orbital diagram (use the polygon-and-circle method if appropriate) and fill electrons in each molecular orbital b. Please indicate the number of π electrons c. Please indicate if each molecule provided is anti-aromatic, aromatic, or non- aromatic TT MO diagram Number of π e- Aromaticity Evaluation (X choose one) Non-aromatic Aromatic Anti-aromatic || ||| + IVarrow_forward1.3 grams of pottasium iodide is placed in 100 mL of o.11 mol/L lead nitrate solution. At room temperature, lead iodide has a Ksp of 4.4x10^-9. How many moles of precipitate will form?arrow_forward
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