Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Question
Chapter 11, Problem 23P
Interpretation Introduction
(a)
Interpretation:
Interpret the following statement is true or false.
‘cis and trans cycloalkane are present with same molar formula with different connectivity.’.
Concept Introduction:
The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.
If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.
Interpretation Introduction
(b)
Interpretation:
Interpret the following statement is true or false.
‘cis can be transferred to trans isomer by rotation of the carbon single bonded to carbon.’.
Concept Introduction:
The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.
If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.
Interpretation Introduction
(c)
Interpretation:
Interpret the following statement is true or false.
‘cis can be transferred to trans isomer by exchanging the two groups.’.
Concept Introduction:
The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.
If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.
Interpretation Introduction
(d)
Interpretation:
Interpret the following statement is true or false.
‘configuration means arrangement of atom in space.’.
Concept Introduction:
The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.
If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.
Interpretation Introduction
(e)
Interpretation:
Interpret the following statement is true or false.
‘cis-1,4-dimethylcyclohexane and trans-1,4-dimethylcyclohexane are conformers.’.
Concept Introduction:
The position of the substituent attached on the carbon having restricted rotation decides the cis or trans isomerism.
If the substituent facing the same side then cis isomerism is observed while the substituent facing the opposite side then trans isomerism is observed.
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Chapter 11 Solutions
Introduction to General, Organic and Biochemistry
Ch. 11.2 - Prob. 11.1QCCh. 11.3 - Prob. 11.2QCCh. 11.3 - Prob. 11.3QCCh. 11.4 - Problem 11-4 Write the molecular formula and IUPAC...Ch. 11.6 - Problem 11-5 Write the molecular formula and IUPAC...Ch. 11.7 - Prob. 11.6QCCh. 11.8 - Prob. 11.7QCCh. 11.9 - Prob. 11.8QCCh. 11.10 - Prob. 11.9QCCh. 11 - 11-11 Define: Hydrocarbon Alkane Saturated...
Ch. 11 - 11-12 Why is it not accurate to describe an...Ch. 11 - 11-13 What is meant by the term line-angle formula...Ch. 11 - Prob. 4PCh. 11 - Write the molecular formula for each alkane.Ch. 11 - Answer true or false. Constitutional isomers have...Ch. 11 - Which statements are true about constitutional...Ch. 11 - Prob. 8PCh. 11 - Each member of the following set of compounds is...Ch. 11 - Prob. 10PCh. 11 - 11-21 In the six following sets, which pairs of...Ch. 11 - Draw line-angle formulas for the nine...Ch. 11 - Answer true or false. The parent name of an alkane...Ch. 11 - Prob. 14PCh. 11 - Among the ingredients listed in one commercial...Ch. 11 - Prob. 16PCh. 11 - Answer true or false. Cycloalkanes are saturated...Ch. 11 - Prob. 18PCh. 11 - Prob. 19PCh. 11 - Prob. 20PCh. 11 - Prob. 21PCh. 11 - 11-32 Calculate the actual C-C-C bond angles in...Ch. 11 - Prob. 23PCh. 11 - 11-34 What structural feature of cycloalkanes...Ch. 11 - Prob. 25PCh. 11 - 11-36 Name and draw structural formulas for the...Ch. 11 - Name and draw structural formulas for the six...Ch. 11 - 11-38 Why is equatorial methylcyclohexane more...Ch. 11 - Prob. 29PCh. 11 - Consider a cyclohexane ring substituted with one...Ch. 11 - Prob. 31PCh. 11 - Prob. 32PCh. 11 - Which unbranched alkane (Table 11-4) has about the...Ch. 11 - Prob. 34PCh. 11 - Prob. 35PCh. 11 - Prob. 36PCh. 11 - Prob. 37PCh. 11 - 11-48 How are the boiling points of hydrocarbons...Ch. 11 - Answer true or false. Combustion of alkanes is an...Ch. 11 - 11-50 Write balanced equations for the combustion...Ch. 11 - The heat of combustion of methane, a component of...Ch. 11 - 11-52 Draw structural formulas for these...Ch. 11 - Prob. 43PCh. 11 - 11-54 Complete and balance the equation for the...Ch. 11 - Name and draw structural formulas for all pos...Ch. 11 - Prob. 46PCh. 11 - Prob. 47PCh. 11 - 11-58 (Chemical Connections 11A) How many rings in...Ch. 11 - Prob. 49PCh. 11 - Prob. 50PCh. 11 - Prob. 51PCh. 11 - 11-62(Chemical Connections 11C) What are Freons?...Ch. 11 - 11-63 (Chemical Connections 11C) In what way do...Ch. 11 - (Chemical Connections 11C) What are HFCs and...Ch. 11 - Prob. 55PCh. 11 - Prob. 56PCh. 11 - Prob. 57PCh. 11 - Prob. 58PCh. 11 - Which of the following compounds can exist as...Ch. 11 - Prob. 60PCh. 11 - Dodecane, C12H26, is an unbranched alkane Predict...Ch. 11 - Prob. 62PCh. 11 - Prob. 63PCh. 11 - Prob. 64PCh. 11 - As stated in Section 11-9, the wax found in apple...Ch. 11 - Prob. 66PCh. 11 - Prob. 67P
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