Organic Chemistry: Principles And Mechanisms (second Edition)
Organic Chemistry: Principles And Mechanisms (second Edition)
2nd Edition
ISBN: 9780393630749
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter 11, Problem 11.9YT
Interpretation Introduction

Interpretation:

An energy diagram for the mechanism in equation 11-17 that takes into account the relative stabilities of the cations produced in steps 1 and 3 is to be constructed.

Concept introduction:

For a chemical reaction or process, an energy profile (or reaction coordinate diagram) is a theoretical representation of a single energetic pathway along the reaction coordinate as the reactants are transformed into products. The reactant reacts to form an intermediate. The intermediate then reacts to give product. Most of the chemical reactions are multistep reactions. This means, to complete the reaction they needs more than one elementary step.

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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b. CH3 H3C CH3 CH3 H3C an unexpected product, containing a single 9- membered ring the expected product, containing two fused rings H3C-I (H3C)2CuLi an enolate

Chapter 11 Solutions

Organic Chemistry: Principles And Mechanisms (second Edition)

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