Organic Chemistry: Principles And Mechanisms (second Edition)
Organic Chemistry: Principles And Mechanisms (second Edition)
2nd Edition
ISBN: 9780393630749
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter 11, Problem 11.12YT
Interpretation Introduction

Interpretation:

To identify the product produced from 1, 2-addition and from 1, 4-addition in the given reaction.

Concept introduction:

This is an electrophilic addition of HCl across C=C in the given alkene. One carbon atom in both products gains H from HCl. These carbon atoms are similar in both the products. Cl is attached to different carbon atoms in both the products.

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H- H H H H H H Identify and select all structures below that represent a constitutional isomer(s) of the compound shown above. H- H H H A. H H H H-C CI H H D. H H H H H H C C -H H C C H H H H B. H CI H H- C C H H H H E. H CI H C.
Why doesn't this carry on to form a ring by deprotonating the alpha carbon and the negatively-charged carbon attacking the C=O?
6. A solution (0.0004 M) of Fe(S2CNEt2)3 (see the structural drawing below) in chloroform has absorption bands at: 350 nm (absorbance A = 2.34); 514 nm(absorbance A = 0.0532); Calculate the molar absorptivity values for these bands. Comment on their possible nature (charge transfer transitions or d-d S N- transitions?). (4 points)

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Organic Chemistry: Principles And Mechanisms (second Edition)

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