The three carbocation rearrangements in the synthesis of cholesterol from squalene as per Equation 11.38 are to be drawn using curved arrow notation. Concept introduction: Carbocations are prone to rearrangements. Generally, this rearrangement is driven by the formation of a more stable carbocation. There are three ways in which a carbocation rearrangement can occur – a 1, 2-hydride shift, a 1, 2-methyl shift, or a resonance rearrangement.

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Answer 1

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Chapter 11, Problem 11.51P

Interpretation Introduction

Interpretation:

The three carbocation rearrangements in the synthesis of cholesterol from squalene as per Equation 11.38 are to be drawn using curved arrow notation.

Concept introduction:

Carbocations are prone to rearrangements. Generally, this rearrangement is driven by the formation of a more stable carbocation. There are three ways in which a carbocation rearrangement can occur – a 1, 2-hydride shift, a 1, 2-methyl shift, or a resonance rearrangement.

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Zn(OH)2(s) Zn(OH)+ Ksp = 3 X 10-16 B₁ = 1 x 104 Zn(OH)2(aq) B₂ = 2 x 1010 Zn(OH)3 ẞ3-8 x 1013 Zn(OH) B4-3 x 1015

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Answer 2

Question

Chapter 11, Problem 11.51P

Interpretation Introduction

Interpretation:

The three carbocation rearrangements in the synthesis of cholesterol from squalene as per Equation 11.38 are to be drawn using curved arrow notation.

Concept introduction:

Carbocations are prone to rearrangements. Generally, this rearrangement is driven by the formation of a more stable carbocation. There are three ways in which a carbocation rearrangement can occur – a 1, 2-hydride shift, a 1, 2-methyl shift, or a resonance rearrangement.

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Answer 3

Question

Chapter 11, Problem 11.51P

Interpretation Introduction

Interpretation:

The three carbocation rearrangements in the synthesis of cholesterol from squalene as per Equation 11.38 are to be drawn using curved arrow notation.

Concept introduction:

Carbocations are prone to rearrangements. Generally, this rearrangement is driven by the formation of a more stable carbocation. There are three ways in which a carbocation rearrangement can occur – a 1, 2-hydride shift, a 1, 2-methyl shift, or a resonance rearrangement.

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Answer 4

Question

Chapter 11, Problem 11.51P

Interpretation Introduction

Interpretation:

The three carbocation rearrangements in the synthesis of cholesterol from squalene as per Equation 11.38 are to be drawn using curved arrow notation.

Concept introduction:

Carbocations are prone to rearrangements. Generally, this rearrangement is driven by the formation of a more stable carbocation. There are three ways in which a carbocation rearrangement can occur – a 1, 2-hydride shift, a 1, 2-methyl shift, or a resonance rearrangement.

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Answer 5

Chapter 11, Problem 11.51P

Interpretation Introduction

Interpretation:

The three carbocation rearrangements in the synthesis of cholesterol from squalene as per Equation 11.38 are to be drawn using curved arrow notation.

Concept introduction:

Carbocations are prone to rearrangements. Generally, this rearrangement is driven by the formation of a more stable carbocation. There are three ways in which a carbocation rearrangement can occur – a 1, 2-hydride shift, a 1, 2-methyl shift, or a resonance rearrangement.

Answer 6

Chapter 11, Problem 11.51P

Interpretation Introduction

Interpretation:

The three carbocation rearrangements in the synthesis of cholesterol from squalene as per Equation 11.38 are to be drawn using curved arrow notation.

Concept introduction:

Carbocations are prone to rearrangements. Generally, this rearrangement is driven by the formation of a more stable carbocation. There are three ways in which a carbocation rearrangement can occur – a 1, 2-hydride shift, a 1, 2-methyl shift, or a resonance rearrangement.

Answer 7

Chapter 11, Problem 11.51P

Interpretation Introduction

Interpretation:

The three carbocation rearrangements in the synthesis of cholesterol from squalene as per Equation 11.38 are to be drawn using curved arrow notation.

Concept introduction:

Carbocations are prone to rearrangements. Generally, this rearrangement is driven by the formation of a more stable carbocation. There are three ways in which a carbocation rearrangement can occur – a 1, 2-hydride shift, a 1, 2-methyl shift, or a resonance rearrangement.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains how the three carbocation rearrangements in the synthesis of cholesterol from squalene can be drawn using curved arrow notation.

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Chapter 11 Solutions