
Concept explainers
Interpretation:
The hypothetical two-step mechanism in which water adds across the double bond in equation
Concept introduction:
Electron rich compounds of hydrogen contain excess valence electrons to form covalent bonds. Electron-poor (electrophiles) substrates can accept an electron pair to form a new bond. They are attached by nucleophiles (electron rich). In

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Chapter 11 Solutions
Organic Chemistry: Principles And Mechanisms
- Heparin is used as an anti-coagulant. A risk of heparin use is thrombocytopenia, or low platelet count. This risk is minimized with the use of low molecular weight heparins (LMWH), therefore it is desirable to separate LMWH from higher molecular weight heparins. The method of choice to do this is molecular exclusion chromatography. Below is a chromatogram from a molecular exclusion chromatographic run. Peaks ranging from A to J are clearly distinguishable. The heparin mixture that was analyzed had anywhere from 6 to 30 repeat units of monomer (where the heparin with 30 repeat units would be roughly five times the size of the heparin with six repeat units). a. Which letter most likely represents the peak with 6 repeat units given these heparin polymers were separated with molecular exclusion chromatography? b. Explain your reasoning describing the mechanism of retention in molecular exclusion chromatography. 100 80 60 60 Relative Abundance 40 40 E GH 20 20 B A 36 38 40 42 44 46 48 50 50…arrow_forwardHELP NOW PLEASE ! URGENT!arrow_forwardHELP NOW PLEASE ! URGENT!arrow_forward
- Draw a Newman projection for the molecule below from the perspective indicated. Which of the groups (letters A-H) are methyl groups? CH3 H H H A H B ☑ >> H. ABCDEFG I H -H CH3 G D CH F E Numeric 4 points How many gauche interactions exist in the conformation shown in the previous problem? 1arrow_forwardHELP NOW PLEASE ! ASAP! URGENT!arrow_forwardHELP NOW PLEASE ! ASAP! URGENT!arrow_forward
- Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forwardPls help.arrow_forward13) When solid barium phosphate is in equilibrium with its ions, the ratio of barium ions to phosphate ions would be: a. 1:1 b. 2:3 c. 3:2 d. 2:1 14) The pH of a 0.05 M solution of HCl(aq) at 25°C is 15) The pH of a 0.20 M solution of KOH at 25°C isarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
