The conjugated diene that was used as the reactant, which leads to the formation of each of the given products, is to identified, and the complete, detailed mechanism is to be given. Concept introduction: The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to Markovnikov rule, and the 1, 4-addition is the conjugate addition across the double bond by shifting the double bond in the resonating structure of the same carbocation.

Question

Want to see the full answer?

Answer 1

Question

Chapter 11, Problem 11.18P

Interpretation Introduction

Interpretation:

The conjugated diene that was used as the reactant, which leads to the formation of each of the given products, is to identified, and the complete, detailed mechanism is to be given.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to Markovnikov rule, and the 1, 4-addition is the conjugate addition across the double bond by shifting the double bond in the resonating structure of the same carbocation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

If the concentration of A decreases exponentially with time, what is the rate equation? (A). -d[A] (B). dt d[A] = k[A] e-kt dt

Given the first-order reaction: aA → products. State its kinetic equation.

Determine the symmetry of the combination of atomic orbitals for bf 4-

Answer 2

Question

Chapter 11, Problem 11.18P

Interpretation Introduction

Interpretation:

The conjugated diene that was used as the reactant, which leads to the formation of each of the given products, is to identified, and the complete, detailed mechanism is to be given.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to Markovnikov rule, and the 1, 4-addition is the conjugate addition across the double bond by shifting the double bond in the resonating structure of the same carbocation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 11, Problem 11.18P

Interpretation Introduction

Interpretation:

The conjugated diene that was used as the reactant, which leads to the formation of each of the given products, is to identified, and the complete, detailed mechanism is to be given.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to Markovnikov rule, and the 1, 4-addition is the conjugate addition across the double bond by shifting the double bond in the resonating structure of the same carbocation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 11, Problem 11.18P

Interpretation Introduction

Interpretation:

The conjugated diene that was used as the reactant, which leads to the formation of each of the given products, is to identified, and the complete, detailed mechanism is to be given.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to Markovnikov rule, and the 1, 4-addition is the conjugate addition across the double bond by shifting the double bond in the resonating structure of the same carbocation.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 11, Problem 11.18P

Interpretation Introduction

Interpretation:

The conjugated diene that was used as the reactant, which leads to the formation of each of the given products, is to identified, and the complete, detailed mechanism is to be given.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to Markovnikov rule, and the 1, 4-addition is the conjugate addition across the double bond by shifting the double bond in the resonating structure of the same carbocation.

Answer 6

Chapter 11, Problem 11.18P

Interpretation Introduction

Interpretation:

The conjugated diene that was used as the reactant, which leads to the formation of each of the given products, is to identified, and the complete, detailed mechanism is to be given.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to Markovnikov rule, and the 1, 4-addition is the conjugate addition across the double bond by shifting the double bond in the resonating structure of the same carbocation.

Answer 7

Chapter 11, Problem 11.18P

Interpretation Introduction

Interpretation:

The conjugated diene that was used as the reactant, which leads to the formation of each of the given products, is to identified, and the complete, detailed mechanism is to be given.

Concept introduction:

The electrophilic addition reaction in a case of conjugated diene system leads to the formation of a mixture of the isomeric products that are 1, 2-addition and 1, 4-addition products. The major products in 1, 2-addition and 1, 4-addition depend on the stability of the carbocation formed as the reaction intermediate. The most stable carbocation gives the major 1, 2-addition and 1, 4-addition products. The stability order for carbocation is Secondary benzylic > Tertiary > Primary benzylic, allylic > Secondary > Primary > Methyl etc. The 1, 2-addition occurs according to Markovnikov rule, and the 1, 4-addition is the conjugate addition across the double bond by shifting the double bond in the resonating structure of the same carbocation.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains the electrophilic addition reaction in a conjugated diene system, which leads to the formation of isomeric products. The most stable carbocation gives the major 1, 2-addition and 1, 4-a

Want to see the full answer?

Chapter 11 Solutions