The structure of the alkane cyclopentane has to be predicted. Concept introduction: IUPAC Nomenclature of cycloalkanes: The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’. The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain. While numbering the longest chain, the substituent should get least possible number. Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

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Answer 1

Question

Chapter 11, Problem 11.63QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

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Answer 2

Question

Chapter 11, Problem 11.63QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

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Answer 3

Question

Chapter 11, Problem 11.63QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

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Answer 4

Question

Chapter 11, Problem 11.63QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

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Answer 5

Chapter 11, Problem 11.63QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 6

Chapter 11, Problem 11.63QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 7

Chapter 11, Problem 11.63QP

a)

Interpretation Introduction

Interpretation:

The structure of the alkane cyclopentane has to be predicted.

Concept introduction:

IUPAC Nomenclature of cycloalkanes:

The longest continuous ring of carbon atoms is identified. The prefix is added with ‘cyclo’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 8

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

Answer 9

b)

Interpretation Introduction

Interpretation:

The structure of cis-2-butene has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkenes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Geometric isomers of Alkenes:

Cis-isomer: When two particular atoms (identical group of atoms) are adjacent (on same side) to each other, the alkene is known as cis-isomer.

Trans-isomer: When two particular atoms (identical group of atoms) are opposite from each other, the alkene is known as trans-isomer.

Answer 10

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 11

c)

Interpretation Introduction

Interpretation:

The structure of 2-hexanol has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkanes:

The longest continuous chain of carbon atoms is identified.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 12

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

Answer 13

d)

Interpretation Introduction

Interpretation:

The structure of 1,4-dibromobenzene has to be predicted.

Concept introduction:

IUPAC Nomenclature of Aromatic compounds:

The parent compound of aromatic compound is Benzene.

The substituent groups attached to the parent is identified. A substituent group contains group of atoms attached to the carbon atom of the aromatic ring.

While numbering the parent, the location of the second group relative to the first substituent uses prefixes like o-ortho (1,2-), m-meta (1,3-), and p-para (1,4) in disubstituted aromatic ring.

Answer 14

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 15

e)

Interpretation Introduction

Interpretation:

The structure of 2-butyne has to be predicted.

Concept introduction:

IUPAC Nomenclature of alkynes:

The longest continuous chain of carbon atoms is identified. The suffix is added replaced with ‘yne’.

The substituent groups attached to the parent chain is identified. A substituent group contains group of atoms attached to the carbon atom of the chain.

While numbering the longest chain, the substituent should get least possible number.

Write the name of the compound; the parent name written as last part of the name. The name of the substituents is written as prefix and a hyphen separates the number that the substituents attached with carbon. More than one substituent should be written in alphabetical order.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 11.2 - Prob. 1PE Ch. 11.2 - Prob. 2PE Ch. 11.2 - Prob. 3PE Ch. 11.2 - Prob. 1RC Ch. 11.3 - Prob. 1RC Ch. 11.4 - Prob. 1PE Ch. 11.4 - Prob. 1RC Ch. 11.5 - Prob. 1PE Ch. 11.5 - Prob. 1RC Ch. 11 - Prob. 11.1QP

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