The phase diagram for compound X are given. The following statements has to be explained. Concept introduction: Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant. Triple point: A point at which three phases of a substance meets together. Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Question

Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

Answer 1

Question

Chapter 11, Problem 11.54QP

(a)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(b)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(c)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(d)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z

Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

Answer 2

Question

Chapter 11, Problem 11.54QP

(a)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(b)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(c)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(d)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

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Answer 3

Question

Chapter 11, Problem 11.54QP

(a)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(b)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(c)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(d)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

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Answer 4

Question

Chapter 11, Problem 11.54QP

(a)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(b)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(c)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(d)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

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Answer 5

Chapter 11, Problem 11.54QP

(a)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(b)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(c)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

(d)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 6

Chapter 11, Problem 11.54QP

(a)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 7

Chapter 11, Problem 11.54QP

(a)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The phase diagram for compound X are given. The following statements has to be explained.

Concept introduction:

Phase diagram: Phase diagram is a graphical representation to review the conditions under which varies states of a substance is constant.

Triple point: A point at which three phases of a substance meets together.

Critical point: The critical point is end point of the phase equilibrium curve in phase diagram.

Answer 14

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Answer 25

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Solution Summary: The author explains the phase diagram for compound X, which is a graphical representation to review the conditions under which varies states of the substance is constant.

Chapter 11 Solutions