(a) Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as S N 2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 1

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Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 3

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 4

Question

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

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Answer 5

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 6

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 7

Chapter 11, Problem 11.17P

Interpretation Introduction

(a)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 8

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 9

Interpretation Introduction

(b)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 10

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 11

Interpretation Introduction

(c)

Interpretation: The acetylide anion and alkyl halide that are used to prepare the given alkyne are to be predicted. All the possible routes that are used to prepare the given alkyne are to be shown.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 12

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Answer 15

Ch. 11 - Draw structures for the three alkynes having...Ch. 11 - Prob. 11.2P Ch. 11 - Give the IUPAC name for each compound.Ch. 11 - Give the structures corresponding to each of the...Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Which bases can deprotonate acetylene? The pKa...Ch. 11 - Draw the organic products formed when each alkyne...Ch. 11 - Prob. 11.9P Ch. 11 - Problem 11.9 Draw the products formed when is...

Solution Summary: The author explains that the acetylide anion and alkyl halide that are used to prepare the given Alkyne are to be predicted.

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Chapter 11 Solutions