a) Interpretation: Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated. Concept introduction: Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary. To state: Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Question

2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Answer 1

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

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Answer 3

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

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Answer 4

Question

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

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Answer 5

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 6

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 7

Chapter 10.SE, Problem 49AP

Interpretation Introduction

a)

Interpretation:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-propanol and 2-propanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 8

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 9

Interpretation Introduction

b)

Interpretation:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 1-methylcyclopentanol and 2-methylcyclopentanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 10

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 11

Interpretation Introduction

c)

Interpretation:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide is to be stated.

Concept introduction:

Alcohols react with HX to yield the corresponding alkyl halide. The order of reactivity is methyl < primary < secondary < tertiary.

To state:

Among the two alcohols, 2,2-dimethyl-1-propanol and 2-methyl-2-butanol, which will react faster with HX to form the corresponding alkyl halide.

Answer 12

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Answer 23

Ch. 10.1 - Prob. 1P Ch. 10.1 - Draw structures corresponding to the following...Ch. 10.2 - Prob. 3P Ch. 10.2 - Taking the relative reactivities of 1Â°, 2Â°, and...Ch. 10.4 - Prob. 5P Ch. 10.4 - The major product of the reaction of...Ch. 10.4 - Prob. 7P Ch. 10.5 - Prob. 8P Ch. 10.6 - Prob. 9P Ch. 10.6 - How might you replace a halogen substituent by a...

Solution Summary: The author explains that alcohols react with HX to yield the corresponding alkyl halide.

Chapter 10 Solutions